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Eco-friendly method for the estimation of cobalt (II) in real samples using 1-(2-Thiazolylazo)-2-naphthol

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Research Paper 01/07/2019
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Eco-friendly method for the estimation of cobalt (II) in real samples using 1-(2-Thiazolylazo)-2-naphthol

Muhammad Bachal Korai, Ghulam Abbas Shar, Gul Afshan Soomro, Nisar Abbas Shar, Rafique Abbas Shar
J. Bio. Env. Sci.15( 1), 12-21, July 2019.
Certificate: JBES 2019 [Generate Certificate]
Key: 1-(2-Thiazolylazo)-2-naphthol (TAN)Cetyltrimethylammonium bromideCobaltMicellar

Abstract

An easy and quick spectrophotometric method is developed for the investigation of cobalt at trace level using 1-(2-Thiazolylazo)-2-naphthol (TAN) in presence of surfactant cetyltrimethylammonium bromide (CTAB) aqueous micellar solution. The cobalt forms bis [1-(2-Thiazolylazo)-2-naphthol] cobalt complex reacting with 1-(2-Thiazolylazo)-2-naphthol. Proposed method is of great importance because use of micellar system instead of solvent extraction steps that were toxic, expensive and time consuming. The method shows improved sensitivity, selectivity and molar absorption. The coefficient of molar absorption and Sandell’s sensitivity was found to be ε 1.89 × 104L mol-1 cm-1 and 3.1ngcm-2 at λmax 572.7nm. Graph of Linear concentration calibration was obtained in the range 0.02-9.0μgmL-1; stoichiometric metal ligand ratio was found 1:2 for the complex Co-[TAN]2 formation. The proposed method was applied for the investigation of cobalt from different alloys, biological, environmental and pharmaceutical samples.

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Afifi SY, Ghonaim AK, Atia BMM, Aly HF. 2014. Extraction and spectrophotometric determination of cobalt using 1,5-diphenylthiocarbazone (dithizone) and its application on geologic samples. Arab Journal of Nuclear Science and Applications 47(1), 61-64.

Amin AS. 2014. Study on the solid phase extraction and spectrophotometric determination of cobalt with 5-(2-benzothiazolylazo)-8-hydroxyquinolene. Arabian Journal of Chemistry 7(5), 715-721.

Andres MPS, MarinamL, Vera S. 1994. Spectrophotometric determination of copper (II), nickel (II), and cobalt (II) as complexes with sodium diethyldithiocarbamate in cationic micellar medium of hexadecyltrimethylammonium salts. Talanta 41(2), 179-185.

Bhattacharya PT, Misra SR, Hussain M. 2016. Nutritional Aspects of Essential Trace Elements in Oral Health and Disease: An Extensive Review. Scientifica 2016, 1-12.

Chandramouleeswarn S, Ram Kumar J. 2014. Speciation studies of cobalt (II) and cobalt (III) and its application to sample analysis. Indian Journal of Advances in Chemical Science 2(2), 134-139.

Cherdantsevaa EV, Nesterovaa AV, Materna AI, Buldakovab LY, Yanchenkob MY, Ishmetovac RI, Rusinov GL. 2010. On the composition of copper (II), cobalt (II), and nickel (II) complexes with some 3,6-disubstituted 1,2,4,5-tetrazines. Russian Journal of General Chemistry 80(9), 1860-1863.

Czarnek K, Terpiłowska S, Siwicki AK. 2015. Review paper Selected aspects of the action of cobalt ions in the human body. Central European Journal of Immunology 2, 236-242.

DaAntonio SM, Katz SA, Scheiner DM, Wood JD. 1982. Anatomically- related variations in trace metal concentrations in hair. Clinical Chemistry 28(12), 2411-2413.

Devi VSA, Reddy VK. 2012. Spectrophotometric Determination of Iron(II) and Cobalt(II) by Direct, Derivative, and Simultaneous Methods Using 2-Hydroxy-1-Naphthaldehyde-p-Hydroxybenzoichydrazone. International Journal of Analytical Chemistry 2012, 1-12.

Dogan Uluozlu O, Tuzen M, Mendil D, Soylak M. 2007. Trace metal content in nine species of fish from the Black and Aegean Seas, Turkey. Food Chemistry 104, 835-840.

Drozd A, Leonova N. 2014. Spectrometric determination of Ni2+, Co3+, Fe2+, Cu2+ concentration with 1-(2-pyridylazo)-2-naphthol in aqueous-micellar medium based on two intensive parameters. Chemistry & Chemical Technology 8(2), 129-134.

El Sheikh R, Gouda AA, El Sayed HA, Al Amin EM. 2015. Cloud point extraction, preconcentration and spectrophotometric determination of cobalt in water samples. International Journal of Pharmacy and Pharmaceutical Sciences 7(9), 213-221.

Ferreira SLC, Nano RMW. 1994. Use of 1-(2-thiazolylazo) 2-naphthol in rapid determination of iron in geological matrices. Talanta 41(11), 1937-1941.

Fornea V, Trupina S, Iosub AV, Bulgariu L. 2016. Spectrometric determination of Cu (II), Co (II) and Ni (II) ions in mono and multi-component systems. Buletinul Institutului Politehnic Din Iaşi 62(2), 9-20.

Ghali AA. 2014. Spectrophotometric Determination of Cobalt (II) Using 4-(6-Bromo 2-benzothiazolylazo) Orcinol as an Organic Reagent. Iraqi National Journal of Chemistry (53), 11-19.

Guzar SH, Jin QH. 2008. Simple, selective, and sensitive spectrophotometric method for determination of trace amounts of nickel (II), copper (II), cobalt (II), and iron (III) with a novel reagent 2-pyridine carboxaldehyde isonicotinyl hydrazone. Chem. Res. Chinese Universities 24(2), 143-147.

Hosseinzadeh R, Gheshlagi M. 2009. Interaction and micellar solubilization of diclofenac with cetyltrimethylammonium bromide: a spectrophotometric study. Collection of Czechoslovak Chemical Communications 74(3), 503-513.

Hosseinzadeh R, Khorsandi K, Hemmaty S. 2013. Study of the effect of surfactants on extraction and determination of polyphenolic compounds and antioxidant capacity of fruits extracts. PLoS ONE 8(3), 1-7.

Hussein FA, Hatam SR, Shaheed MI. 2016. Spectrophotometric Study for Determination of Cobalt (II) by the Reagent [2-(4-Methoxyphenyl) Azo (4, 5-Dipheny Imidazole)](MPAI). International Journal of Pharmacy And Pharmaceutical Research 6(4), 671-683.

Jain KNP, Memon IR. 2017. Complexation of Co (II) and Spectrophotometric Determination of the complex using 5-Nitrosalicylaldehyde semicarbazone (NSS) as an Analytical Reagent. International Journal of Emerging Trends in Science and Technology 4(2), 4970-4973.

Jayanna BK, Nagendrappa G, Gowda N. 2010. A facile spectrophotometric method for the determination of cobalt (II) using iodine monochloride reagent. E-Journal of Chemistry 7(4), 1426-1434.

Ketola A. 2016. Determination of surfactants in industrial waters of paper and board mills. Master’s Thesis, University of Jyväskylä.

Khadem M, Golbabaei F, Froushani AR, Shahtaheri SJ. 2010. Optimization of solid phase extraction for trace determination of cobalt(II) using chromosorb 102 in biological monitoring. International Journal of Occupational Hygiene 2(1), 10-16.

Khammas ZAA. 2009. Recent trends for separation and preconcentration in metal ions and organic compounds analysis after clould-point methodology: Developments and analytical applications – A review. Eurasian Journal of Chemistry 4(1), 1-35.

Korai MB. 2019. Spectrophotometer Determination of cobalt, nickel, iron, copper and zinc using 1-(2-Thiazolylazo)-2-Naphthol in Micellar Media. PhD. Thesis, Shah Abdul Latif University Khairpur, Sindh, Pakistan.

Mallah, A, Memon SQ, Solangi AR, Memon N, Abbasi K, Khuhawar MY. 2012. A novel micellar electrokinetic chromatographic method for separation of metal-DDTC complexes. The Scientific World Journal 2012, Article ID 743407, 1-8.

Mehra R, Juneja M. 2005. Fingernails as biological indices of metal exposure. Journal of Biosciences 30(2), 253-257.

Naeemullah, Kazi, TG, Shah F, Afridi HI, Khan S, Arian SS, Brahman KD. 2012. A Green Preconcentration Method for Determination of Cobalt and Lead in Fresh Surface and Waste Water Samples Prior to Flame Atomic Absorption Spectrometry. Journal of Analytical Methods in Chemistry 2012, 1-8.

Nekouei F, Nekouei S. 2014. Determination of copper, nickel and cobalt in water and food samples by FAAS after separation and preconcentration using multiwall carbon nanotubes modified by methyl-(2-pyridyl) ketone oxime. Indian Journal of Scientific Research 8(1), 138-145.

Niazi A, Yazdanipour A. 2008. Simultaneous spectrophotometric determination of cobalt, copper and nickel using 1-(2-thiazolylazo)-2-naphthol by chemometrics methods. Chinese Chemical Letters 19(7), 860-864.

Olkowska E, Polkowska Z, Namiesnik J. 2012. Analytical procedures for the determination of surfactants in environmental samples. Talanta 88 (2012), 1-13.

Patil YK, Lokhande RS, Rana PK, Janwadkar SP, Patil CY. 2016. Extractive spectrometric determination of copper (II) by using 2-hydroxy-3-methoxy benzaldehyde thiosemicarbazone as an analytical reagent. World Journal of Pharmacy and Pharmaceutical Sciences 5(2), 965-970.

Perrin DD. 2012. Buffers for pH and Metal ion Control: Springer science & business media.

Prashanth L, Kattapagari KK, Chitturi RT, Baddam VRR, Prasad LK. 2015. A review on role of essential trace elements in health and disease. Journal of Dr. NTR University of Health Sciences 4(2), 75-85.

Rajni R, Usha G. 2012. Simultaneous determination of Zinc(II) and Cobalt(II) by first order derivative spectrophotometry in Triton X-100 micellar media. Research Journal of Chemical Sciences 2(11), 8-13.

Raju MM, Rao VT, Ramakrishna K. 2013. Direct and derivative spectrophotometric determination of cobalt (II) using 3,4-dihydroxybenzaldehyde-1-(3chloro-2 quinoxalinyl) hydrazone (DHBCQH) in presence of micelle medium. International Journal of Scientific and Research Publications 3(4), 1-10.

Reddy KNP, Reddy TG, Kumar DS, Reddy AVR, Parveen NS, Reddy GCN. 2016. A new hydrazone derivative as a sensitive analytical reagent for the determination of Co(II) in food, water and synthetic samples. International Journal of Pharmaceutical Sciences and Research 7(1), 153-162.

Reddy KV, Reddy DN, Reddy KH. 2011. Derivative spectrophotometric determination of cobalt (II) and nickel (II) using 2-acetylpyridine-4-methyl-3-thiosemicarbazone (APMT). Journal of Chemical and Pharmaceutical Research 3, 835-839.

Scharf B, Clement CC, Zolla V, Perino G, Yan B, Elci SG, Santambrogio L. 2014. Molecular analysis of chromium and cobalt-related toxicity. Scientific Reports 4(1), 1-12.

Shar GA, Soomro GA. 2014. A simple spectrophotometric method for the determination of copper (II) using 1-nitroso-2-naphthol as complexing agent in micellar solution of sodium dodecyl sulphate. International Journal of Research in Chemistry and Environment 4(3), 169-176.

Singh R, Gautam N, Mishra A, Gupta R. 2011. Heavy metals and living systems: An overview. Indian Journal of Pharmacology 43(3), 246-253.

Soomro GA, Shar GA. 2014. A simple spectrophotometric method for the determination of cobalt (II) using 1-nitroso-2-naphthol in anionic aqueous solution of sodium dodecyl sulphate. International Journal of Chemical Sciences 12(3), 982-992.

Soomro GA, Shar GA. 2015. Spectrophotometric determination of copper(II) using 1-(2- pyridylazo)-2-naphthol in micellar solution of cetyltrimethyl ammonium bromide. Asian Journal of Chemistry 27(4), 1361-1364.

Teng TT, Yusup Y, Low LW. 2012. Heavy metal ion extraction using organic solvents: An application of the equilibrium slope method, stoichiometry and research. The importance of quantity in biomedicine. Dr. ALESSIO INNOCENTI (Ed.), InTech. March.

Wani AB, Singh J, Upadhyay N. 2017. Synthesis and characterization of transition metal complexes of para-aminosalicylic acid with evaluation of their antioxidant activities. Oriental Journal of Chemistry 33(3), 1120-1126.

Zoubi WA. 2013. Solvent extraction of metal ions by use of Schiff bases. Journal of Coordination Chemistry 66(13), 2264-2289.

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