Kinetic studies on malachite green dye adsorption from aqueous solutions by Algae with Chitosan nanocomposite adsorbent: Nanocomposite synthesis and characterization

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Research Paper 10/03/2023
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Kinetic studies on malachite green dye adsorption from aqueous solutions by Algae with Chitosan nanocomposite adsorbent: Nanocomposite synthesis and characterization

SP. Manobala, S. Amutha, E. Pushpalakshmi, T. Madhumitha, R. Venkateshwari, S. Rajaduraipandian, G. Annadurai
J. Bio. Env. Sci.22( 3), 9-21, March 2023.
Certificate: JBES 2023 [Generate Certificate]

Abstract

Water polluted by dyestuffs compounds is a global threat to health and the environment; accordingly, we prepared a green novel sorbent chemical and Physical system from an algae, chitosan and chitosan nanoparticle and impregnated with algae with chitosan nanocomposite for the sorption of Malachite green dye from water. The algae with chitosan nanocomposite by a simple method and used as a recyclable and effective adsorbent for the removal of malachite green dye from aqueous solutions. Algae, chitosan, chitosan nanoparticle and algae with chitosan nanocomposite were characterized using different physicochemical methods. The functional groups and chemical compounds found in algae, chitosan, chitosan algae, chitosan nanoparticle, and chitosan nanoparticle with algae were identified using FTIR, SEM, and TGADTA/DTG techniques. The optimal adsorption conditions, different dosages, pH and Temperature the amount of algae with chitosan nanocomposite were determined. At optimized conditions and the batch equilibrium studies more than 99% of the dye was removed. The adsorption process data matched well kinetics showed that the reaction order for dye varied with pseudo-first order and pseudo-second order. Furthermore, the maximum adsorption capacity of the algae with chitosan nanocomposite toward malachite green dye reached as high as 15.5mg/g, respectively. Finally, multiple times reusing of algae with chitosan nanocomposite and removing dye from a real wastewater has made it a promising and attractive option for further practical applications.

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Abidi NJ, Duplay A, Jada E, Errais M, Ghazi K, Semhi M, Trabelsi A. 2019. Removal of anionic dye from textile industries’ effluents by using Tunisian clays as adsorbents. Ζeta potential and streaming-induced potential measurements. Compt. Rendus Chem 22, 113-125.

Aguiar JE, Cecilia PAS, Tavares DCS, Azevedo ER, Castellon SMP, Lucena IJ. 2017. Adsorption study of reactive dyes onto porous clay heterostructures. Appl. Clay Sci 135, 35 – 44.

Aragaw TA, Angerasa FT. 2020. Synthesis and characterization of Ethiopian kaolin for the removal of basic yellow (BY 28) dye from aqueous solution as a potential adsorbent. Heliyon 6, 1-16.

Ata A, Nalcaci OO, Ovez B. 2012. Macro algae Gracilaria verrucosa as a biosorbent: a study of sorption mechanisms. Algal Res 1(2), 194-204.

Bentahar S, Dbik A, El Khomri M, El Messaoudi N, Lacherai A. 2017. Adsorption of methylene blue, crystal violet and Congo red from binary and ternary systems with natural clay: kinetic, isotherm, and thermodynamic. J. Environ. Chem. Eng 5, 5921- 5932.

Bolan NS, Syers JK, Sumner ME. 1991. Dissolution of various sources of gypsum in aqueous solutions and in soil. J. Sci. Food Agric 57(4), 527-541

Boukhemkhem A, Rida K. 2017. Improvement adsorption capacity of methylene blue onto modified Tamazert kaolin. Adsorpt. Sci. Technol 35, 753-777.

Cestari AR, Vieira EFS, Tavares AMG, Bruns RE. 2008. The removal of the indigo carmine dye from aqueous solutions using cross-linked chitosan-eval- uation of adsorption thermodynamics using a full factorial design. Journal of Hazardous Materials 153, 566-574.

Chang MY, Juang RS. 2004. Adsorption of tannic acid, humic acid, and dyes from water using the composite of chitosan and activated clay. Journal of Colloid and Interface Science 278, 18-25.

Darvishi Cheshmeh Soltani R, Khataee AR, Safari M, Joo SW. 2013. Preparation of bio-silica/chitosan nanocomposite for adsorption of a textile dye in aqueous solutions. International Biodeterioration & Biodegradation 85, 383-391

Dias M, Valerio A, de Oliveira D, Ulson de Souza A, de Souza, SMGU. 2019. Adsorption of natural annatto dye by kaolin: kinetic and equilibrium. Environ. Technol 1, 2648- 2656.

Dogan M, Alkan M. 2003. Adsorption kinetics of methyl violet onto perlite, Chemosphere. 50(4), 517-528.

Elbaraka N, Saffaj N, Younssi SA, Mamouni R, Laknifli A, Albizane A, Barhon Z. 2012. Photocatalysis-Membrane separation coupling reactor: removal of organic pollutants from water, Scientific Study & Research. Chemistry & Chemical Engineering, Biotechnology. Food Industry 13(1), 105-108.

Errais E, Duplay J, Darragi F, M’Rabet I, Aubert A, Huber F, Morvan G. Efficient anionic dye adsorption on natural untreated clay: kinetic study and thermodynamic parameter. Desalination 275, 74- 81.

Errais E, Duplay J, Elhabiri M, Khodja M, Ocampo R, Baltenweck-Guyot R, Darragi F. 2012. Anionic RR120 dye adsorption onto raw clay: surface properties and adsorption mechanism, Colloids Surfaces A Physicochem. Eng. Asp 403, 69-78.

Franke MD, Ernst WR, Myerson AS. 1987. Kinetics of dissolution of alumina in acidic solution. AIChE Journal 33(2), 267-273.

Gadd GM. 2009. Biosorption: Critical review of scientific rationale, environmental importance and significance for pollution treatment, J. Chem. Technol. Biotechnol.: International Research in Process. Environmental & Clean Technology 84(1), 13-28.

Hameed BH, Daud FBM. 2008. Adsorption studies of basic dye on activated carbon derived from agricultural waste: Hevea brasiliensis seed coat. Chemical Engineering Journal 139(1), 48-55.

Ho Y. 2000. The kinetics of sorption of divalent metal ions onto sphagnum moss peat. Water Research 34(3), 735-742.

Ho YS, McKay G. 1998. A Comparison of Chemisorption Kinetic Models Applied to Pollutant Removal on Various Sorbents. Process Safety and Environmental Protection 76(4), 332-340.

Jumasiah A, Chuah TG, Gimbon J, Choong TSY, Azni I. 2005. Adsorption of basic dye onto palm kernel shell activated carbon: sorption equilibrium and kinetics studies. Desalination 186(1-3), 57-64.

Karim AB, Mounir B, Hachkar M, Bakasse M, Yaacoubi A. 2009. Removal of Basic Red 46 dye from aqueous solution by adsorption onto Moroccan clay, J. Hazard Mater 168, 304-309.

Karim Z, Adnan R, Husain Q. 2012. A b-cyclodextrinechitosan complex as the immobilization matrix for horseradish peroxidase and its application for the removal of azo dyes from textile effluent. International Biodeterioration & Biodegradation 72, 10-17.

Kaur Parul K, Badru R, Singh PP, Kaushal S. 2020. Photodegradation of organic pollutants using hetero junctions: a review. J. Environ. Chem. Eng 8(2), 1-66.

Khorramabadi GS, Soltani RDC, Rezaee A, Khataee AR, Jonidi Jafari A. 2012. Utilisation of immobilised activated sludge for the biosorption of chromium (VI). The Canadian Journal of Chemical Engineering 90, 1539-1546.

Krzysztof C, Xuecheng C, Ewa M, Wojciech K. 2013. Application of hollow mesoporous carbon nanospheres as an high effective adsorbent for the fast removal of acid dyes from aqueous solutions. Chemical Engineering Journal 228, 824-833.

Lagergren S. 1898. Zur theorie der sogenannten adsorption geloÈster stoffe, Kungliga Svenska Vetenskapsakademiens. Handlingar 24(4), 1-39.

Longhinotti E, Pozza F, Furlan L, Sanchez M, de N. de M, Klug M, Laranjeira, MCM, Favere VT. 1998. Adsorption of Anionic Dyes on the Biopolymer Chitin. Journal of the Brazilian Chemical Society 9(5), 435-440.

Martínez-Huitle CAP, anizza M. 2018. Electrochemical oxidation of organic pollutants for wastewater treatment. Current Opinion in Electrochemistry 11, 62-71.

Mohammed Rafeeq, Ateequrahman, Sanjar Alam, Mikdad. 2016. Automation of plastic, metal and glass waste materials segregation using arduino in scrap industry. International Conference on Communication and Electronics Systems (ICCES).

Nandi BK, Goswami A, Das AK, Mondal B, Purkait MK. 2008. Kinetic and equilibrium studies on the adsorption of crystal violet dye using Kaolin as an adsorbent. Separ. Sci. Technol 43, 1382-1403.

Niu S, Xie X, Wang Z, Zheng L, Gao F, Miao Y. 2019. Enhanced removal performance for Congo red by coal-series kaolin with acid treatment. Environ. Technol 25, 1472-1481.

Peternel IT, Koprivanac N, Bozic AML, Kusic HM. 2007. Comparative study of UV/TiO2, UV/ZnO and photo-Fenton processes for the organic reactive dye degradation in aqueous solution. J. Hazard Mater 148(12), 477-484.

Rashid N, Rehman MS, Han JI. 2013. Use of chitosan acid solutions to improve separation efficiency for harvesting of the microalga Chlorella vulgaris. Chemical Engineering Journal 226, 238-242.

Robinson T, McMullan G, Marchant A, Nigam P. 2001. Remediation of dyes in textile effluent: a critical review on current treatment technologies with a proposed alternative. Bioresour. Technol 77(3), 247-255.

Seozudoru O, Fil BA, Boncukcuollu R, Aladal E, Kul S. 2016. Adsorptive removal of cationic (BY2) dye from aqueous solutions onto Turkish clay: isotherm, kinetic, and thermodynamic analysis. Part, Sci. Technol 34, 103 -111

Tehrani-Bagha AR, Nikkar H, Mahmoodi NM, Markazi M, Menger FM. 2011. The sorption of cationic dyes onto kaolin: kinetic, isotherm and thermodynamic studies. Desalination 266, 274-280.

Wan Ngah WS, Teong LC, Hanafiah MAKM. 2011. Adsorption of dyes and heavy metal ions by chitosan composites: a review. Carbohydrate Polymers 83, 1446-1456.

Weber Jr WJ, Morris JC. 1963. Kinetics of adsorption on carbon from solution, J Sanit Eng Div Am Soc Civ Engrs 89, 31-59.

Yavuz O, Aydin AH. 2006. Removal of direct dyes from aqueous solution using various adsorbents. Pol. J. Environ. Stud 15, 155-161.

Zhao X, Lv L, Pan B, Zhang W, Zhang S, Zhang Q. 2011. Polymer-supported nanocomposites for environmental application: A review. Chemical Engineering Journal 170, 381-394.

Zhou L, Jin J, Liu Z, Liang X, Shang, C. 2011. Adsorption of acid dyes from aqueous solutions by the ethylenediamine-modified magnetic chitosan nano- particles. Journal of Hazardous Materials 185, 1045-1052.

Zhu HY, Jiang R, Fu YQ, Jiang JH, Xiao L, Zeng GM. 2011. Preparation, characterization and dye adsorption properties of g-Fe2O3/SiO2/chitosan com- posite. Applied Surface Science 258, 1337-1344.