Optimization studies on electrochemical and biosorption treatment of effluent containing nitro benzene by RSM

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Research Paper 01/02/2013
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Optimization studies on electrochemical and biosorption treatment of effluent containing nitro benzene by RSM

P. SivaKumar, D. Prabhakaran, T. Kannadasan, S. Karthikeyan
Int. J. Biosci. 3(2), 1-7, February 2013.
Copyright Statement: Copyright 2013; The Author(s).
License: CC BY-NC 4.0

Abstract

A novel process combining Electrochemical Oxidation and Biosorption treatment was presented for
Nitrobenzene abatement. The electrochemical oxidation was investigated batch-wise in the presence of NaCl (2gL-1) electrolyte with lead as anode and copper as cathode electrodes. The conditions were optimized using response surface methodology (RSM), which result in 76.4% reduction of COD was found to be maximum and the optimum conditions were satisfied at current density 3.56 A dm-2, time 3 hours, flow rate 40 L hr -1, volume 9 L occur at minimum power consumption of 30.3 kWhr / kg COD. It is followed by biosorption treatment in the presence of biosorbents such as maize and rice stems at 15 g L-1. From this study it was observed that the maximum % of COD reduction was 97.7 % for the optimized time 4 days and volume 6 L for pretreated effluent containing nitrobenzene.

Hartter DR. 1985. The use and importance of nitroaromatic chemicals in the chemical industry. In Toxicity of Nitroaromatic Compounds – Chemical Industry Institute of Toxicology series. 1-13.

Lin ZX, Zheng FX. 2003. Study on adsorption process for nitrobenzene on water hyacinth root. Shanghai Environmental Sciences 12, 703-709, http://dx.doi.org/10.1021/ie0308487

Norvell Nelson. 2002. Electrochemical destruction of organic hazardous wastes. Platinum Metals Review 46(1), 18-23.

Panizza M, Bocca P, Cerisola G. 2000. Electrochemical treatment of wastewater containing polyaromatic organic pollutants. Water Research 34, 2601-2605, http://dx.doi.org/10.1016/S0043-1354(00)00145-7

Radha KV, Sridevi V, Kalaivani K. 2009. Electrochemical oxidation for the treatment of textile industry wastewater. Bioresource Technology 100(2), 987–990, http://dx.doi.org/10.1016/j.biortech.2008.06.048

Rajeshwar K, Ibanez JG. 1997. Fundamentals and Application in Pollution Abatement. Academic Press, ISBN: 9780125762601.

Rajeshwar K, Ibanez JG, Swain GM. 1994. Electrochemistry and the environment. Journal of Applied Electrochemistry 24(11), 1077–1091.

Robinson T, Chandran B, Nigam P. 2005. Removal of dyes from a synthetic textile dye effluent by biosorption on apple pomace and wheat straw. Water Research 36, 2824–2830, http://dx.doi.org/10.1016/S0043-1354(01)00521-8

Shengrui Wang, Suwen Yang, Xiangcan Jin, Liangke Liu, Fengchang Wu. 2010. Use of low cost crop biological wastes for the removal of Nitrobenzene from water. Desalination 264, 32-36, http://dx.doi.org/10.1016/j.desal.2010.06.075

Yousuf M, Mollah A, Schennach R, Parga JR, Cocke DL. 2001. Electro coagulation (EC)-science and applications. Journal of Hazardous Materials 84, 29–41, http://dx.doi.org/10.1016/S0304-3894(01)00176-5

Yu-Ping Li, Hong-Bin Cao, Chen-Ming Liu, Yi Zhang. 2006. Electrochemical reduction of nitrobenzene at carbon nanotube electrode. Journal of Hazardous Materials 148, 158-163, http://dx.doi.org/10.1016/j.jhazmat.2007.02.021

Zhao XK, Yang GP, Gao XC. 2003. Studies on the sorption behaviors of nitrobenzene on marine sediments. Chemosphere 52(5), 917-25.

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