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Treatment of electroplating industry wastewater using iron nanoparticle doped spent tea waste charcoal

Ramma S. Butt, Rabia Nazir, Muhammad Naeem Khan, Almas Hamid, Farah Deeba

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J. Bio. Env. Sci.5(6), 7-17, December 2014


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Potentiality of spent tea waste charcoal has been determined as low cost adsorbent for the removal of heavy metals (Nickel and Chromium) from the waste water with the three fold objective of solid waste management for effective and green treatment of heavy metals’ highly contaminated effluent. Iron nanoparticles doped tea waste charcoal (Fe-TWC) was synthesized and characterized using powder XRD, SEM and EDX. Synthesized Fe-TWC was found quite effective in removing high concentrations of Ni (II) and Cr (VI) from the simulated samples as well as actual industrial samples. Adsorption data follows Langmuir adsorption and pseudo-second order kinetic model for both the metals. Thermodynamic parameters have also been assessed. This study indicated that Fe-TWC can be used as an effective, low cost and environment friendly adsorbent for the treatment of electroplating waste effluent.


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Treatment of electroplating industry wastewater using iron nanoparticle doped spent tea waste charcoal

Ahluwalia SS, Goyal D. 2005. Removal of Heavy Metals by Waste Tea Leaves from Aqueous Solution. Engineering in Life Sciences, 5, 158-162.

Aikpokpodion P, Ipinmoroti R, Omotoso S. 2010. Biosorption of nickel (II) from aqueous solution sing waste tea (Camella cinencis) materials. American–Eurasian Journal of Toxicological Sciences, 2, 72-82.

Amarasinghe BMWPK, Williams RA. 2007. Tea waste as a low cost adsorbent for the removal of Cu and Pb from wastewater. Chemical Engineering Journal, 132, 299-309.

Argun ME, Dursun S, Ozdemir C, Karatas M. 2007. Heavy metal adsorption by modified oak sawdust: Thermodynamics and kinetics. Journal of Hazardous Materials, 141, 77-85.

Asgari G, Rahmani AR, Faradmal J, Mohammadi S, Motaleb A. 2012. Kinetic and isotherm of hexavalent chromium adsorption onto nano hydroxyapatite. Journal of Research in Health Sciences, 12, 45-53.

Boddu VM, Abburi K, Talbott JL, Smith ED. 2003. Removal of hexavalent chromium from wastewater using a new composite chitosan biosorbent. Environmental Science and Technology, 37, 4449-4456.

Boparai HK, Joseph M, O’Carroll DM. 2011. Kinetics and thermodynamics of cadmium ion removal by adsorption onto nano zerovalent iron particles. Journal of Hazardous Materials, 186, 458-465.

Brar SK, Verma M, Tyagi R, Surampalli R. 2010. Engineered nanoparticles in wastewater and wastewater sludge–Evidence and impacts. Waste Management, 30, 504-520.

Cay S, Uyanık A, Özaşık A. 2004. Single and binary component adsorption of copper (II) and cadmium (II) from aqueous solutions using tea-industry waste. Separation and Purification Technology, 38, 273-280.

Cempel M, Nikel G. 2006. Nickel: A review of its sources and environmental toxicology. Polish Journal of Environmental Studies, 15, 375-382.

Chen W, Parette R, Zou J, Cannon FS, Dempsey BA. 2007. Arsenic removal by iron-modified activated carbon. Water Research, 41, 1851-1858.

Costa M. 2003. Potential hazards of hexavalent chromate in our drinking water. Toxicology and Applied Pharmacology, 188, 1-5.

Cundy AB, Hopkinson L, Whitby RL. 2008. Use of iron-based technologies in contaminated land and groundwater remediation: A review. Science of the total environment, 400, 42-51.

Demirbas A. 2009. Agricultural based activated carbons for the removal of dyes from aqueous solutions: a review. Journal of Hazardous Materials, 167, 1-9.

Demirbas E, Kobya M, Senturk E, Ozkan T. 2004. Adsorption kinetics for the removal of chromium(VI) from aqueous solutions on the activated carbons prepared from agricultural wastes. Water SA, 30, 533-540.

Demirbas E, Kobya M, Senturk E, Ozkan T. 2004. Adsorption kinetics for the removal of chromium(VI) from aqueous solutions on the activated carbons prepared from agricultural wastes. Water S. A., 30, 533-540.

Gao P, Chen X, Shen F, Chen G. 2005. Removal of chromium (VI) from wastewater by combined electrocoagulation–electroflotation without a filter. Separation and Purification Technology, 43, 117-123.

Government of Pakistan. 1997. National Environmental Quality Standards-Pakistan Environmental Legislation.

Gzara L, Dhahbi M. 2001. Removal of chromate anions by micellar-enhanced ultrafiltration using cationic surfactants. Desalination, 137, 241-250.

Hoch LB, Mack EJ, Hydutsky BW, Hershman JM, Skluzacek JM, Mallouk TE. 2008. Carbothermal synthesis of carbon-supported nanoscale zero-valent iron particles for the remediation of hexavalent chromium. Environmental Science & Technology, 42, 2600-2605.

Hu J, Chen G, Lo IMC. 2005. Removal and recovery of Cr (VI) from wastewater by maghemite nanoparticles. Water Research, 39, 4528-4536.

Lackovic JA, Nikolaidis NP, Dobbs GM. 2000. Inorganic arsenic removal by zero-valent iron. Environmental Engineering Science, 17, 29-39.

Malkoc E. 2006. Ni (II) removal from aqueous solutions using cone biomass of Thuja orientalis. Journal of Hazardous Materials, 137, 899-908.

Malkoc E, Nuhoglu Y. 2005. Investigations of nickel (II) removal from aqueous solutions using tea factory waste. Journal of Hazardous Materials, 127, 120-128.

Malkoc E, Nuhoglu Y. 2007. Potential of tea factory waste for chromium (VI) removal from aqueous solutions: thermodynamic and kinetic studies. Separation and Purification Technology, 54, 291-298.

McAnally S, Benefield L, Reed RB. 1984. Nickel removal from a synthetic nickel-plating wastewater using sulfide and carbonate for precipitation and coprecipitation. Separation Science and Technology, 19, 191-217.

Monser L, Adhoum N. 2002. Modified activated carbon for the removal of copper, zinc, chromium and cyanide from wastewater. Separation and Purification Technology, 26, 137-146.

Owlad M, Aroua MK, Daud WAW, Baroutian S. 2009. Removal of hexavalent chromium-contaminated water and wastewater: A review. Water, Air and Soil Pollution, 200, 59-77.

Panneerselvam P, Morad N, Tan KA. 2011. Magnetic nanoparticle (Fe3O4) impregnated onto tea waste for the removal of nickel (II) from aqueous solution. Journal of Hazardous Materials, 186, 160-168.

Park SJ, Jang YS. 2002. Pore structure and surface properties of chemically modified activated carbons for adsorption mechanism and rate of Cr (VI). Journal of colloid and interface science, 249, 458-463.

Pehlivan E, Altun T. 2008. Biosorption of chromium (VI) ion from aqueous solutions using walnut, hazelnut and almond shell. Journal of Hazardous Materials, 155, 378-384.

Rafatullah M, Sulaiman O, Hashim R, Ahmad A. 2009. Adsorption of copper (II), chromium (III), nickel (II) and lead (II) ions from aqueous solutions by meranti sawdust. Journal of Hazardous Materials, 170, 969-977.

Rangsivek R, Jekel M. 2005. Removal of dissolved metals by zero-valent iron (ZVI): Kinetics, equilibria, processes and implications for stormwater runoff treatment. Water Research, 39, 4153-4163.

Rengaraj S, Joo CK, Kim Y, Yi J. 2003. Kinetics of removal of chromium from water and electronic process wastewater by ion exchange resins: 1200H, 1500H and IRN97H. Journal of Hazardous Materials, 102, 257-275.

Royle H. 1975. Toxicity of chromic acid in the chromium plating industry. Journal of Hazardous Materials, 10, 39-53.

Shaikh MS, Qureshi K, Bhatti I. 2011. Utilization of tea waste for the removal of arsenic (III) from aqueous solution. Sindh Univ. Res. Jour. (Sci. Ser.), 43, 97-104.

Uddin MT, Islam MA, Mahmud S, Rukanuzzaman M. 2009. Adsorptive removal of methylene blue by tea waste. Journal of Hazardous Materials, 164, 53-60.

Veglio F, Beolchini F. 1997. Removal of metals by biosorption: A review. Hydrometallurgy, 44, 301-316.

Wang Y, Wang X, Wang X, Liu M, Wu Z, Yang L, Xia S, Zhao J. 2013. Adsorption of Pb (II) from aqueous  solution  to  Ni-doped  bamboo  charcoal. Journal of Industrial and Engineering Chemistry, 19, 353-359.