Separation and pre concentration of Co (II) from water samples with impregnated resin containing 1, 4-diaminoantraquinone

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Research Paper 01/07/2014
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Separation and pre concentration of Co (II) from water samples with impregnated resin containing 1, 4-diaminoantraquinone

Fatemeh Abedi, Reyhaneh Emamian, Atefeh Mohammadian, Alireza, Motavalizadehkakhky, Jamshid Mehrzad, Zohreh Ebrahimi, Zohreh Emrani
J. Biodiv. & Environ. Sci. 5(1), 243-248, July 2014.
Copyright Statement: Copyright 2014; The Author(s).
License: CC BY-NC 4.0

Abstract

A new study for separation and pre concentration of Co(II) in water samples was done using adsorbant solid phase containing amberlit resin XAD-16 that impregnated with ligand; 1,4-diamino antraquinone. The solid phase was packed into mini column (10cm length and 5mm diameter) and water sample containing Co (II) was passed through the column. Then, adsorbed ions were eluted using HCl (2M) as eluent and subsequent determination was done with flame atomic absorption spectrometer (FAAS).For access to the highest recovery, various parameters such as PH, ionic strength, type of eluent, sample flow rate and eluent flow rate were optimized. In this manner, the recovery obtained was quantitative (95%) and LOD (3Sb/m), RSD were obtained 1.2 ×10-9 M, 3.2% respectively.

Underwood EJ. 1977. Trace Elements in Human and Nutrition’s, 4th ed., Academic Press: New York, p. 545.

Seiler HG. 1994. Siegel, A.; Siegel, H.; Handbook on Metals in Clinical Analytical Chemistry, Marcel Dekker: New York, p720.

McKenzie HA, Smythe LE. 1988. Quantitative Trace Analysis of Biological Materials, Elsevier: New York, p.353.

Belitz HD, Grosch W. 1987. Food Chemistry, Springer-Verlag: Berlin.

Rojas C, Arancibia V, Góme M, Nagles E. 2012. Speciation of Cr(VI) and Cr(III) in Water Samples by Adsorptive Stripping Voltammetry in the Presence of Pyrogallol Red Applying a Selective Accumulation Potent, International journal of electrochemical science. 7, 11444.

Cai Y, Jiang G, Liu J. 2002. Preconcentration of Cu (II), Fe(III), Ni(II), Co(II) and Pb(II) ions in some manganese salts with solid phase extraction method using chromosoreB-102 resin, Talanta 57, 1173.

Cerutti S, Moyano S, Gásquez JA, Stripeikis J, Olsina  RA,  Martinez  LD.  2003.  Trace  and selective determination of cobalt(II) in water and salt samples   using   cathodic   adsorptive   stripping voltammetry  in  the  presence  of  Pyrogallol  Red, Spectro Chimica Acta, B 58 ,2015.

Praveen RS, Daniel S, Rao TP. 2005. flame atomic absorption spectrophotometric determination trace amount of nickel in water samples after solid-phase extraction and preconcentration on to IR-120 amberlit resin modified with 5-(4-dimethyl amino-benzyliden)-rhodamin, Talanta 66, 513.

Citak D, Tuzen M. 2010. a novel preconcentration procedure using cloud point extraction for determination of Lead, Cobalt and Copper in water and food samples using flame atomic absorption spectrometry,Food chemistry and toxicological journal 48 , 1399.

Ghaedi M, Shokrollahi A, Ahmadi F, Rajabi RH, Soylak M. 2009. Determination of Cu, Fe, Pb and Zn by Flame-AAS after Preconcentration using Sodium Dodecyl Sulfate Coated Alumina Modified with Complexing Agent, Journal of the Chinese Chemical Society56, 150-157.

Agarwal S, Mathur SP. 2001. Photometric determination of Co (II) by adsorption of its 1-allyl-3-(5-chloro-pyridyl)thiourea complex on poly urethane foam, Indian journal of chemistry 40A,544.

Jain V K, Pandia RA, Pillai S G, Shrivastay PS. 2006. Simultaneous preconcentration of Uranium(VI) and Thurium(IV) from aqeous solutions using a chelaiting calixarene anchored chloromethylated polystyrene solid phase. Talanta 70, 257-266.

Hennion MC. 1999. Solid-phase extraction:method development,sorbents and coupling with liquid chromatography. Journal of Chromatography A 856, 3-54.

Reis BF, Rocha FRP, Teixeira LSG, Costa ACG, Korn M. 2000. Construction of a .ow cell for measurements by solid-phase spectrophotometry. quim nova journal 23, 116-118.

Teixeira LSG, Rocha FRP, Korn M, Reis BF, Ferreira SLC, Costa ACS. 2000. Nickel and zinc determination by .ow-injection solid-phase spectrophotometry exploiting different sorption rates. Talanta 51, 1027-1033.

Teixeira LSG, Reis JON, Costa ACS, Ferreira SLC, Korn MGA, Andrade JBD. 1998. ICP–AES determination of small amounts of zinc in copper-base alloys after separation by adsorption of the zinc– TAN complex on Sep Pak C18 cartridges. Talanta 46, 1279-1283.

Juang RS, Su JY. 1992. Sorption of copper and zinc from aqueous sulfate solutions with bis(2-ethylhexy1) phosphoric acid-impregnated macroporous resin. Industerial and Engineering Chemistry Research 31, 2774-2779.

Prabhakaran D, Subramanian MS. 2004. selective extraction of U(VI),Th(IV),La(III) from acidic matrix solutions and environmental samples using chemically modified Amberlite XAD-16 resin. Journal of Analytical and Bio Analalytical Chemistry 379, 519-525.

Prabhakaran D, Subramanian MS. 2003. A column system for the selective extraction of U(VI),Th(IV) using a new chelating sorbent. Talanta, 61, 423-430.

Hosseini MS, Hosseini-Bandegharari A. 2011. Comparison of sorption behavior of Th(IV),U(VI)on modified impregnated resin containing qunizarin with that conventional prepared impregnated resin. Journal of Hazardous Materials 169, 52-62.

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