Single drop scanometry, Determination of cyanide in water in the various color spaces

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Research Paper 01/05/2016
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Single drop scanometry, Determination of cyanide in water in the various color spaces

Abdolreza Khajehzadeh, Tahere Ghaedian, Farzaneh Barani, Zahra Sadeghi Mazidi
J. Biodiv. & Environ. Sci. 8(5), 1-15, May 2016.
Copyright Statement: Copyright 2016; The Author(s).
License: CC BY-NC 4.0

Abstract

In this study, the application of new and simple single drop scanometric method was described for determination of cyanide as alternative for visible spectrophotometric method. Cyanide ion reacts with the methyl violet and causes a decrease in the color intensity of solution. In the single drop scanometry, color intensity of one droplet of solution was measured with color analyzing software in the various color models such as RGB, CMYK, HSV and XYZ. In the proposed method, characterization of single drop was done with potassium permanganate 0.001 M solution and pixel sampling box location, droplet location, glass plate location and image format were studied and optimized. This method has a linear range 5–12 mM with a limit of detection of 2.3 mM for CN- ions. The developed method was successfully applied to the determination of cyanide in the mineral waters with acceptable results.

Abbaspour A, Khajehzadeh A, Ghaffarinejad A. 2009. A simple and cost-effective method, as an appropriate alternative for visible spectrophotometry: development of a dopamine biosensor. Analyst 134, 1692 – 1698.

Abbaspour A, Valizadeh H, Khajehzadeh A. 2011. simple, fast and cost effective method for detection and determination of dopamine in bovine serum. Anal. Methods 3, 1405 – 1409.

Abbaspour A, Asadi M, Ghaffarinejad A, Safaei E. 2005. A selective modified carbon paste electrode for determination of cyanide using tetra-3,4-pyridinoporphyrazinatocobalt(II). Talanta 66, 931 – 936.

Afkhami A, Sarlak N. 2007. A novel cyanide sensing phase based on immobilization of methyl violet on a triacetylcellulose membrane. Sens. Actuators B 122, 437 – 441.

Baskin SI, Brewer TG, Sidell F, Takafuji ET, Franz DR. 1997. Medical Aspects of Chemical and Biological Warfare. TMM publications, Washington, 271–286.

Biller J, Lippincott W, Wilkins. 2008. Interface of neurology and internal medicine. 939.

Cacace D, Ashbaugh H, Kouri N, Bledsoe S, Lancaster S, Chalk S. 2007. Spectrophotometric determination of aqueous cyanide using a revised phenolphthalein method. Anal. Chim. Acta 589, 137– 141.

Chattaraj S, Das AK. 1991. Indirect Determination of Free Cyanide in Industrial Waste Effluent by Atomic Absorption Spectrometry. Analyst 116, 739-741.

Gamoh K, Imamichi S. 1991. Postcolumn liquid chromatographic method for the determination of cyanide with fluorimetric detection. Anal. Chim. Acta 251, 255 – 259.

Gattrell M, Cheng SC, Guena T, MacDougall B. 2001. Cyanide ion-selective electrode measurements in the presence of copper. J. Electroanal. Chem. 508, 97 – 104.

Gumus G, Demirata B, Apak R. 2000. Simultaneous spectrophotometric determination of cyanide and thiocyanate after separation on a melamine-formaldehyde resin. Talanta 53, 305 – 315.

Hachiya H, Ito S, Fushinuki Y, Masadome T, Asano Y, Imato T. 1999. Continuous monitoring for cyanide in waste water with a galvanic hydrogen cyanide sensor using a purge system.Talanta 48, 997-1004.

Meeussen JCL, Temminhoff EJM, Keiser MG. 1989. Spectrophotometric determination of total cyanide, iron-cyanide complexes, free cyanide and thiocyanate in water by a continuous-flow system. Analyst 114, 959 – 963.

Moriya F, Hashimoto Y. 2001. Potential for error when assessing blood cyanide concentrations in fire victims. J. Forensic Sci. 46, 1421-1425.

Nelson D, Nelson DL, Cox MM. 2004. Lehniger Principles of Biochemistry. New York: Worth Publishers. 668-670, 71-676.

Nonomura M. 1987. Indirect determination of cyanide compounds by ion chromatography with conductivity measurement. Anal. Chem. 59, 2073 – 2076.

Ohno T. 1989. Spectrophotometric determination of total cyanide in surface waters following ultraviolet induced photodecomposition. Analyst 114, 857 – 858.

Scoggins MW. 1972. Ultraviolet spectrophotometric determination of cyanide ion. Anal. Chem. 44, 1294 – 1296.

Watanabe K, Seno H, Ishii A, Suzuki O. 1997. Capillary Gas Chromatography with Cryogenic Oven Temperature  for  Headspace  Samples:  Analysis  of Chloroform or Methylene Chloride in Whole Blood. Anal. Chem. 69, 5178-5181.

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