Removal of Pb(II) from aqueous solutions using solvent impregnated resin containing 1,4-diaminoantraquinone before the determination by flame atomic absorption spectrometry

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Research Paper 01/02/2014
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Removal of Pb(II) from aqueous solutions using solvent impregnated resin containing 1,4-diaminoantraquinone before the determination by flame atomic absorption spectrometry

Fatemeh Abedi, Mohammad Saeid Hosseini, Raheleh Zhiani, Ali Reza Motavalizadeh, Zohreh Ebrahimi
J. Bio. Env. Sci.4( 2), 245-252, February 2014.
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This study is a simultaneous separation and pre concentration of Pb (II) ion from water samples befor determination with flame atomic absorption spectrometric. It is based on sorption of Pb(II) at the buffering pH of 8, on a mini column(10cm length and 5mm internal diameter) packed with 0.7 g Amberlite XAD-16 resin impregnated with chelating agent of 1,4-diaminoantraquinone (DAAQ). After passing of sample solution from the column, elution process was carried out with passing of 5 mL 2M HCl into column and then subjected to FAAS for the determination. The sample and eluent flow rate, eluent concentration and ionic strength effect were investigated and optimized. RSD, LOD (3sb/m), recovery were found to be 2.8%, 1.8×10-9 M, 92.95% respectively.


Douglas C B, Wolfgang F. 1995. Speciation of lead in environmental and biological samples. Journal of Pure and Applied Chemistry 67, 615-648.

Du B, Yang J, Wei Q, Chang G. 2002. Spectrophotometric determination of trace amounts of lead in environmental water samples in the presence of mixed microemulsion. Journal of Anal Lett, 35, 895-908.

Dutta S, Das A K. 2007. Synthesis, characterization and application of a new chelating resin functionalized with ithiooxamide. Journal of Applied Polymer Science 103, 2281-2285.

Yavuz H, Denizli A, Güngünes H, Safarikova M, Safarik I. 2006. Biosorption of mercury on magnetically modified yeast cells. Seperation Purifing Technology 52, 253-260.

Manohar D M, Anoop Krishnan K, Anirudhan T S. 2002. Removal of mercury(II) from aqueous solutions and chlor-alkali industry wastewater using 2-mercaptobenzimidazole-clay. Water Resolution 36, 1609–1619.

Feng Q, Lin Q, Gong F, Sugita S, Shoya M. 2004. Adsorption of lead and mercury by rice husk ash. Journal of Colloid Interface Science 278, 1-8.

Song C Ji S, Wang C, Sun C, Qu R, Wang C, Chen H. 2010. Preparation and adsorption properties of chelating resins containing 3-aminopyridine and hydrophilic spacer arm for Hg(II). Journal of Chemical Engineering 165, 573-580.

Atia A A, Donia A M, ELwakeel K Z. 2008. Selective separation of mercury(II) using magnetic chitosan resin modi.ed with Schiff’s base derived from thiourea and glutaraldehyde. Journal of Hazardous Material 151, 372-379.

Jain V K, Pandia R A, Pillai S G, Shrivastay P S. 2006. Simultaneous preconcentration of Uranium(VI) and Thurium(IV) from aqeous solutions using a chelaiting calixarene anchored chloromethylated polystyrene solid phase. Talanta 70, 257-266.

Hennion M C. 1999. Solid-phase extraction:method development,sorbents and coupling with liquid chromatography. Journal of Chromatography A 856, 3-54.

Reis B F, Rocha F R P, Teixeira L S G, Costa A C G, Korn M. 2000. Construction of a .ow cell for measurements by solid-phase spectrophotometry. Quim. Nova 23, 116-118.

Teixeira L S G, Rocha F R P, Korn M, Reis B F, Ferreira S L C, Costa A c S. 2000. Nickel and zinc determination by .ow-injection solid-phase spectrophotometry exploiting different sorption rates. Talanta 51, 1027-1033.

Teixeira L S G, Reis J O N, Costa A C S, Ferreira S L C, Korn M G A, Andrade J B De. 1998. ICP–AES determination of small amounts of zinc in copper-base alloys after separation by adsorption of the zinc–TAN complex on Sep Pak C18 cartridges. Talanta 46, 1279-1283.

Juang R S, Su J Y. 1992. Sorption of copper and zinc from aqueous sulfate solutions with bis(2-ethylhexy1) phosphoric acid-impregnated macroporous resin. Industerial and Engineering Chemistry Research 31, 2774-2779.

Prabhakaran D, Subramanian M S. 2004. selective extraction of U(VI),Th(IV),La(III) from acidic matrix solutions and environmental samples using chemically modified Amberlite XAD-16 resin. Journal of Analytical and Bio Analalytical Chemistry 379, 519-525.

Prabhakaran D, Subramanian M S. 2003. A column system for the selective extraction of U(VI),Th(IV) using a new chelating sorbent. Talanta, 61, 423-430.

Hosseini M S, Hosseini-Bandegharari A. 2009. Comparison of sorption behavior of Th(IV),U(VI)on modified impregnated resin containing qunizarin with that conventional prepared impregnated resin. Journal of Hazardous Materials 169, 52-62.

Hosseini M S, Hosseini-Bandegharaei A, Hosseini M. 2009. Column-mode separation and preconcentration of some heavy metal ions by solvent impregnated resins containing quinizarin before the determination by .ame atomic absorption spectrometry, International Journal of Environmental and Analytical Chemistry 89, 35–48.

Hosseini M S, Hosseini-Bandegharaei A. 2010. Selective extraction of Th(IV) over U(VI) and other co-existing ions using eosin B-impregnated Amberlite IRA-410 resin beads. Journal of Radioanalytical and Nuclear Chemistry 283, 23–30.

Hosseini M S, Hosseini-Bandegharaei A, Raissi H, Belador F. 2009. Sorption of Cr(VI) by Amberlite XAD-7 resin impregnated with brilliant green  and  its  determination  by  quercetin  as  a selective  spectrophotometric  reagent.  Journal  of Hazardous Materials 169, 52–57.

Hosseini-Bandegharaei A, Hosseini, M. Sarw- Ghadi,  S.  Zowghi,  E.  Hosseini,  Hosseini- Bandegharaei H.2010.  Kinetics,  equilibrium  and thermodynamic   study   of   Cr(VI)   sorption   into toluidine blue o-impregnated XAD-7 resin beads and its  application  for  the  treatment  of  wastewaters containing  Cr(VI).  Chemical  Engineering  Journal 160, 190-198.