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Sustainable Solution to reduce corrosion rate in mild steel using aqueous and organic extracts of Plants

By: Ali Hamza Khalil, Dr. Misbah Ullah

Key Words: Corrosion, Inhibition, Plants, Mild steel, Factorial design

Int. J. Biosci. 12(2), 127-136, February 2018.


Certification: ijb 2018 0238 [Generate Certificate]


Three plants Sageretia thea, Calotropis procera and Cucumis melo were selected to investigate the corrosion inhibition potential against mild steel. Different test concentrations (0.05gm, 0.1gm and 0.3gm) of aqueous, methanol and ethanol extracts of the selected plants were tested in 2 Molar HCL Solution. The main and interactive effects of Plant type sample concentration and solvent used were studied using 33 factorial design of experiment with three replicates by taking readings at 12 hrs, 24 hrs and 48 hrs systematically. Weight loss measurements were considered enough to determine corrosion inhibition efficiency of the selected plants. Statistical results indicate that Main effect of plant type; Joint effect of plant type and extract used; and interaction effect of plant type, extract used and concentration level were found significant at 12 hrs and 24 hrs readings: Also Main Effect of Plant type; Joint effect of Plant type and extract used were found significant factors at 48 hrs readings in the corrosion control via used green resources. Percent weight loss was calculated for all the test samples. Our results indicate that aqueous and organic extracts of Sageretia thea, Calotropis procera and Cucumis melo have impressive anti-corrosion potential against mild steel resulting in remarkable inhibition efficiencies for the included plants.

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Sustainable Solution to reduce corrosion rate in mild steel using aqueous and organic extracts of Plants

Abiola OK, Otaigbe J, Kio O. 2009. Gossipium hirsutum L. extracts as green corrosion inhibitor for aluminum in NaOH solution. Corrosion Science, 51(8), 1879-1881.

Ajani K, Abdulrahman A, Mudiare E. 2014. Inhibitory action of aqueous Citrus aurantifolia seed extract on the corrosion of mild steel in H2SO4 Solution. World Applied Sciences Journal, 31(12), 2141-2147.

Ajayi O, Everitt N, Voisey K. 2016. Evaluation of inulin and aloe vera as green corrosion inhibitors for mild steel in 15% HCl. In: European Federation of Corrosion Congress (Eurocorr, 2016), 11-15 September 2016, Montpellier, France.

Anuradha K, Vimala R, Narayanasamy B, Arockia Selvi J, Rajendran S. 2007. Corrosion inhibition of carbon steel in low chloride media by an aqueous extract of Hibiscus rosa-sinensis Linn. Chemical Engineering Communications 195(3),352-366.

Arockiasamy P, Sheela X, Thenmozhi G, Franco M, Sahayaraj JW, Santhi RJ. 2014. Evaluation of corrosion inhibition of mild steel in 1 M hydrochloric acid solution by Mollugo cerviana. International Journal of Corrosion, 2014.

Behpour M, Ghoreishi S, Kashani MK, Soltani N. 2009. Inhibition of 304 stainless steel corrosion in acidic solution by Ferula gumosa (galbanum) extract. Materials and corrosion 60(11), 895-898.

Belayachi M, Serrar H, Zarrok H, El Assyry A, Zarrouk A, Oudda H. 2015. New pyrimidothiazine derivative as corrosion inhibitor for carbon steel in acidic media. International Jourmal of  Electrochemical Science 10, 3010-3025.

Chigondo M, Chigondo F. 2016. Recent Natural Corrosion Inhibitors for Mild Steel: An Overview. Journal of Chemistry, 2016.

Cruz J, Martınez R, Genesca J, Garcıa-Ochoa E. 2004. Experimental and theoretical study of 1-(2-ethylamino)-2-methylimidazoline as an inhibitor of carbon steel corrosion in acid media. Journal of Electroanalytical Chemistry, 566(1), 111-121.

Ehsani A, Mahjani M, Hosseini M, Safari R, Moshrefi R, Shiri HM. 2017. Evaluation of Thymus vulgaris plant extract as an eco-friendly corrosion inhibitor for stainless steel 304 in acidic solution by means of electrochemical impedance spectroscopy, electrochemical noise analysis and density functional theory. Journal of Colloid and interface Science 490, 444-451.

Ferreira E, Giacomelli C, Giacomelli F,  Spinelli A. 2004. Evaluation of the inhibitor effect of L-ascorbic acid on the corrosion of mild steel. Materials Chemistry and Physics, 83(1), 129-134.

Flores EA, Olivares O, Likhanova NV,Domínguez-Aguilar MA, Nava N, Guzman-Lucero D, 2011. Sodium phthalamates as corrosion inhibitors for carbon steel in aqueous hydrochloric acid solution. Corrosion Science 53(12), 3899-3913.

Gerengi H, Sahin HI. 2011. Schinopsis lorentzii extract as a green corrosion inhibitor for low carbon steel in 1 M HCl solution. Industrial & Engineering Chemistry Research 51(2), 780-787.

Hanza AP, Naderi R, Kowsari E, Sayebani M. 2016. Corrosion behavior of mild steel in H 2 SO 4 solution with 1, 4-di [1′-methylene-3′-methyl imidazolium bromide]-benzene as an ionic liquid. Corrosion Science 107, 96-106.

Hassan HM, Eldesoky AM, Al-Rashdi A, Ahmed HM. 2016. Green Corrosion Electrochemistry: Cheilocostus Speciosus Extract (CSE) Investigated Electro-analytically as a Potential Green Corrosion Inhibitor for Copper within Acidic Solution.International Journal of Emerging Trends in Engineering and Development 1(7), 72-98.

Khandelwal R, Agarwal C, Arora R. 2016. Investigation of extracts of Plant Cordia Dichotoma as potential corrosion inhibitor for Mild Steel in Acid media. Journal of Integrated Science and Technology, 4(2), 87-89.

Li L, Zhang X, Lei J, He J, Zhang S, Pan F. 2012. Adsorption and corrosion inhibition of Osmanthus fragran leaves extract on carbon steel. Corrosion Science, 63, 82-90.

Mert BD, Mert ME, Kardaş, G, Yazıcı B. 2011. Experimental and theoretical investigation of 3-amino-1, 2, 4-triazole-5-thiol as a corrosion inhibitor for carbon steel in HCl medium. Corrosion Science, 53(12), 4265-4272.

Migahed M, Nassar I. 2008. Corrosion inhibition of Tubing steel during acidization of oil and gas wells. Electrochimica Acta, 53(6), 2877-2882.

Morales-Gil P, Walczak M, Camargo CR, Cottis R, Romero J, Lindsay R. 2015. Corrosion inhibition of carbon-steel with 2-mercaptobenzimidazole in hydrochloric acid. Corrosion Science, 101, 47-55.

Morales-Gil P, Walczak M, Cottis R, Romero, J, Lindsay R. 2014. Corrosion inhibitor binding in an acidic medium: Interaction of 2-mercaptobenizmidazole with carbon-steel in hydrochloric acid. Corrosion Science, 85, 109-114.

Mounir F, Salghi R, Jodeh S, El Issami S, Bazzi L. 2016. Argania spinosa (L.) as a source of new and efficient green corrosion inhibitor for copper in acidic medium: A comparative study of three green compounds. International Journal of Corrosion and Scale Inhibition, 5(2), 159-171.

Oguzie E, Enenebeaku C, Akalezi C, Okoro S, Ayuk A, Ejike E. 2010. Adsorption and corrosion-inhibiting effect of Dacryodis edulis extract on low-carbon-steel corrosion in acidic media. Journal of Colloid and interface Science 349(1), 283-292.

Okafor P, Ikpi ME, Uwah I, Ebenso E, Ekpe U, Umoren S. 2008. Inhibitory action of Phyllanthus amarus extracts on the corrosion of mild steel in acidic media. Corrosion Science 50(8), 2310-2317.

Roque JM, Pandiyan T, Cruz J, García-Ochoa E. 2008. DFT and electrochemical studies of tris (benzimidazole-2-ylmethyl) amine as an efficient corrosion inhibitor for carbon steel surface. Corrosion Science, 50(3), 614-624.

Saxena A, Prasad D, Haldhar R. 2016. Withania somnifera Extract as Green Inhibitor for Mild Steel in 8% H^ sub 2^ SO^ sub 4. Asian Journal of Chemistry 28(11), 2471.

Sharma K, Sharma J. 2016. Extract of Heliotropium Indicum as Green Corrosion Inhibitor for Mild Steel in Acidic Medium. International Journal of Engineering, Technology, Science and Research, 3(4), 96-105

Soltani N, Tavakkoli N, Ghasemi M. 2016. Corrosion inhibition of low carbon steel by strychnos nux-vomica extract as green corrosion inhibitor in hydrochloric acid solution. International Journal of Electrochemical Science 11(10), 8827-8847.

Umoren S, Eduok U, Solomon M, Udoh A. 2016. Corrosion inhibition by leaves and stem extracts of Sida acuta for mild steel in 1M H 2 SO 4 solutions investigated by chemical and spectroscopic techniques. Arabian journal of chemistry, 9, S209-S224.

Yurt A, Balaban A, Kandemir SU, Bereket G,  Erk B. 2004. Investigation on some Schiff bases as HCl corrosion inhibitors for carbon steel. Materials Chemistry and Physics, 85(2), 420-426.

Ali Hamza Khalil, Dr. Misbah Ullah.
Sustainable Solution to reduce corrosion rate in mild steel using aqueous and organic extracts of Plants.
Int. J. Biosci. 12(2), 127-136, February 2018.
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