A multifunctional poly (vinylidene fluoride) nanocomposites reinforced with single walled carbon nanotubes and iron oxide nanoparticles

Paper Details

Research Paper 01/01/2019
Views (405) Download (19)
current_issue_feature_image
publication_file

A multifunctional poly (vinylidene fluoride) nanocomposites reinforced with single walled carbon nanotubes and iron oxide nanoparticles

Muhammad Arif, Mohsan Nawaz, Saira Bibi, Saddiqa Bigum, Shakeel Zeb, Qaribullah, Hameed Ur Rehman, Wajid Ullah, Ikram Ullah, Muhammad Ikramullah, Zia Ul Islam, Zohra Aftab Bokharee
Int. J. Biosci.14( 1), 271-283, January 2019.
Certificate: IJB 2019 [Generate Certificate]

Abstract

This research work elaborates the synthesis and characterization of PVDF nanocomposite films reinforced with Fe3O4 NPs and γ-SWCNTs. Nanocomposite film were synthesized through solution casting method, DMF (Dimethyleformamide) used as a solvent. For proper dispersion of nanofiller, samples were sonicated followed by reflux. Different types of PVDF nanocomposite were synthesized by adding different weight percent of nanofiller (0%, 0.03% γ-SWCNTs, 0.01% Fe3O4, 0.03% γ-SWCNTs/0.01% Fe3O4) to PVDF matrix. Results obtained from the analysis of Scanning electron microscopy (SEM), Fourier transform infrared spectrometry (FT-IR), X-rays diffraction (XRD) were very informative for the phase change of PVDF from α-phase to β-phase, Thermogravimetric analysis (TGA) shows the thermal stability of the system, while impedance spectroscopy shows the enhancement in electrical and dielectrical properties of PVDF by incorporating nanofillers.

VIEWS 24

Lovinger AJ. 1983. Ferroelectric polymers, Science 220, p 1115-1121.

Salimi A, Yousefi A. 2003. Analysis method: FTIR studies of β-phase crystal formation in stretched PVDF films, Polymer Testing 22, p 699-704.

Bhatt AS, Bhat DK, Santosh M. 2011. Crystallinity, conductivity, and magnetic properties of PVDF‐Fe3O4 composite films, Journal of Applied Polymer Science 119, p 968-972.

Tsonos C, Pandis C, Soin N, Sakellari D, Myrovali E, Kripotou S. 2015. Multifunctional nanocomposites of poly (vinylidene fluoride) reinforced by carbon nanotubes and magnetite nanoparticles, Express Polymer Letters 9.

Prinz GA. 1998. Magnetoelectronics, Science,vol. 282, p 1660-1663.

Kim GH, Hong SM, Seo Y. 2009. Piezoelectric properties of poly (vinylidene fluoride) and carbon nanotube blends: β-phase development, Physical chemistry chemical physics 11, p 10506-10512.

Kawai H. 1969. The piezoelectricity of poly (vinylidene fluoride), Japanese Journal of Applied Physics 8, p 975.

Bergman Jr J, McFee J, Crane G. 1971. Pyroelectricity and optical second harmonic generation in polyvinylidene fluoride films, Applied Physics Letters 18, p 203-205.

Kumar J, Singh RK, Samanta SB, Rastogi RC, Singh R. 2006. Single‐Step Magnetic Patterning of Iron Nanoparticles in a Semiconducting Polymer Matrix, Macromolecular chemistry and physics 207, p 1584-1588.

Yuan JK, Yao SH, Dang ZM, Sylvestre A, Genestoux M, Bai1 J. 2011. Giant dielectric permittivity nanocomposites: realizing true potential of pristine carbon nanotubes in polyvinylidene fluoride matrix through an enhanced interfacial interaction, The Journal of Physical Chemistry C 115, p 5515-5521.

Wang L, Dang ZM. 2005. Carbon nanotube composites with high dielectric constant at low percolation threshold, Applied physics letters 87, p 042903.

Wang M, Shi JH, Pramoda K, Goh SH. 2007. Microstructure, crystallization and dynamic mechanical behaviour of poly (vinylidene fluoride) composites containing poly (methyl methacrylate)-grafted multiwalled carbon nanotubes,” Nanotechnology 18, p 235701.

Arjmand M, Apperley T, Okoniewski M, Sundararaj U. 2012. Comparative study of electromagnetic interference shielding properties of injection molded versus compression molded multi-walled carbon nanotube/polystyrene composites, Carbon 50, p 5126-5134.

Levi N, Czerw R, Xing S, Iyer P, Carroll DL, 2004. Properties of polyvinylidene difluoride− carbon nanotube blends, Nano Letters 4, p 1267-1271.

Bajpai O, Setua D, Chattopadhyay S. 2015. A Brief Overview on Ferrite (Fe3O4) Based Polymeric Nanocomposites: Recent Developments and Challenges, Journal of Research Updates in Polymer Science 3, p 184-204.

Martins P, Lopes A, Lanceros-Mendez S. 2014. Electroactive phases of poly (vinylidene fluoride): determination, processing and applications, Progress in polymer science 39, p 683-706.

Martins P, Costa CM, Botelho G, Lanceros-Mendez S, Barandiaran J, Gutierrez J. 2012. Dielectric and magnetic properties of ferrite/poly (vinylidene fluoride) nanocomposites, Materials Chemistry and Physics 131, p 698-705.

Martins P, Costa CM, Lanceros-Mendez S. 2011. Nucleation of electroactive β-phase poly (vinilidene fluoride) with CoFe2O4 and NiFe2O4 nanofillers: a new method for the preparation of multiferroic nanocomposites, Applied Physics A, 103, p233-237.

Gregorio Jr R, Cestari M. 1994. Effect of crystallization temperature on the crystalline phase content and morphology of poly (vinylidene fluoride), Journal of Polymer Science Part B: Polymer Physics 32, p 859-870.

Begum S, Kausar A, Ullah H, Siddiq M. 2016. Potential of Polyvinylidene Fluoride/Carbon Nanotube Composite in Energy, Electronics, and Membrane Technology: An Overview, Polymer-Plastics Technology and Engineering  55, p 1949-1970.

Zhang S, Zhang N, Huang C, Ren K, Zhang Q. 2005. Microstructure and electromechanical properties of carbon nanotube/poly (vinylidene fluoride—trifluoroethylene—chlorofluoroethylene) composites, Advanced Materials 17, p 1897-1901.

Manna S, Mandal A, Nandi AK. 2010. Fabrication of Nanostructured Poly (3-thiophene methyl acetate) within Poly (vinylidene fluoride) Matrix: New Physical and Conducting Properties,  The Journal of Physical Chemistry B 114, p 2342-2352.

Prabhakaran T, Hemalatha J. 2013.  Ferroelectric and magnetic studies on unpoled Poly (vinylidine Fluoride)/Fe3O4 magnetoelectric nanocomposite structures, Materials Chemistry and Physics 137, p 781-787.

Furukawa T. 1989. Ferroelectric properties of vinylidene fluoride copolymers,”Phase Transitions: A Multinational Journal 18, p 143-211.

Sencadas V, Moreira MV, Lanceros-Méndez S, Pouzada AS, Gregório Filho R. 2006. α-to β Transformation on PVDF films obtained by uniaxial stretch, in Materials science forum p 872-876.

Eerenstein W, Mathur N, Scott JF. 2006.  Multiferroic and magnetoelectric materials, nature 442, p 759.

Zhang WB, Zhang Zx, Yang JH, Huang T, Zhang N, Zheng XT. 2015. Largely enhanced thermal conductivity of poly (vinylidene fluoride)/carbon nanotube composites achieved by adding graphene oxide, Carbon 90, p 242-254.

Gu X, Michaels C, Nguyen D, Jean Y, Martin J, Nguyen T. 2006. Surface and interfacial properties of PVDF/acrylic copolymer blends before and after UV exposure, Applied surface science 252, p 5168-5181.

Wang X, Li W, Luo L, Fang Z, Zhang J, Zhu Y, 2012. High dielectric constant and superparamagnetic polymer‐based nanocomposites induced by percolation effect, Journal of Applied Polymer Science 125, p 2711-2715.

Fu Y, Harvey EC, Ghantasala MK, Spinks G. M. 2005. Design, fabrication and testing of piezoelectric polymer PVDF microactuators, Smart materials and structures 15, p S141.

Liu Z, Feng Y, Li W. 2015. High dielectric constant and low loss of polymeric dielectric composites filled by carbon nanotubes adhering BaTiO3 hybrid particles, RSC Advances  5, p 29017-29021.