Development of Cu-Fe loaded activated porous carbon (CuFe2O4/AC nanocomposite) using sugarcane bagasse for photodegradation, antimicrobial activity and dye adsorption by batch kinetic studies

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Research Paper 05/07/2024
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Development of Cu-Fe loaded activated porous carbon (CuFe2O4/AC nanocomposite) using sugarcane bagasse for photodegradation, antimicrobial activity and dye adsorption by batch kinetic studies

T. Madhumitha, M. Margret Leema, E. Amutha, E. Pushpalakshmi, M. Earnest Stephen Gnanadoss, S. Rajaduraipandian, G. Annadurai
J. Bio. Env. Sci.25( 1), 10-25, July 2024.
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Abstract

A novel hydrothermal method has been utilized to synthesize Cu Fe2O4/AC Nanocomposite that avoids any usage of surfactants. Wherein, Cu Fe2O4/AC Nanoparticle was synthesized in the temperature range between 120 to 180°C by hydrothermal method and results a greater reproducibility. The synthesized Cu Fe2O4/AC Nanocomposite  and Characterized by SEM, XRD, FTIR, TGA, Cyclic Voltammetry (CV), Electrostatic Impedance Spectroscopy (EIS), Electrostatic impedance spectroscopy (EIS) studies. Studies on the antibacterial activity and photocatalytic degradation of a chemically generated Cu Fe2O4/AC nanocomposite were also carried out. The Kinetic model better fits the experimental findings of the Cu Fe2O4/AC Nanocomposite. The kinetic adsorption results were studied using pseudo-first- and pseudo-second-order models. The second-order models primarily regulated the adsorption rate and exhibited a high correlation coefficient (R2 > 0.99). Cu Fe2O4/AC Nanocomposite usually absorbs anions during the adsorption process of Methylene blue because, at acidic pH values, an increase in positively charged regions creates attractive electrostatic forces.  The results of this investigation demonstrate that the Cu Fe2O4/AC Nanocomposite effectively extracts the Methylene blue dye from the aqueous solution; hence, the Cu Fe2O4/AC Nanocomposite exhibits a low rate of degradation during repeated use.

VIEWS 69

Abdelwahab NA, Shukry N. 2014. Synthesis, characterization and antimicrobial properties of grafted sugarcane bagasse/silver nanocomposites. Carbohydrate Polymers 115, 276-284.

Ahmed S, Ahmad M, Swami BL, Ikram S. 2016. A review on plants extract mediated synthesis of silver nanoparticles for antimicrobial applications: a green expertise. Journal of Advanced Research 7(1), 17-28.

Ahn CH, Choi JW, Cho HJ. 2004. Encyclopedia of Nanoscience and Nanotechnology; Nalwa, H.S., Ed.; American Scientific Publishers: Stevenson Ranch, CA, USA. 6, 815.

Amit K, Changsheng G, Gaurav S, Deepak P, Mu N, Susheel KPD. 2016. Magnetically recoverable ZrO2/Fe3O4/chitosan nanomaterials for enhanced sunlight driven photoreduction of carcinogenic Cr(VI) and dechlorination & mineralization of 4-chlorophenol from simulated wastewater. RSC Advances 6, 13251-13263.

Ansari R, Mosayebzadeh Z. 2010. Removal of basic dye methylene blue from aqueous solutions using sawdust and sawdust coated with polypyrrole. Journal of the Iranian Chemical Society 7, 339-350.

Arun M, Panicker K, Rajesh T, Varghese O. 2017. Mixed morphology nanocrystalline cellulose from sugarcane bagasse fibers/poly(lactic acid) nanocomposite films: synthesis, fabrication and characterization. Iranian Polymer Journal 25, 125-136.

Bello OS, Adelaide OM, Hammed MA, Popoola OAM. 2010. Kinetic and equilibrium studies of methylene blue removal from aqueous solution by adsorption on treated sawdust. Macedonian Journal of Chemistry and Engineering 29, 77-85.

Benaissa H. 2005. Removal of acid dyes from aqueous solutions using orange peel as a sorbent material. Ninth International Water Technology Conference, IWTC9, Sharm El-Sheikh, Egypt. 1175-1185.

Bharathi KS, Ramesh ST. 2013. Removal of dyes using agricultural waste as low-cost adsorbents: a review. Applied Water Science 3, 773-790.

Boudrahem F, Soualah A, Aissani-Benissad F. 2011. Pb(II) and Cd(II) removal from aqueous solutions using activated carbon developed from coffee residue activated with phosphoric acid and zinc chloride. Journal of Chemical Engineering Data 56, 1946-1955.

Choi JH. 2010. Fabrication of a carbon electrode using activated carbon powder and application to the capacitive deionization process. Separation and Purification Technology 70, 362-366.

Crini G, Peindy HN. 2006. Adsorption of CI. Basic Blue 9 on cyclodextrin-based material containing carboxylic groups. Dyes and Pigments 70, 204-211.

Dogan M, Alkan M. 2003. Adsorption kinetics of methyl violet onto perlite. Chemosphere 50(4), 517-528.

Fang L, Zu X, Liu C, Li Z, Peleckis G, Zhu S, Liu H, Wang L. 2010. Microstructure and magnetic properties in Sn1−xFexO2 (x = 0.01, 0.05, 0.10) nanoparticles synthesized by hydrothermal method. Journal of Alloys and Compounds 491(1-2), 679-683.

Garg VK, Rakesh K, Renuka G. 2004. Removal of Malachite green dye from aqueous solution by adsorption using agro-industry waste: a case study of Prosopis cineraria. Dyes and Pigments 62, 1-10.

Gokce Y, Aktas Z. 2014. Nitric acid modification of activated carbon produced from waste tea and adsorption of methylene blue and phenol. Applied Surface Science 313, 352-359.

Goldberg M, Langer R, Jia X. 2007. Nanostructured materials for applications in drug delivery and tissue engineering. Journal of Biomaterials Science, Polymer Edition 18, 241-268.

Gregorio C. 2008. Kinetic and equilibrium studies on the removal of cationic dyes from aqueous solution by adsorption onto a cyclodextrin polymer. Dyes and Pigments 77, 415-426.

Han Z, Dong Y, Dong S. 2011. Copper-iron bimetal modifies PAN fiber complexes as novel heterogeneous Fenton catalyst for the degradation of organic dye under visible light irradiation. Journal of Hazardous Materials 189, 241-248.

Hema M, Arivoli S. 2007. Comparative study on the adsorption kinetics and thermodynamics of dyes onto acid activated low cost carbon. International Journal of Physical Sciences 2, 10-17.

Ho YS, McKay G. 1998a. Kinetic models for the sorption of dye from aqueous solution by wood. Process Safety and Environmental Protection 76, 183-191.

Ho YS, McKay G. 1998b. Sorption of dye from aqueous solution by peat. Chemical Engineering Journal 70, 115-124.

Ho YS, McKay G. 1999. A kinetic study of dye sorption by biosorbent waste product pith. Resources Conservation Recycling 25, 171-193.

Huang W, Zhang Y, Bao S, Cruz R, Song S. 2014. Desalination by capacitive deionization process using nitric acid-modified activated carbon as the electrodes. Desalination 340, 67-72.

Jin X, Liang Y, Wang J, Wang Q, Wu Y, Chong WWF, Sonne C, Lam SS, Xia C. 2023. Hierarchical self-assembly of polyphenolic functionalized magnetic superstructure for enhanced removal of organic dyes. Journal of Chemical Engineering 457, 141142.

Khenniche L, Benissad-Aissani F. 2010. Adsorptive removal of phenol by coffee residue activated carbon and commercial activated carbon: equilibrium, kinetics, and thermodynamics. Journal of Chemical Engineering Data 55, 4677-4686.

Liu QS, Zheng T, Li N, Wang P, Abulikemu G. 2010. Modification of bamboo-based activated carbon using microwave radiation and its effects on the adsorption of methylene blue. Applied Surface Science 256, 3309-3315.

Low KS, Lee CK. 1990. The removal of cationic dyes using coconut husk as an adsorbent. Pertanika 132, 221-228.

Lozano-Castello D, Lillo-R.Odenas M, Cazorla-Amorós D, Linares-Solano A. 2001. Preparation of activated carbons from Spanish anthracite: I. Activation by KOH. Carbon 39, 741-749.

Mall ID, Srivastava VC, Kumar GV, Mishra IM. 2006. Characterization and utilization of mesoporous fertilizer plant waste carbon for adsorptive removal of dyes from aqueous solution. Colloids and Surfaces A 278(1-3), 175-187.

Mi J, Wang XR, Fan RJ, Qu WH, Li WC. 2012. Coconut-shell-based porous carbons with a tunable micro/mesopore ratio for high-performance supercapacitors. Energy and Fuels 26, 5321-5329.

Mohanty K, Naidu JT, Meikap BC, Biswas MN. 2006. Removal of crystal violet from wastewater by activated carbons prepared from rice husk. Industrial & Engineering Chemistry Research 45, 5165-5171.

Namasivayam C, Kavitha D. 2002. Removal of Congo Red from water by adsorption onto activated carbon prepared from coir pith, an agricultural solid waste. Dyes and Pigments 54(1), 47-58.

Namasivayam C, Muniasamy N, Gayatri K, Rani M, Ranganathan K. 1996. Removal of dyes from aqueous solutions by cellulosic waste orange peel. Bioresource Technology 57(1), 37-43.

Namasivayam C, Prabha D, Kumutha M. 1998. Removal of direct red and acid brilliant blue by adsorption on to banana pith. Bioresource Technology 64(1), 77-79.

Namasivayam C, Radhika R, Subha S. 2001. Uptake of dyes by a promising locally available agricultural solid waste: Coir pith. Waste Management 38, 381-387.

Oladoja NA, Aboluwoye CO, Oladimeji YB. 2008. Kinetics and isotherm studies on methylene blue adsorption onto ground palm kernel coat. Turkish Journal of Engineering and Environmental Science 32, 303-312.

Onal Y, Akmil-Basar C, Eren D, SarIcI-Ozdemir C, Depci T. 2006. Adsorption kinetics of Malachite green onto activated carbon prepared from Tunc¸bilek lignite. Journal of Hazardous Materials 128, 150-155.

Onundi YB, Mamun AA, Khatib MFA, Ahmed YM. 2010. Adsorption of copper, nickel and lead ions from synthetic semiconductor industrial wastewater by palm shell activated carbon. International Journal of Environmental Science and Technology 7, 751-758.

Ozcan A, O¨meroglu C, Erdogan Y, Ozcan AS. 2007. Modification of bentonite with a cationic surfactant: an adsorption study of textile dye Reactive Blue 19. Journal of Hazardous Materials 140, 173-179.

Piyush K, Yun Z, Najia M, Ujwal KT, Benjamin DW, Ryan K, Karthik S. 2018. Heterojunctions of mixed phase TiO2 nanotubes with Cu, CuPt, and Pt nanoparticles: interfacial band alignment and visible light photoelectrochemical activity. Nanotechnology 29, 014002.

Prodyut D, Bruna P, Antonio J, Gonçalves C, Sandip B, Sakamoto S, Imai HJ, Shiraishi Y, Tanaka S, Ichikawa S, Hirai T. 2019. Photocatalytic dehalogenation of aromatic halides on Ta2O5-supported Pt–Pd bimetallic alloy nanoparticles activated by visible light. ACS Catalysis 7, 5194-5201.

Radovic LR, Silva IF, Ume JI, Menendez JA, Leon CA, Leon Y, Scaroni AW. 1997. An experimental and theoretical study of the adsorption of aromatics possessing electron withdrawing and electron-donating functional groups by chemically modified activated carbons. Carbon 35, 1339-1348.

Rivera-Utrilla J, Bautista-Toledo I, Ferro-Garcia MA, Moreno-Castilla C. 2001. Activated carbon surface modifications by adsorption of bacteria and their effect on aqueous lead adsorption. Journal of Chemical Technology and Biotechnology 76(12), 1209-1215.

Salleh MAM, Mahmoud DK, Karim WAWA, Idris A. 2011. Cationic and anionic dye adsorption by agricultural solid wastes: a comprehensive review. Desalination 280, 1-13.

Sarasidis VC, Plakas KV, Karabelas AJ. 2017. Novel water-purification hybrid processes involving in-situ regenerated activated carbon, membrane separation and advanced oxidation. Journal of Chemical Engineering 328, 1153-1163.

Sawant SY, Munusamy K, Somani RS, John M, Newalkar BL, Bajaj HC. 2017. Precursor suitability and pilot scale production of super activated carbon for greenhouse gas adsorption and fuel gas storage. Journal of Chemical Engineering 315, 415-425.

Sekirifa ML, Hadj-Mahammed M, Pallier S, Baameur L, Richard D, Al-Dujaili AH. 2013. Preparation and characterization of an activated carbon from a date stones variety by physical activation with carbon dioxide. Journal of Analytical and Applied Pyrolysis 99, 155-160.

Senthilkumaar S, Kalaamani P, Subburaam CV. 2006. Liquid phase adsorption of crystal violet onto activated carbons derived from male flowers of coconut tree. Journal of Hazardous Materials 136, 800-808.

Sumanjit K, Seema R, Rakesh KM. 2013. Adsorption kinetics for the removal of hazardous dye Congo red by biowaste materials as adsorbents. Journal of Chemistry 628582, 1-12.

Taer E. 2019. Preparation of activated carbon electrode from pineapple crown waste for supercapacitor application. International Journal of Electrochemical Science 14, 2462-2475.

Zawani Z, Luqman Chuah A, Choong TSY. 2009. Equilibrium, kinetics and thermodynamic studies: adsorption of Remazol black 5 on the palm kernel shell activated carbon PKS-AC. European Journal of Science Research 37, 67-76.

Zhou J, Luo A, Zhao Y. 2018. Preparation and characterisation of activated carbon from waste tea by physical activation using steam. Journal of the Air and Waste Management Association 68, 1269-1277.