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Adsorption kinetics of iron (II) From waste/aqueous solution by using potato peel as carbonaceous material

By: Muhammad Usman Sabri, Abdul Qayyum Ather, MubeenAkhtar, Zeeshan Munawar

Key Words: Adsorption, Iron, Isotherms, Kinetics, Potato peels, Wastewater.

Int. J. Biosci. 13(5), 212-220, November 2018.

DOI: http://dx.doi.org/10.12692/ijb/13.5.212-220

Certification: ijb 2018 0021 [Generate Certificate]

Abstract

Adsorption is one of the effective techniques for the removal of iron from aqueous solution / industrial waste water. The liberation of heavy metal pollutant particularly Fe (II) ions emerging out from industries has become a solemn concern. The objective of this study is to use low cost material as adsorbent for adsorption of Fe (II).The adsorption of Fe II from aqueous solution was studied using un-treated and treated (HCl& H3PO4) potato peel charcoal (PPC). Batch adsorption studies were carried out using different parameters like effect of contact time, effect of amount of adsorbent, effect of temperature and effect of concentration of adsorb ate. The test results revealed the adsorption capacity in following sequence: HCl- treated PPC > H3PO4-treated PPC > Untreated PPC. Adsorption studies were carried out by using Freundlich and Langmuir adsorption isotherms. Kinetic studies were revealed out by using pseudo 1st & 2nd order kinetics models to determine the rate constants. It was observed that the rate constants were generally decreased when concentration of solution was increased from 50 mg/L to 250 mg/L.  It was also noticed that correlation coefficients (R2) range from 0.912 to 0.983 for pseudo 1st order and 0.9956 to 0.9995 for pseudo 2nd order model.

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Adsorption kinetics of iron (II) From waste/aqueous solution by using potato peel as carbonaceous material

Babel S, Kurniawan TA. 2004. Cr(VI) removal from synthetic wastewater using coconut shell charcoal and commercial activated carbon modified with oxidizing agents and/or chitosan. Chemosphere 54, 951-967.

Balaria A, Schiewer S. 2008. Assessment of biosorption mechanism for Pb binding by citrus pectin. Separation and Purification Technology 63, 577-581.

Bekci Z, Seki Y, Yurdakoc MK. 2006. Equilibrium studies for trimethoprim adsorption on montmorillonite KSF. Journal of Hazardous Materials 133, 233-242.

Bhattacharyya KG, Gupta SS. 2006. Adsorption of Fe(III) from water by natural and acid activated clays: Studies on equilibrium isotherm, kinetics and thermodynamics of interactions. Adsorption 12, 185–204.

Bhattacharyya KG, Gupta SS. 2008. Adsorption of Fe(III), Co(II) and Ni(II) on ZrO–kaolinite and ZrO–montmorillonite surfaces in aqueous medium. Colloids and Surfaces A 317, 71-79.

Bhattacharyya KG, Gupta SS. 2009. Calcined tetrabutylammonium kaolinite and montmorillonite and adsorption of Fe(II), Co(II) and Ni(II) from solution. Applied Clay Science 46, 216-221.

Chaturvedi S, Dave PN. 2012. Removal of iron for safe drinking water. Desalination 303, 1-11.

Garcia-Rosales G, Colín-Cruz A. 2010. Biosorption of lead by maize (Zea mays) stalk sponge. Journal of Environmental Management 91, 2079-2086.

Gundogdu A, Ozdes D, Duran C, Bulut VN, Soylak M, Senturk HB. 2009. Biosorption of Pb(II) ions from aqueous solution by pine bark (Pinus brutia Ten.). Chemical Engineering Journal 153, 62-69.

Gupta SS, Bhattacharyya KG. 2011. Kinetics of adsorption of metal ions on inorganic materials: A review. Advances in Colloid and Interface Science 162, 39-58.

Hamdi AMB. 2017. Adsorption of Iron and Manganese using Libiyan Bentonite Clay. Chemical Science Transformation 6, 209-218.

Jong T, Parry DL. 2004. Adsorption of Pb(II), Cu(II), Cd(II), Zn(II), Ni(II), Fe(II), and As(V) on bacterially produced metal sulfides. Journal of Colloid and Interface Science 275, 61–71.

Kyzas GZ, Deliyanni EA. 2015. Modified activated carbons from potato peels as green environmental-friendly adsorbents for the treatment of pharmaceutical effluents. Chemical Engineering Research and Design 69, 135-144.

McKay G, Otterburn MS, Sweeney AG. 1980. The removal of colour from effluent using various adsorbents—IV. Silica: Equilibria and column studies. Water Research 14, 21-27.

Moaaz KS, Sridhar K. 2016. Equilibrium and Kinetic studies for adsorption of iron from aqueous solution by synthetic Na-A Zeolite: statistical modelling and optimization. Micropporous and Mesoporous Materials 228, 266-274.

Moreno-Pirajana JC, Giraldo L. 2011. Activated carbon obtained by pyrolysis of potato peel for the removal of heavy metal copper (II) from aqueous solutions. Journal of Analytical and Applied Pyrolysis 90, 42-47.

Nasir HM, Azmi A, Aris AZ, Praveena SM. 2016. Adsorption of Iron by using Hybrid Akar Putra and Comercialized Chiken Eggshells as biosorbent from aqueous solution. Global Journal of Environmental Science Management 2, 257-264.

Ngah WSW, Ghani SA, Kamari A. 2005. Adsorption behaviour of Fe(II) and Fe(III) ions in aqueous solution on chitosan and cross-linked chitosan beads. Bioresource Technology 96, 443–450.

Okeke BC, Frankenberger Jr WT. 2005. Use of starch and potato peel waste for perchlorate bioreduction in water. Science of the Total Environment 347, 35– 45.

Ouadjenia-Marouf F, Marouf R, Schott J, Yahiaoui A. 2013. Removal of Cu(II), Cd(II) and Cr(III) ions from aqueous solution by dam silt. Arabian Journal of Chemistry 6, 401-406.

Ramana DKV, Reddy DHK, Yu JS, Seshaiah K. 2012. Pigeon peas hulls waste as potential adsorbent for removal of Pb(II) and Ni(II) from water. Chemical Engineering Journal 197, 24-33.

Riaz M, Nadeem R, Hanif MA, Ansari TM, Rehman KU. 2009. Pb(II) biosorption from hazardous aqueous streams using Gossypium hirsutum (Cotton) waste biomass. Journal of Hazardous Materials 161, 88–94.

Selatnia A, Boukazoula A, Kechid N, Bakhti MZ, Chergui A. 2004. Biosorption of Fe3+ from aqueous solution by a bacterial dead Streptomyces rimosus biomass. Process Biochemistry 39, 1643-1651.

Sheibani A, Shishehbor M, Alaei H. 2012. Removal of Fe(III) ions from aqueous solution by hazelnut hull as an adsorbent. International Journal of Industrial Chemistry 3, 1-4.

Shukla SR, Pai RS, Shendarkar AD. 2006. Adsorption of Ni(II), Zn(II) and Fe(II) on modified coir fibres. Separation and Purification Technology 47, 141–147.

Tahir SS, Rauf N. 2004. Removal of Fe(II) from the wastewater of a galvanized pipe manufacturing industry by adsorption onto bentonite clay. Journal of Environmental Management 73, 285–292.

Tang PL, Lee CK, Low KS, Zainal Z. 2003. Sorption of Cr(VI) and Cu(II) in aqueous solution by ethylenediamine modified rice hull. Environmental technology 24, 1243-1251.

Tangjuank S, Insuk N, Udeye V, Tontrakoon J. 2009. Chromium (III) sorption from aqueous solutions using activated carbon prepared from cashew nut shells. International Journal of Physical Sciences 4, 412-417.

Tanwar KS, Petitto SC, Ghose SK, Eng PJ, Trainor TP. 2008. Structural study of Fe(II) adsorption on hematite. Geochimica et Cosmochimica Acta 72, 3311–3325.

Tien C, Ramarao BV. 2014. Further examination of the relationship between the Langmuir kinetics and the Lagergren and the second-order rate models of batch adsorption. Separation and Purification Technology 136, 303-308.

Toor M, Jin B. 2012. Adsorption characteristics, isotherm, kinetics, and diffusion of modified natural bentonite for removing diazo dye. Chemical Engineering Journal 187,79-88.

Ullah I, Nadeem R, Iqbal M, Manzoor Q. 2013. Biosorption of chromium onto native and immobilized sugarcane bagasse waste biomass. Ecological Engineering 60, 99-107.

US-EPA. (United State Environmental Protection Agency) 2007. Water Quality Data & Pollution Source: Exercise 13, P.206-216.

Wolfova R, Pertile E, Fecko P. 2013. Removal of lead from aqueous solution by walnut shell. Journal of Environmental Chemistry and Ecotoxicology 5, 159-167.

Xiaotao Z, Yinan H, Ximing W, Zhangjing C. 2017. Adsorption of Iron (III), Cobalt (II) and Nickel (II) on Activated Carbon derived from Xanthoceras Sorbifolia Bange Hull: Mechanism, Kinetics and influencing parameters. Water Science and Technology 75, 1849-1861.

Zaporozhets O, Gawer O, Sukhan V. 1998. Determination of Fe(II), Cu(II) and Ag(I) by using silica gel loaded with 1,10-phenanthroline. Talanta 46, 1387-1394.

Muhammad Usman Sabri, Abdul Qayyum Ather, MubeenAkhtar, Zeeshan Munawar.
Adsorption kinetics of iron (II) From waste/aqueous solution by using potato peel as carbonaceous material.
Int. J. Biosci. 13(5), 212-220, November 2018.
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