Optimization studies on electrochemical and biosorption treatment of effluent containing nitro benzene by RSM

Paper Details

Research Paper 01/02/2013
Views (620)
current_issue_feature_image
publication_file

Optimization studies on electrochemical and biosorption treatment of effluent containing nitro benzene by RSM

P. SivaKumar, D. Prabhakaran, T. Kannadasan, S. Karthikeyan
Int. J. Biosci. 3(2), 1-7, February 2013.
Copyright Statement: Copyright 2013; The Author(s).
License: CC BY-NC 4.0

Abstract

A novel process combining Electrochemical Oxidation and Biosorption treatment was presented for
Nitrobenzene abatement. The electrochemical oxidation was investigated batch-wise in the presence of NaCl (2gL-1) electrolyte with lead as anode and copper as cathode electrodes. The conditions were optimized using response surface methodology (RSM), which result in 76.4% reduction of COD was found to be maximum and the optimum conditions were satisfied at current density 3.56 A dm-2, time 3 hours, flow rate 40 L hr -1, volume 9 L occur at minimum power consumption of 30.3 kWhr / kg COD. It is followed by biosorption treatment in the presence of biosorbents such as maize and rice stems at 15 g L-1. From this study it was observed that the maximum % of COD reduction was 97.7 % for the optimized time 4 days and volume 6 L for pretreated effluent containing nitrobenzene.

Hartter DR. 1985. The use and importance of nitroaromatic chemicals in the chemical industry. In Toxicity of Nitroaromatic Compounds – Chemical Industry Institute of Toxicology series. 1-13.

Lin ZX, Zheng FX. 2003. Study on adsorption process for nitrobenzene on water hyacinth root. Shanghai Environmental Sciences 12, 703-709, http://dx.doi.org/10.1021/ie0308487

Norvell Nelson. 2002. Electrochemical destruction of organic hazardous wastes. Platinum Metals Review 46(1), 18-23.

Panizza M, Bocca P, Cerisola G. 2000. Electrochemical treatment of wastewater containing polyaromatic organic pollutants. Water Research 34, 2601-2605, http://dx.doi.org/10.1016/S0043-1354(00)00145-7

Radha KV, Sridevi V, Kalaivani K. 2009. Electrochemical oxidation for the treatment of textile industry wastewater. Bioresource Technology 100(2), 987–990, http://dx.doi.org/10.1016/j.biortech.2008.06.048

Rajeshwar K, Ibanez JG. 1997. Fundamentals and Application in Pollution Abatement. Academic Press, ISBN: 9780125762601.

Rajeshwar K, Ibanez JG, Swain GM. 1994. Electrochemistry and the environment. Journal of Applied Electrochemistry 24(11), 1077–1091.

Robinson T, Chandran B, Nigam P. 2005. Removal of dyes from a synthetic textile dye effluent by biosorption on apple pomace and wheat straw. Water Research 36, 2824–2830, http://dx.doi.org/10.1016/S0043-1354(01)00521-8

Shengrui Wang, Suwen Yang, Xiangcan Jin, Liangke Liu, Fengchang Wu. 2010. Use of low cost crop biological wastes for the removal of Nitrobenzene from water. Desalination 264, 32-36, http://dx.doi.org/10.1016/j.desal.2010.06.075

Yousuf M, Mollah A, Schennach R, Parga JR, Cocke DL. 2001. Electro coagulation (EC)-science and applications. Journal of Hazardous Materials 84, 29–41, http://dx.doi.org/10.1016/S0304-3894(01)00176-5

Yu-Ping Li, Hong-Bin Cao, Chen-Ming Liu, Yi Zhang. 2006. Electrochemical reduction of nitrobenzene at carbon nanotube electrode. Journal of Hazardous Materials 148, 158-163, http://dx.doi.org/10.1016/j.jhazmat.2007.02.021

Zhao XK, Yang GP, Gao XC. 2003. Studies on the sorption behaviors of nitrobenzene on marine sediments. Chemosphere 52(5), 917-25.

Related Articles

Design and development of an arduino-based smart feeder system

Arvin Anthony S. Araneta, Int. J. Biosci. 27(2), 29-36, August 2025.

Socio-psychological and technological predictors of academic resilience in online graduate programs in STEM and natural sciences

Sonny Soriano, Christine Nabor-Ferrer, MA. Cristina Estioco, Marmelo Abante, Roger A. Martinez Jr., Rosalie Sheryll T. Rosales, Dannah Valerie J. Dulnuan, Danilo B. Dorado, Marcelo P. Villaluna Jr., Int. J. Biosci. 27(2), 1-16, August 2025.

Introduction of heavy metals contamination in the water: A review on source, toxicity and remediation methods

Khushaboo Soni, Preeti Maurya, Sanjay Singh, Int. J. Biosci. 27(1), 405-423, July 2025.

Groundnut (Arachis hypogaea L.) presents many similar responses to drought and salinity, two water stress factors

Mouniratou Zoungrana, Moumouni Konate, Jacob Sanou, Pauline Bationo Kando, Int. J. Biosci. 27(1), 386-404, July 2025.