Preparation of nanospinels La1-X Sr XCrO3 using hydrothermal method and their applications on removal of azo dye from aqueous solutions
Paper Details
Preparation of nanospinels La1-X Sr XCrO3 using hydrothermal method and their applications on removal of azo dye from aqueous solutions
Abstract
In The present study, nanoparticles of perovskite-type La1-X Sr XCrO3 (LSCO) were prepared by Hydrothermal method in the presence of NaOH as a chelating agent. A series of common analytical techniques were used to characterize of the nanopowders. Thermal decomposition process of the complex precursor was examined by means of thermal gravimetric analysis (TGA). The surface morphology and composition of these nanopowders were also investigated using scanning electron microscopy (SEM). X-ray diffraction (XRD) patterns showed that single perovskite phase has been completely formed after calcinations treatment and transmission electron microscopy (TEM). The average particle size of LSCO is about 30 nm. The Fourier transform infrared (FT-IR) spectra were also measured for studying of structure of prepared nanopowders. The nanoparticles showed the excellent adsorption properties towards Bromo thymol blue (C27H28Br2O5S).The adsorption studies have been carried out at different pH values, initial dye concentration and adsorbent doses to the optimum conditions. the removal of BTB above 88% was achieved. The Kinetic studies indicate that the removal process obeys the second-order kinetic equation. Also, The experimental isotherms were analyzed with four parameters equations (Freundlich, Langmuir, Temkin, and Redlich–Peterson) using linear regression.
Ahmad M, Rahman N. 2011. Equilibrium, kinetics and thermodynamic of remazol brillant orange 3R dye adsorption on coffee husk-based activated carbon. Chem. Eng. J 170, 154-161.
Al-Degs Y, El-Barghouthi M, El-Sheikh A, Walker G. 2008. Effect of solution pH, ionic strength, and temperature on adsorption behavior of reactive dyes on activated carbon. Dyes and Pigments 77, 16 -23.
Arana J, Herrera Melian J, Dona Rodríguez J, Gonzalez Diaz O, Viera A, Perez Pena J, Marrero Sosa P, Espino Jimenez V. 2002. TiO2 photocatalysis as tertiary treatment of naturally treated wastewater. Catal. Today 76, 279– 289.
Bonel G. 1972. Annales Chimie 7, 127-144.
Boyer B, Cardoso N, Lima E, Macedo T. 2010. A useful organofunctionalized layered silicate for textile dye removal. J. Hazard. Mater 181, 366 -374.
Choy K, McKay G, Porter J. 1999. Sorption of acid dyes from effluents using activated carbon, Resour. Conserv. Rec 27, 57-71.
Chung K, Stevens S. 1993. Degradation of azo dyes by environmental microorganisms and helminthes. Environ. Toxicol. Chem 12, 2121– 2132.
Da Silva L, Ruggiero R, Gontijo P, Pinto R, Royer B, Lima E, Fernandes T, Calvete T. 2011. Adsorption of brillant red 2BE dye from water solutions by chemically modified sugarcane bagasse lignin. Chem. Eng. J 168, 620-628.
El Boujaady H, El Rhilassi A, Ziatni M, El Hamri R, Taitai A, Lacout J. 2011. Removal of a textile dye by adsorption on synthetic calcium phosphates. Desalination, in press.
Eng H, Barnes P, Auer B, Woodward P. 2003. Investigations of the electronic structure of d0 transitionmetal oxides belonging to the pervoskite family. J. Solid State Chem 175, 94– 109.
Errais E, Duplay J, Darragi F, M’Rabet I, Aubert A, Huber F, Morvan G. 2001. Efficient anionic dye adsorption on natural untreated clay: Kinetic study and thermodynamic parameters. Desalination 275, 74-81.
Forgacs E, Cserhati T, Oros G. 2004. Removal of synthetic dyes from wastewaters: a review. Environ. Int 30, 953–971.
Freundlich H. 1906. Uber die adsorption in lasugen. Z. Phys. Chem 57A, 385-470.
Garcia De La Cruz R, Falcon H, Pena M, Fierro J. 2001. Role of bulk and surface structures of La1−xSrxNiO3 perovskite-type oxides in methane combustion. Appl. Catal. B: Environ 33, 45–55.
Gil A, Assis F, Albeniz S, Korili A. 2011. Removal of dyes from wastewaters by adsorption on pillared clays. Chem. Eng. J 168, 1032-1040.
Giles C, Macewan T, Smith D. 1960. Studies in adsorption. Part XI. A system of classification of solution adsorption isotherms, and its use in diagnosis of adsorption mechanisms and in measurement of specie surface areas of solids. Chem. Soc XI, 3973- 3993.
Hao Y, Li J, Yang X, Wang X, Lu L. 2004. Preparation of ZrO2–Al2O3 composite membranes by sol–gel process and their characterization. Mater. Sci. Eng. A 367, 243–247.
Hsueh C, Lu Y, Hung C, Huang Y, Chen C. 2007. Adsorption kinetic, thermodynamic and desorption studies of Reactive Black 5 on a novel photoassisted Fenton catalyst. Dyes Pigm 75, 130– 135.
Indra D, Vimal C, Nitin K. 2006. Removal of Orange-G and Methyl Violet dyes by adsorption onto bagasse fly ash- kinetic study and equilibrium isotherm analyses. Dyes Pigm 69, 210– 223.
Kao C, Jeng C. 1999. Preparation and characterization of lanthanum nickel oxides by combined coprecipitation and molten salt reactions. Ceram. Int 25, 375– 382.
Kao C, Jeng C. 2000. Preparation and characterisation of lanthanum nickel strontium oxides by combined coprecipitation and molten salt reactions. Ceram. Int 26, 237–243.
Kim J, Honma I. 2004. Synthesis and proton conducting properties of zirconia bridged hydrocarbon/ phosphotungstic acid hybrid materials. Electrochim. Acta 49, 3179–3183.
Kritikos D, Xekoukoulotakis N, Psillakis E, Mantzavinos D. 2007. Photocatalytic degradation of reactive black 5 in aqueous solutions: Effect of operating conditions and coupling with ultrasound irradiation. Water Res 41, 2236– 2246.
Kuznetsov P, Kuznetzova L, Zhyzhaev A, Pashkov G, Boldyrev V. 2002. Ultra fast synthesis of metastable tetragonal zirconia by means of mechanochemical activation. Appl. Catal. A 227, 299–307.
Langmuir I. 1906. The adsorption of gases on plane surfaces. Phys. Chem. A 57, 385– 471.
Leite E, Sousa C, Longo E, Varela J. 1995. Influence of polymerization on the synthesis of SrTiO3: Part I. Characteristics of the polymeric precursors and their thermal decomposition. Ceram. Int 21, 143–152.
Lin S, Chen M. 1997. Treatment of textile wastewater by chemical methods for reuse. Water Res 31, 868–876.
Liu S, Qian X, Xiao J. 2007. Synthesis and characterization of La0.8Sr0.2Co0.5Fe0.5O3±δ nanopowders by microwave assisted sol–gel route. J. Sol-Gel Sci. Technol 44, 187–193.
Mansilla H, Bravo C, Ferreyra R, Litter M, Jardim W, Lizama C, Freer J, Fernandez J. 2006. Photocatalytic EDTA degradation on suspended and immobilized TiO2. J. Photochem. Photobiol. A. Chem 181, 188– 194.
Mazloumia M, Shahcheraghia N, Kajbafvala A, Zanganeha S, Laka A, Mohajerania M, Sadrnezhaad S. 2009. 3D bundles of self-assembled lanthanum hydroxide nanorods via a rapid microwave-assisted route. J. Alloys Compd 473, 283– 287.
Meadowcroft D. 1970. Low-cost Oxygen Electrode Material. Nature 226, 847– 848.
Neumann A, Walter D. 2006. The thermal transformation from lanthanum hydroxide to lanthanum hydroxide oxide. Thermochim. Acta 445, 200– 204.
Nimmo W, Ali N, Brydson R, Calvert C, Hampartsoumian E, Hind D, Milne S. 2003. Formation of lead zirconate titanate powders by spray pyrolysis. J. Am. Ceram. Soc 86, 1474–1480.
Oliveira D, Carneiro P, Sakagami M, Zanoni M, Umbuzeiro G. 2007. Chemical characterization of a dye processing plant effluent- Identification of the mutagenic components. Mutat. Res 626, 135– 142.
Pantelis A, Nikolaos P, Dionissios M. 2006. Treatment of textile dyehouse wastewater by TiO2 photocatalysis. Water Res 40, 1276–1286.
Robinson T, McMullan G, Marchant R, Nigam P. 2001. Remediation of dyes in textile effluent: a critical review on current treatment technologies with a proposed alternative. Bioresour. Technol 77, 247– 255.
Sakar-Deliormanl A, Celik E, Polat M. 2009. Solubility and aging of lead magnesium niobate in water. Ceram. Int 35, 503–508.
Singh R, Lal B. 2000. High surface area lanthanum cobaltate and its A and B sites substituted derivatives for electrocatalysis of O2 evolution in alkaline solution. Int. J. Hydrogen Energy 27, 45–55.
Tanabe K. 2003. Catalytic application of niobium compounds. Catal. Today 78,65–77.
Van der Zee F, Bouwman R, Strik D, Lettinga G, Field J. 2001. Application of redox mediators to accelerate the transformation of reactive azo dyes in anaerobic bioreactors. Biotechnol. Bioeng 75, 691–701.
Van der Zee F, Villaverde S. 2005. Combined anaerobic–aerobic treatment of azo dyes- A short review of bioreactor studies. Water Res 39, 1425– 1440.
Vandevivere P, Bianchi R, Verstraete W. 1998. Treatment and reuse of wastewater from the textile wet-processing industry: Review of emerging technologies. J. Chem. Technol. Biotechnol 72, 289– 302.
Weisburger J. 2002. Comments on the history and importance of aromatic and heterocyclic amines in public health. Mutat. Res 506, 9–20.
Yazdanbakhsh M, Tavakkoli H, Hosseini S. 2011. Characterization and evaluation catalytic efficiency of La0.5Ca0.5NiO3 nanopowders in removal of reactive blue 5 from aqueous solution. Desalination 281, 388–395.
Yongfa Z, Ruiqin T, Tao Y, Song G, Chunhua Y, Lili C. 2000. Preparation of nanosized La2CuO4 perovskite oxide using an amorphous heteronuclear complex as a precursor at low-temperature. J. Alloys and Comp 311, 16– 21.
Maryam Maskanati, Haman Tavakkoli (2015), Preparation of nanospinels La1-X Sr XCrO3 using hydrothermal method and their applications on removal of azo dye from aqueous solutions; JBES, V6, N4, April, P541-551
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