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A novel green spectrophotometric method for the analysis of Cadmium using Benzohydrazide chelating agent

By: Muhammad Kashif Channa, Ghulam Abbas Shar, Gul Afshan Soomro, Muhammad Bachal Korai

Key Words: Benzohydrazide (BH), Cadmium, Spectrophotometry, Triton X-100

J. Bio. Env. Sci. 16(3), 56-64, March 2020.

Certification: jbes 2020 0262 [Generate Certificate]

Abstract

Various methods are present for the analysis at trace level of Cadmium (Cd) metal ions. Most of the methods are time taking, tedious, toxic and sophisticated. Recently some less sensitive and less selective spectrophotometric methods were developed for the determination of Cd (II) ions. We have developed a convenient, rapid, selective and sensitive method for the investigation of Cd (II) at trace level using Benzohydrazide (BH) as chelating agent in surfactant 3.0% Triton X-100 micellar media. Proposed method showed enhancement in the analytical characteristics. The maximum absorbance of complex Cd-BH was measured at  instead of it max 323.9nm at pH 7. The Lambert Beer’s law was obeyed over the range of 0.1-5.0 μgmL-1 and 1:2 ligand to metal ratio was obtained for complex. The Sandell’s sensitivity and molar absorptivity were found to be as 6.2ngcm-2 and ε 3.05×104 L mol-1cm-1 respectively. Detection limit was found as 6.2ng/mL. The proposed technique was effectively employed for the estimation of Cd (II) ions from various biological, natural, alloys, environmental and industrial samples.

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A novel green spectrophotometric method for the analysis of Cadmium using Benzohydrazide chelating agent

Abbasi S, Bahiraei A, Abbasai F. 2011. A highly sensitive method for simultaneous determination of ultra trace levels of copper and cadmium in food and water samples with luminol as a chelating agent by adsorptive stripping voltammetry. Food chemistry 129(3), 1274-1280.

Aşkun H, Gülbakan B, Çelikbıçak Ö, Uzun C, Güven O, Salih B. 2008. Preconcentration and matrix elimination for the determination of Pb (II), Cd (II), Ni (II), and Co (II) by 8‐hydroxyquinoline anchored poly (styrene‐divinylbenzene) microbeads. Journal of applied polymer science 107(4), 2714-2722.

Bernhoft RA. 2013. Cadmium toxicity and treatment. The Scientific World Journal 2013, 1-7.

Burham N, Abdel-Azeem SM, El-Shahat MF. 2011. Determination of heavy metal ions in environmental samples employing preconcentration on novel resins of polyurethane foam linked with o-Aminophenol or o-Hydroxyphenylazonaphthol. International Journal of Environmental and Analytical Chemistry 91(3), 197-212.

Chahid A, Hilali M, Benlhachimi A, Bouzid T. 2014. Contents of cadmium, mercury and lead in fish from the Atlantic sea (Morocco) determined by atomic absorption spectrometry. Food chemistry 147, 357-360.

Dogan Uluozlu O, Tuzen M, Mendil D, Soylak M. 2007. Trace metal content in nine species of fish from the Black and Aegean Seas, Turkey. Food Chemistry 104, 835-840.

Fergusson JE. 1989. The toxicity of heavy elements to human beings in: The Heavy Elements: Chemistry, Environmental Impact and Health Effects. Pergamon Press, Oxford 548.

Friberg L. 2018. Cadmium in the Environment. CRC press.

Iqbal HH, Shahid N, Qadir A, Ahmad SR, Sarwar S, Ashraf MR, Arshad HM, Masood N. 2017. Hydrological and Ichthyological Impact Assessment of Rasul Barrage, River Jhelum, Pakistan. Polish Journal of Environmental Studies 26(1), 107-114.

Jamaluddin MA, Zannat T, Fatema Z. 2014. A Simple Spectrophotometric Method for the Determination of Trace Level of Cadmium in Real, Environmental, Biological, Tobacco, Fertilizer and Soil Samples Using 2’, 3, 4’, 5, 7 Pentahydroxyflavone. American Chemical Science Journal 4(4), 481-503.

Key MM, Henschel AF, Butter J, Ligo RN, Tabershaed IR. 1977. Occupational Diseases-A Guide to Their Recognition, U. S. Department of Health, Education and Welfare, US Government Printing, Washington, DC 265.

Koduru JR, Lee KD. 2014. Evaluation of thiosemicarbazone derivative as chelating agent for the simultaneous removal and trace determination of Cd (II) and Pb (II) in food and water samples. Food chemistry 150, 1-8.

Koksharova TV, Mandzii TV, Stoyanova IV. 2018. Coordination Compounds of Cobalt (II), Nickel (II), and Zinc (II) Malonates and Phthalates with Benzohydrazide. Russian Journal of General Chemistry 88(3), 500-504.

Korai MA, Shar GA, Soomro GA, Korai MB. 2019. Environmental friendly spectrophotometric method for the determination of cadmium (II) using 1-nitroso-2-naphthol in micellar media. Journal of Biodiversity and Environmental Sciences 15(4), 1-9.

Korai MA. 2019. Method development for spectrophotometer determination of chromium, manganese, vanadium and cadmium complexing with 1-nitroso-2-naphthol. PhD. Thesis, Shah Abdul Latif University Khairpur, Sindh, Pakistan.

Korai MB, Shar GA, Soomro GA, Shar NA, Shar RA. 2019. Eco-friendly method for the estimation of cobalt (II) in real samples using 1-(2-Thiazolylazo)-2-naphthol. Journal of Biodiversity and Environmental Sciences 15(1), 12-21.

Korai MB. 2019. Spectrophotometer Determination of cobalt, nickel, iron, copper and zinc using 1-(2-Thiazolylazo)-2-Naphthol in Micellar Media. PhD. Thesis, Shah Abdul Latif University Khairpur, Sindh, Pakistan.

Krishna GD, Devanna N, Chandrasekhar BK. 2010. Direct and derivative spectrophotometric determination of cadmium(II) in presence of micellar medium in biological materials and in alloy samples using cinnamaldehyde-4-hydroxy benzoylhydrazone (CMHBH). International Journal of Pharma and Biosciences 1(3), 1-19.

Malik AK, Rao ALJ. 2000. Spectrophotometric determination of cobalt, nickel, palladium, copper, ruthenium and molybdenum after extraction of their isoamyl xanthate complexes into molten naphthalene. Journal of Analytical Chemistry 55(8), 746-749.

Mezynska M, Brzóska MM. 2018. Environmental exposure to cadmium – A risk for health of the general population in industrialized countries and preventive strategies. Environmental Science and Pollution Research 25(4), 3211-3232.

Mohammed AA, Hussein MA, Albdiri AD. 2018. Application of bulk liquid membrane technique for cadmium extraction from aqueous solution. Arabian Journal for Science and Engineering 43(11), 5851-5858.

Naghibzadeh L, Manoochehri M. 2018. Determination of nickel and cadmium in fish, canned tuna, black tea, and human urine samples after extraction by a novel quinoline thioacetamide functionalized magnetite/graphene oxide nanocomposite. Carbon Letters (Carbon Lett.) 26, 43-50.

Olkowska E, Polkowska Z, Namiesnik J. 2012. Analytical procedures for the determination of surfactants in environmental samples. Talanta 88(2012), 1-13.

Perrin DD. 2012. Buffers for pH and Metal ion Control: Springer science & business media.

Reddy SA, Reddy KJ, Reddy AV. 2010. Analytical Applications of 2, 6‐Diacetylpyridine‐bis‐4‐phenyl‐3‐thiosemicarbazone (2, 6‐DAPBPTSC): Determination of Cd (II) in Foods and Water Samples. Journal of the Chinese Chemical Society 57(2), 236-243.

Rosolina SM, Chambers JQ, Lee CW, Xue ZL. 2015. Direct determination of cadmium and lead in pharmaceutical ingredients using anodic stripping voltammetry in aqueous and DMSO/water solutions. Analytica chimica acta 893, 25-33.

Sanguthai S, Klamtet J. 2015. Preconcentration and Determination of Cadmium in Natural Water using Amberlite XAD-4/4-(2-Pyridylazo) Resorcinol Resin Prior to Flame Atomic Absorption Spectrometric Detection. Naresuan University Journal: Science and Technology (NUJST) 23(2), 8-20.

Singh R, Gautam N, Mishra A, Gupta R. 2011. Heavy metals and living systems: An overview. Indian Journal of Pharmacology 43(3), 246-253.

Soomro GA, Shar GA. 2014. A Simple Spectrophotometric Method for determination of cadmium (II) using 1-(2- pyridylazo)-2-naphthol in micellar aqueous solution of CTAB. Ultra Chemistry 10(2), 95-104.

Taher MA. 2003. Flame Atomic Absorption Spectrometric Determination of Trace Cadmium in Alloys and Biological Samples after Solid-Liquid Extraction and Preconcentration with Use of Nitroso-S. Microchimica Acta 141, 101-106.

Usha G, Rajni R. 2012. Simultaneous determination of Zinc (II) and Cobalt(II) by first order derivative spectrophotometry in Triton X-100 micellar media. Research Journal of Chemical Science 2(11), 8-13.

Velmurugan M, Chen SM. 2017. Synthesis and characterization of porous MnCo2 O4 for electrochemical determination of cadmium ions in water samples. Scientific reports 7(1), 1-8.

Venugopal B, Luckey TD. 1979. Metal Toxicity in Mammals-2, Plemum Press, New York 76.

Wang Z, Wang H, Zhang Z, Yang X, Liu G. 2014. Sensitive electrochemical determination of trace cadmium on a stannum film/poly (p-aminobenzene sulfonic acid)/electrochemically reduced graphene composite modified electrode. Electrochimica Acta 120, 140-146.

Wedepohl KH. 1995. The composition of the continental crust. Geochimica et cosmochimica Acta 59(7), 1217-1232.

Wei XS, Wu YW, Han LJ. 2015. Determination of lead and cadmium in water and pharmaceutical products by inductively coupled plasma optical emission spectrometry with preconcentration by thiourea immobilized silica. Analytical Letters 48(6), 996-1008.

World Health Organization (WHO). 2003. Nordic Council of Ministers, cadmium review.

Yun J, Choi H. 2000. Micellar colorimetric determination of iron, cobalt, nickel and copper using 1-nitroso-2-naphthol. Talanta 52, 893-902.

Zhang Y, Mao X, Liu J, Wang M, Qian Y, Gao C, Qi Y. 2016. Direct determination of cadmium in foods by solid sampling electrothermal vaporization inductively coupled plasma mass spectrometry using a tungsten coil trap. Spectrochimica Acta Part B: Atomic Spectroscopy 118, 119-126.

Muhammad Kashif Channa, Ghulam Abbas Shar, Gul Afshan Soomro, Muhammad Bachal Korai.
A novel green spectrophotometric method for the analysis of Cadmium using Benzohydrazide chelating agent.
J. Bio. Env. Sci. 16(3), 56-64, March 2020.
https://innspub.net/jbes/novel-green-spectrophotometric-method-analysis-cadmium-using-benzohydrazide-chelating-agent/
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