Enhancing biogas quality: An experimental investigation of CO2 and H2S removal techniques

Paper Details

Research Paper 08/06/2024
Views (61) Download (9)
current_issue_feature_image
publication_file

Enhancing biogas quality: An experimental investigation of CO2 and H2S removal techniques

Dianne Mae M. Asiñero, Antonio-Abdu Sami M. Magomnang
Int. J. Biosci.24( 6), 114-122, June 2024.
Certificate: IJB 2024 [Generate Certificate]

Abstract

The increasing demand for sustainable energy sources has brought biogas into focus as a promising alternative to fossil fuels. However, impurities like carbon dioxide (CO2) and hydrogen sulfide (H2S) in biogas pose challenges to its effective utilization. This study aimed to design a purification system to decrease these impurities, evaluating the efficacy of conventional methods (iron sponge and water scrubbing) and alternative approaches (activated carbon and NaOH solution) in removing CO2 and H2S from biogas. The experimental setup involved integrating the purification system with an anaerobic digester producing raw biogas from swine manure. The concentrations of CH4, CO2, and H2S were measured before and after passing through the purification chambers. Although no H2S was detected in the raw biogas, the study focused on CO2 removal. Results showed that the activated carbon scrubber significantly reduced CO2 levels from 35% to 20% after a 60-minute retention time. The NaOH solution demonstrated excellent CO2 removal efficiency of 86.27%, while the water scrubber achieved only 8.98% efficiency. Both the iron sponge and water scrubber modestly increased the CH4 concentration by 1.9% and 1.7%, after 15 minutes. However, the NaOH solution yielded a more substantial 6.6% increase in CH4 concentration. This study highlights the potential of alternative methods like activated carbon and NaOH solution for effective biogas purification, particularly in removing CO2 impurities and enriching the methane content, promoting sustainable energy solutions.

VIEWS 13

Abatzoglou N, Boivin S. 2009. A review of biogas purification processes. Biofuels Bioproducts and Biorefining 3(1), 42-71. https://doi.org/10.1002/bbb.117

Acharya S, Bajinath TG, Sasidhar G, Gupta S. 2021. A comparative study of biogas purification through various methods and its energy application. Sustainable Energy Technologies and Assessments 48, 101615. https://doi.org/10.1016/j.seta.2021.101615

Aghbashlo M, Hosseinpour S, Tabatabaei M, Dadak A. 2021. Biogas upgrade to biomethane by applying physical absorption, biological and chemical techniques: opportunities and challenges. Fuel 298, 120831. https://doi.org/10.1016/j.fuel.2021.120831

Andriani D, Wresta A, Atmaja TD, Saepudin A. 2014. A review on optimization production and upgrading biogas through CO2 removal using various techniques. Applied Biochemistry and Biotechnology 172(4), 1909-1928. https://doi.org/10.1007/s12010-013-0652-x

Awe OW, Zhao Y, Nzihou A, Minh DP, Lyczko N. 2017. A review of biogas utilisation, purification and upgrading technologies. Waste and Biomass Valorization 8(2), 267-283. https://doi.org/10.1007/s12649-016-9826-4

Bari S. 1996. Effect of carbon dioxide on the performance of biogas/diesel duel-fuel engine. Renewable Energy 9(1-4), 1007-1010. https://doi.org/10.1016/0960-1481(96)88436-5

Bauer F, Hulteberg C, Persson T, Tamm D. 2013. Biogas upgrading–Review of commercial technologies. Biofuels 18(2), 1-16. DOI: https://doi.org/10.18331/BF2013.0207

Bhargava D, Purohit J, Gundavarapu S, Mishra R. 2022. Systematic study and analysis of CO2 capture using advanced materials and techniques. Environmental Science and Pollution Research 29(14), 20423-20452. https://doi.org/10.1007/s11356-022-18905-0

Choudhury AA, Rahman MM, Choi BC. 2019. Biogas purification utilizing thermal swing adsorption with a metal–organic framework. ACS Omega 4(19), 18157-18169. https://doi.org/10.1021/acsomega.9b02535

Cristiano G, Petrone AM, Reda R, Tesser R, Perego C. 2020. Nanoiron based adsorbents for biogas desulfurization. Renewable Energy 161, 892-898. https://doi.org/10.1016/j.renene.2020.07.109

Deng Y, Liu J, Zhang J, Gao H, Dong F. 2020. Biogas conversion to methane-rich gas using pressure swing adsorption. Energy & Fuels 34(4), 4279-4287. https://doi.org/10.1021/acs.energyfuels.0c00142

Dorman DC. 2010. Toxicology, occupational. In: Cornell RG, Hay WP, Buck WB, Harari J, editors. Clinical Veterinary Advisor (Elsevier) 1103-1106

Gao H, Liu K, Xu J, Zhou D, Ge X, Hong X. 2020. Biogas upgrading using water scrubbing: A review of CO2 removal and pollution control strategies. Environmental Science and Pollution Research 27(31), 38459-38480. https://doi.org/10.1007/s11356-020-10129-x

Islamiyah S, Ihsanawati I, Herdiansyah H. 2014. Biogas purification performance of a double-stage bubble column scrubber. Evergreen 1(2), 34-39. https://doi.org/10.22141/eg.v1i2.1176

Kadam SD, Panwar NL. 2017. Recent advancement in biogas enrichment and its applications. Renewable and Sustainable Energy Reviews 73, 898-907. https://doi.org/10.1016/j.rser.2017.01.16

Khunprasert A, Charinpanitkul T. 2022. Comparison of the performance of water scrubber and iron sponge scrubber for biogas purification. Environmental Technology & Innovation 27, 102365. https://doi.org/10.1016/j.eti.2022.102365

Koubaissy B, Joly G, Toufaily J, Hamieh T, Germain P. 2019. Adsorption kinetics and equilibrium for CO2 removal on an activated carbon. Chemical Physics 217, 211-228. https://doi.org/10.1016/j.chemphys.2018.10.010

Maile OI, Muzenda E, Bambo FM. 2017. The chemical absorption of carbon dioxide by sodium hydroxide solutions for processes in the coal power plant. In International Conference on Chemical Process Engineering: Proceedings. 6-11

Peredo-Mancilla D, Lasso R, Pozo C. 2019. Selective CO2 capture by modified activated carbon. Environmental Science and Pollution Research 26(31), 31887-31899. https://doi.org/10.1007/s11356-019-06317-4

Rajendran K, Aslanzadeh S, Taherzadeh MJ. 2012. Household biogas digesters—A review. Energies 5(8), 2911-2942. https://doi.org/10.3390/en5082911

Rajendran S, Ganesh Prabhu M, George JA, Abishek GS, Saravanan V. 2020. Biogas upgrading techniques: A technical review with reference to the application perspective. Process Safety and Environmental Protection 136, 320-348. https://doi.org/10.1016/j.psep.2020.01.026

Rashed MA, Zhang Q, Garoma T, Kabir G, Mi J. 2019. Biogas generation from anaerobic co-digestion of cow manure with waste from agro-based soy products industry. Energy Conversion and Management 195, 957-968. https://doi.org/10.1016/j.enconman.2019.05.064

Rashidi NA, Yusup S. 2017. Potential of palm kernel shell as a renewable source for CO2 removing. Aerosol and Air Quality Research 17(3), 708-719. https://doi.org/10.4209/aaqr.2016.05.0186

Rattanapan C, Suksaroj TT, Suksaroj C. 2019. Adsorption of methane, carbon dioxide, and their mixture on activated carbon in the defouling mode: A theoretical evaluation. Arabian Journal of Chemistry 12(3), 351-359. https://doi.org/10.1016/j.arabjc.2015.10.023

Shen Y, Peng S, Liu Z, Lu X, Zhang C, Ni BJ, Peng Y. 2021. An overview of biogas production and upgrading from manure and concepts of integrating anaerobic digestion with composting. Renewable and Sustainable Energy Reviews 150, 111519. https://doi.org/10.1016/j.rser.2021.111519

Sithole B, Murungu R, Chidembo A, Timbom I. 2017. Biomass adsorbent materials for biogas upgrading. International Journal of Sustainable Energy and Environmental Research 6(2), 1-16.

Spigarelli BP, Kawatra SK. 2013. Opportunities and challenges in carbon dioxide capture. Journal of CO2 Utilization 1, 69-87. https://doi.org/10.1016/j.jcou.2013.03.002

Tippayawong N, Thanompongchart P. 2010. Biogas quality upgrade by simultaneous removal of CO2 and H2S in a packed column reactor. Energy 35(12), 4531-4535. https://doi.org/10.1016/j.energy.2010.04.045

Tobiesen FA, Svensson RE, Bakken J. 2018. Study of Anthropogenic CO2 as Feed to Anaerobic Digestion Process. In Energy Procedia 147, 237-242. https://doi.org/10.1016/j.egypro.2018.07.083

Tock L, Gassner M, Maréchal F. 2010. Thermochemical production of liquid fuels from biomass: Thermo-economic modeling, process design and process integration analysis. Biomass and Bioenergy 34(12), 1838-1854. https://doi.org/10.1016/j.biombioe.2010.07.018

Xu G, Xue Y, Zhou J, Lu Z, Du P, D’hooge DR, Baeyens J. 2020. Recent advances in biogas upgrading techniques: a review. Current Opinion in Environmental Science & Health 13, 10-17. https://doi.org/10.1016/j.coesh.2019.09.004

Xu S, Lam WC, Hölken I, Pivokonska L, Janssens-Maenhout G. 2019. Integrating techniques for atmospheric CO2 and CH4 measurements. In Advanced Remote Sensing Techniques for Ground-Based and Airborne Carbon Monitoring, 1-46.

 Xu X, Tian Z, Lian Y, Guo Y, Chang Y. 2002. Removal of hydrogen sulfide from biogas by biotrickling filters. Environmental Progress, 21(3), 196-201. https://doi.org/10.1002/ep.670210315

Yahya MA, Al-Qodah Z, Ngah CZ. 2015. Agricultural bio-waste materials as potential sustainable precursors used for activated carbon production: A review. Renewable and Sustainable Energy Reviews 46, 218-235. https://doi.org/10.1016/j.rser.2015.02.051

Yousef AM, El-Qanni WA, Alnaser WE. 2016. Biogas production from co-digestion of vegetable crop residues and industrial food waste. Biofuel Research Journal, 3(1), 398-406. https://doi.org/10.18331/BRJ2016.3.1.6

Zhang J, Yang Y, Zhang M, Wang W, Li J, Chu C. 2021. A review of biogas adsorption and membrane separation models and their applications in biogas upgrading. Chemical Engineering Journal 410, 128346. https://doi.org/10.1016/j.cej.2020.128346.