Comparison removal malachite green and methylene blue from aqueous solutions by new adsorbent prepared from Rosa canina
Paper Details
Comparison removal malachite green and methylene blue from aqueous solutions by new adsorbent prepared from Rosa canina
Abstract
In this research, low cost activated carbon simply was prepared from a local , plenty Rosa canina tree (AC-RC) in sou´wester of Iran. The potential applicability of AC-RC as useful adsorbent for the removal of Malachite Green(MG) and Methylene Blue(MB) from aqueous solutions. The AC-RC with low cost and toxicity with nano size pore diameter as a good adsorbent for removal dyes MG and MB from aqueous media. The effects of different parameters of pH , contact time, agitation time, initial dye concentration and amount of adsorbent AC-RC on removal MG and MB were evaluated. Increase in pH up to 8 for AC-RC , increase the adsorption capacity and reach equilibrium within 40min of contact time for (MB) dye and 45min for(MG) dye. Experimental data was analyzed by four kinetic models including pseudo first ,second-order, Elovich and the intraparticle diffusion equations. The result shows that adsorption of MG and MB onto AC-RC at all conditions such as versatile adsorbent dosages combination of the pseudo second-order equation.experimental data study for isotherm models like Langmuir, Freundlich, Tempkin and Dubinin-Radushkevich and show results , removal MG and MB dyes by AC-RC conformed from Freundlich isotherm. The adsorption capacity of AC-RC from removal of MG and MB was found to be 30.3 and 27.02mg/g. these results show that adsorbent AC-RC as a low cost adsorbent and high strength for removal Dyes from aqueous media.
Pavan FA, Dias SLP, Lima EC, Benvenutti EV. 2008. Removal of congo red from aqueous solution by anilinepropylsilica xerogel. Dyes pigments 76, 64-69. http://dx.doi.org / doi:10.1016/j.dyepig.2006.08.027
Wu FC, Tseng RL. 2006. Prepration of highlyporous carbon from fire wood by KOH etching and CO2 gastification for adsorption of dyes and phenols from water. Journal of Colloid and Interface Science 294, 21-30.
Reza S, Vahid V, Mansur Z, Akram V. 2010. Adsorption of Acid Red 18 (AR18) by Activated Carbon from Poplar Wood: A Kinetic and Equilibrium Study. European Journal of Chemistry 7, 65-72. http://dx.doi.org/10.1155/2010/958073
Gregorio C. 2006. Non-conventional low-cost adsorbents for dye removal: A review, Bioresour. Technol 97, 1061–1085.
Sudipta C, Seong-Rin L, Seung HW. 2010. Removal of Reactive Black 5 by zero-valent iron modified with various surfactants. Chemical engineering Journal 160, 27–32. http://dx.doi.org/10.1016/j.cej.2010.02.045
Han RP, Wnag YF, Han PJ,Yang YS Lu. 2006. Removalofmethyleneblue from aqueous solution by chaffin batch mode. Journal of Hazardous Materials 137, 550–557.
Zhang J, Zhang YLC, Jing Y. 2008. Bisorption of malachite green from aqueous solutions by pleurotus ostreatus using Taguchi method. Journal of Hazardous Materials 150,774-782.
Mittal A. 2006. Adsorption kinetics of removal of a toxic dye, malachite green, from wastewater by using hen feathers. Journal of Hazardous Materials 133, 196-202. http://dx.doi.org/10.1016/j.jhazmat.2005.10.017
Culps SJ, Blankeship LR, Kusewitt DF, Doerge DR, Mulligan LT, Beland FA. 1999. Toxicity and metabolism of malachite green and leucomalachitegreen during short-term feeding to Fischer 344 rats and B6C3F (1) mice. Chemico-Biological Interactions 122(3), 153-170. http://dx.doi.org/10.1016/S0009-2797 (99)00119-2
Singh S, Das M, Khaana SK. 1994. Biodegradation of malachite green and Rhodamine-B by cecal microflora of rats. Biochemical and Biophysical Research Communications 200(3), 1544-1550.
Gupta VK, Ali I, Saini VK. 2004. Removal of Rhodamine B, fast green and methylene blue from wastewater using red mud, an aluminium industry waste. Industrial & Engineering Chemistry Research 43, 1740-1747. http://dx.doi.org/ 10.1021/ie034218g
Beridou C, Poulios I, Xekoukoulotakis NP, Mantzavinos D. 2007. Sonolytic, photocatalytic and sonophotocatalytic degradationof malachite green in aqueous solutions . Applied Catalysis A B74, 63-72. http://dx.doi.org/ 10.1016/j.apcatb.2007.01.013
Ghaedi M, Nejati Biyareh M, Nasiri Kokhdan S, Shamsaldini H, Sahraei R, Daneshfar A, Shahriyar S. 2012. Comparison of the efficiency of palladium and silver nanoparticles loaded on activated carbon and zinc oxide nanorods loaded on activated carbon as new adsorbents for removal of Congo red from aqueous solution:Kinetic and isothermstudy. Master of Science in Engineering C32 (4), 725-734.
Ghaedi M, Hossainian H, Montazerozohori M, Shokrollahi A, Shojaipour F, Soylak M, Purkiat M. 2011. A novel acon based adsorbent for the removal of brilliant green. Desalination 281, 226-234. http://dx.doi.org/10.1016/j.desal.2011.07.068
Ghaedi M, Sadeghian B, Amiri Pedani A, Sahraei A, Daneshfar A, Duran C.2012. Kinetics, thermodynamic and equilibrium evaluation of direct yellow 12 removals onto silver nanoparticles loaded activated carbon. Chemical engineering Journal 187,133-141.
Yang LiW,Peng K,Zhang J,Guo L,Xia S. 2008. Effects of carbonization temperatures on characteristics of porosity in cocounat shell chars and activated carbons derived from carbonized coconut shell chars. Industrial Crops and Products 28, 190-198. http://dx.doi.org/10.1016/j.indcrop.2008.02.012
Ghaedi M,Tavallali H, Sharifi M,Nasiri Kokhdan S, Asghari A. 2012. Preparation of low cost activated carbon from Myrtus communis and pomegranate and their efficient application for removal of Congo red from aqueous solution Spectrochimi. Acta Crystallographica 86, 107– 114.
Pan XL, Zhang D. 2009. Removal of malachite green from water by Firmiana simplex wood fiber. Electronic Journal of Biotechnology 12 . http://dx.doi.org/10.2225/vol12-issue4-fulltext-4
Jabbar Z, Angham A, Hadi Ferdoos G, Sami. 2014. Removal of azo dye from aqueous solutions using chitosan. Oriental Journal of Chemistry 30, 571-575.
Apple M, Jackson MA. 2007. Sorption of ochratoxin a from aqueous solutions using cyclodextrin-polyurethane polymer. Technology 53, 97-110. http://dx.doi.org/10.1.1.270.813
Tuzen M, Soylak M. 2007. Multiwalled carbon nanotubes for speciation of chromium in environmental samples. Journal of Hazardous Materials147, 219-225. http://dx.doi.org/10.1016/j.jhazmat.2006.12.069
Dubinin MM. 1960. The potential theory of adsorption of gases and vapors for adsorbents with energetically nonuniform surfaces. Chemical Reviews 60, 235-241.
Alkan M, Dogan M, Turhan Y, Demirbas O, Turan P. 2008. Adsorption Kinetics and Mechanism of Maxilon Blue 5G Dye on Sepiolite from Aqueous Solutions. Chemical engineering Journal 139, 213-223.
Dogan M, Alkan M, Demirbas O, Ozdemir Y, Ozmetin C. 2006. Adsorption Kinetics of Maxilon Blue GRL onto Sepiolite from Aqueous Solutions. Chemical engineering Journal 124, 89-101. http://dx.doi.org/10.1016/j.cej.2006.08.016
Dubinin MM. 1960. The potential theory of adsorption of gases and vapors for adsorbents with energetically nonuniform surfaces. Chemical Reviews 60, 235. http://dx.doi.org/10.1021/cr60204a006
Dubinin MM, Fiz ZH. 1965. Equilibrium modeling, kinetic and thermodynamic study. Chim 39, 1305-1317.
Maryam Tavakol, Parviz Aberoomand Azar, Mehrorang Ghaedi, Mohammad Saber Tehrani, 2014. Comparison removal malachite green and methylene blue from aqueous solutions by new adsorbent prepared from Rosa canina. J. Biodiv. Environ. Sci., 5(3), 177-201.
Copyright © 2014 by the Authors. This article is an open access article and distributed under the terms and conditions of the Creative Commons Attribution 4.0 (CC BY 4.0) license.