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Bioavailability of potentially toxic elements (PTES) in soil from a former industrial site using EDTA/acetic acid

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Research Paper 01/08/2011
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Bioavailability of potentially toxic elements (PTES) in soil from a former industrial site using EDTA/acetic acid

Ikechukwu Alexander Okorie, Chime Charles
Int. J. Biosci.1( 4), 51-62, August 2011.
Certificate: IJB 2011 [Generate Certificate]
Key: Acetic acidEDTAICP-MSPotentially toxic elements analysis

Abstract

Pseudo total Potentially Toxic Elements concentration is a useful guide in evaluating the pollution level in the environment. Samples of soils from a former industrial site have been analysed for potentially toxic elements (Arsenic, Cadmium, Chromium, Copper, Nickel, Lead and Zinc) using EDTA and HOAc. The accuracy of the microwave digestion and ICP-MS analysis was assessed by determination of the elements in a certified reference material (BCR 700). Excellent agreement was obtained in all cases between certified and measured values for the elements investigated. The plant availability estimated using EDTA/AcOH varies across the sampled points. Correlation analysis has been carried out between the pseudo total PTE content and the single extraction using EDTA/HOAc and the results shows significant strong positive correlation between the EDTA/HOAc and the pseudo total concentration for all the PTEs measured. The correlation coefficients between EDTA and HOAc are as follows: – As (0.911), Cd (0.985), Cr (0.844), Cu (0.905), Ni (0.589), Pb (0.891) and Zn (0.816). This implies that both EDTA and HOAc are good for extraction of PTEs in soil.

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Abumaizar RJ, Smith EH. 1999. Heavy metal contaminants removal by soil washing. Journal of Hazardous Material B70, 71 -86.

Bacon JR, Davidson CM. 2008. Is there a future for sequential chemical extraction? The Analyst 133, 25-46.

Baize D. 1993. Soil Science Analyses: A Guide to Current Use. John Wiley & Sons, Chichester UK.

Cai S, Yue L, Hu ZN, Zhong XZ, Ye ZL, Xu HD. 1990. Cadmium exposure and health effects among residents in an irrigation area with ore dressing waste water. Science of the Total Environment 90, 67–73

Callahan MA, Slimak MW, Gabel NW. 1979. Water-Related Environmental Fate of 129 Priority Pollutants, Vol.1, Introduction and Technical Background, Metals and Organics, Pesticides and PCBs. Report to U.S.EPA, Office of Water Planning and Standards, Washington, D.C.

Cameron RE. 1992. Guide to site and soil description for hazardous waste site characterisation. Volume 1 Metals. Environmental Protection Agency EPA/600/491/029

Chaney RL. 1990. Public health and sludge utilization. Biocycle 30, 68 – 73.

Environment Agency. 2002. Soil guidelines values for metal contamination, R&D Publication SGV. Available at: http://www.environment-agency.gov.uk/.

Ge Y, Murray P, Hendershot WH. 2000. Trace metal speciation and bioavailabilty in urban soils. Environmental Pollution 107, 137-144.

Ghanedi M, Shokrollahi A, Kianfar AH, Mirsadeghi AS, Pourfarokhi A, Soylak M. 2008. The determination of some heavy metals in food samples by flame atomic absorption spectrometry after their separation – preconcentration on bis salicyl aldehyde 1, 3 propandiimine (BSPDI) loaded on activated carbon. Journal of Hazardous Material 154, 128 – 134.

Jin T, Nordberg M, Frech W, Dumont X, Bernard A, Ye T. 2002. Cadmium biomonitoring and renal dysfunction among a population environmentally exposed to cadmium from smelting in China (ChinaCad). BioMetals 15, 397– 410.

Jose MA, Luis ML, Jesus N, Ana O, Maria IR. 2006. Comparison of EDTA and Sequential Extraction Tests for Phytoavailability Prediction of Manganese and Zinc in Agricultural alkaline Soils. Geoderma 132, 450-463

Kabata-Pendias A, Mukherjee A B. 2007. Trace elements from soil to humans. Berlin: Springer-Verlag.

Lim TT, Tay JH, Wang JY. 2004. Chelating-agent-enhanced heavy metal extraction from a contaminated acidic soil. Environmental Engineering 130, 59 – 66.

Linn JH, Elliott H A. 1998. Mobilization of copper and zinc in contaminated soil by nitriloacetic acid. Water Air and Soil Pollution 37, 449 -458.

Lucia DT, Murray BM. 1982. Mobility and extractability of cadmium, copper nickel and zinc in organic and mineral soil column. Plant and Soil 134(3), 198-205.

McGrath SP. 1995. Nickel In Heavy metals in soils (2nd edition) (ed B.J Alloway) London. Blackie Academic and Professional Press.

Muhammad KJ, Tasneem GK, Muhammad BA, Hassan IA, Nosrat J, Ghulam AK, Abdul QS, Jameel AB. 2009. Heavy metal accumulation in different varieties of wheat (Triticum aestiyum) grown in soil amended with domestic sewage sludge. Journal of Hazardous Materials 164, 1386 – 1391.

Narwal SB, Salbu B. 1999. Association of cadmium, zinc, copper and nickel with components in naturally heavy metal rich soils studied by parallel and sequential extractions. Communications in Soil Science and Plant analysis 30, 1209-1230.

Peters RW. 1999. Chelant extraction of heavy metals from contaminated soils. Journal of Hazadous Materials 66, 151 – 210.

Perez C B, De Jesus GM, Gomez E.  2002. Comparison of single extraction procedures and the Tessier sequential extraction method for the fractionation of heavy metals from environmental samples. The Analyst 127, 681-688.

Polettini A, Pomi R, Rolle E. 2007. The effect of operating variables on chelant-assisted remediation of contaminated dredged sediment. Chemosphere 66, 866 – 877.

Rauret G. 1997. Extraction procedures for the determination of heavy metals in contaminated soil and sediment. Talanta 46, 449 – 455.

Rauret G, Lopez-Sanchez J, Sahuquillo A, Rubio R, Davidson C, Ure A, Quevauviller P. 1999. Improvement of the BCR three step sequential extraction procedure prior to certification of new sediment and soil reference materials. Journal of Environmental Monitoring 1, 57- 61.

Reddy KJ, Wang L, Gloss S P. 1995. Solubility and mobility of copper, zinc and lead in acidic environment. Plant and Soil 171, 53-58.

Robertson GP, Sollins P, Ellis BG, Lajtha K. 1999. Standard soil methods for long term ecological research: Exchangeable Ions, pH, and Cation Exchange Capacity. in Robertson, G. P., Coleman, D. C., Bledsoe, C. S. Oxford University Press.

Samani Z, Hu S, Hanson AT, Heil DM. 1998. Remediation of lead contaminated soil by column extraction with EDTA. Water Air and Soil Pollution 102, 221 – 238.

Schafer J, Hannker D, Eckhardt DJ, Stuben D. 1998. Uptake of traffic related heavy metals and platinum group elements (PGE) by plants. The Science of the Total Environment 215, 59 – 67.

Schramel O, Michaike B, Kettrup A.  2000. Study of the copper distribution in a column in contaminated soils of hop fields by single and sequential extraction procedures. The Science of the Total Environment 263, 11-22.

Smith LA, Means JL, Chen A, Alleman B, Chapman CC, Tixier JS, Brauning SE, Gasvaskar AR, Royer MD. 1995. Remedial Options for Metals-Contaminated Sites. Lewis Publishers, Boca Raton, Florida.

Strowbel B W, Borggaard O K, Hansen H C B, Andersen M K, Raulund-Rasmussen K. 2005. ‘Dissolved Organic Carbon and Decreasing pH Mobilize Cadmium and Copper in Soil’. European Journal of Soil Science 56, 189-196.

Suave  S,  Hendershot  W,  Allen  HE.  2000. Solid-solution partitioning of metals in contaminated soils. Environmental Science and Technology 34(7), 1125-1131.

Sun B, Zhao FJ, Lombi E, McGrath SP. 2001. Leaching of heavy metals from contaminated soils using EDTA. Environmental Pollution 113, 111- 120.

Tandy S, Bossart K, Mueller R, Ritschel J, Hauser L, Schulin R and Nok B. 2004. Extraction of heavy metals from soils using biodegradable chelating agents. Environmental Science and Technology 38, 937 – 944.

Tessier  A,  Campell  PGC,  Bisson  M.  1979. Sequential extraction procedure for the speciation of particular trace metals. Analytical Chemistry 51, 844– 850.

Walid BA, Noureddine G, Abdelbasset L, Gijs DL, Tahar, G. 2009. Effect of a 5-year application of municipal solid waste compost on the distribution and mobility of heavy metals in a Tunisian calcareous soil. Agri. Eco. Envir. 130, 156-163.

Watanabe T, Zhang ZW, Qu JB, Gao WP, Jian ZK, Shimbo S. 2000. Background lead and cadmium exposure of adult women in Xian City and two farming villages in Shaanxi Province, China. Science of the Total Environment 247, 1– 13.

Weihua Z, Hao H, Fenfang T, Hong W, Rongliang Q. 2009. Influence of EDTA washing on the species and mobility of heavy metals residual in soils. Journal of Hazardous Materials 12, 148-161.

Whalley C, Grant A. 1994. Assessment of the phase selectivity of the European Community Bureau of Reference (BCR) sequential extraction procedure for metals in sediments. Analytica Chimica Acta 291, 287 -295.

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