Synthesis and characterization of TiO2 nanoparticle infused with MMT for testing its antibacterial efficacy

Paper Details

Research Paper 13/11/2023
Views (267) Download (53)
current_issue_feature_image
publication_file

Synthesis and characterization of TiO2 nanoparticle infused with MMT for testing its antibacterial efficacy

CI. Anish, M. Jaya Rajan
J. Bio. Env. Sci.23( 5), 72-80, November 2023.
Certificate: JBES 2023 [Generate Certificate]

Abstract

Bio nanocomposite clay-based material Montmorillonite (MMT) and Titanium dioxide (TiO2) are modified for the application to antibacterial effect in waste water. TiO2 is employed because of its photostability, nontoxicity, high activity, and relatively low cost. In that view, the current study investigates the antibacterial potentials of TiO2/MMT nanocomposite formed by the hydrothermal synthesis route. The physicochemical properties of the formed TiO2/MMT nanocomposite were characterized by the powdered XRD, SEM, EDAX, BET, FTIR, and UV-Visible spectroscopies. The crystallinity and crystal structure are confirmed by the XRD, the bonding information and surface functionality by the FTIR, and the morphology and elemental composition with the SEM/EDAX analysis. From the BET investigations, the structural morphology of TiO2/MMT nanocomposite showed an improved pore volume, surface area, and voids, while the optical properties of TiO2 nanoparticles significantly enhanced following the composite formation with that of MMT. Further tests of antibacterial activity of TiO2/MMT nanocomposite towards Gram-positive (Bacillus cereus, Enterococcus and Staphylococcus aureus) and Gram-negative (Escheria coli and Pseudomonas aeruginosa) bacteria supported the efficiency of prepared composite and thereby confirming its promising potentials in the applications related to microbial removal from wastewater.

VIEWS 74

Jesus AML, Ferreira AM, Lima LFS, Batista GF, Mambrini RV, Mohallem NDS. 2021. Micro-mesoporous TiO2/SiO2 nanocomposites: Sol-gel synthesis, characterization, and enhanced photodegradation of quinoline, Ceramics International 47( 17), 23844-23850.

Takari A, Ghasemi AR, Hamadanian M, Sarafrazi M, Najafidoust A. 2021. Molecular dynamics simulation and thermo-mechanical characterization for optimization of three-phase epoxy/TiO2/SiO2 nano-composites. Polymer Testing 93, 106890.

Bilgic A. 2022. Fabrication of mono BODIPY-functionalized Fe3O4@SiO2@TiO2 nanoparticles for the photocatalytic degradation of rhodamine B under UV irradiation and the detection and removal of Cu(II) ions in aqueous solutions, Journal of Alloys Compounds 899, 163360.

Bayal N, Singh R, Polshettiwar V. 2017. Nanostructured Silica-Titania Hybrid using Fibrous Nanosilica as Photocatalysts. Chemical Sustainable Chemistry 10(10), 2182-2191.

Butman MF, Gushchin AA, Ovchinnikov NL, Gusev GI, Zinenko NV, Karamysheva SP, Krämer KW. 2020. Synergistic Effect of Dielectric Barrier Discharge Plasma and TiO2-Pillared Montmorillonite on the Degradation of Rhodamine B in an Aqueous Solution. Catalysts 10, 359.

Carolin CF, Kumar PS, Saravanan A, Joshiba GJ, Naushad M. 2017. Efficient techniques for the removal of toxic heavy metals from aquatic environment: A review, Journal of Environmental Chemical Engineering 5 (3), 2017,

Pragathiswaran C, Smitha C, Abbubakkar BM, Govindhan P, Krishnan NA. 2021. Synthesis and characterization of TiO2/ZnO–Ag nanocomposite for photocatalytic degradation of dyes and anti-microbial activity, Materials Today: Proceedings, 3357-3364.

Daniel Sam N, Anish CI, Sabeena G, Rajaduraipandian S, Gandhimathi S, Annadurai G, Jaya Rajan M. 2021. Synthesis and Characterization of TiO2-CeO2 (TiO2-Ce) Nanocomposite: Testing its antibacterial effect, Research Journal of Chemistry and Environment 25(10), 13-19.

Kadhim FJ, Hammadi OA, Muthesher NH. 2022. Photocatalytic activity of TiO2/SiO2 nanocomposites synthesized by reactive magnetron sputtering technique, Journal of Nanophotonics 16(2), 026005.

Ghanbari S, Givianrad MH, Aberoom, Azar P. 2020. Synthesis and characterization of visible light-driven N-Fe-co-doped TiO2/SiO2 for simultaneous photo removal of Cr (VI) and AZO dyes in a novel fixed bed continuous flow photoreactor, Canadian Journal of Chemical Engineering 98, 705–716.

Hassani A, Khataee A, Karaca S, Fathinia M. 2016. Heterogeneous photocatalytic ozonation of ciprofloxacin using synthesized titanium dioxide nanoparticles on a montmorillonite support: Parametric studies, mechanistic analysis and intermediates identification. Royal Society of Chemistry Advances 6, 87569–87583.

Yang J, Liang Q. 2019. TiO2/SiO2 membrane materials via a sol–gel process: preparation and characterization calcined under N2 atmosphere, Ferroelectrics, 547:1, 10-20.

Joseph CG, Taufiq-Yap YH, Letshmanan E,  Vijayan. 2022. Heterogeneous photocatalytic chlorination of methylene blue using a newly synthesized TiO2-SiO2 photocatalyst. Catalysts 12(2), 156.

Vardhan KH, Kumar PS, Panda RC. 2019. A review on heavy metal pollution, toxicity and remedial measures: Current trends and future perspectives. Journal of Molecular Liquids 290, 111197.

Kumar PS. 2021. Modern Treatment Strategies for Marine Pollution, Chapter One e Introduction to Marine Biology, pp. 1-10. DOI:10.1016/B978-0-12-822279-9.00008-7

Malkappa K, Rao BN, Suresh G. 2018. Organic/inorganic hybrid nanocolloids of water dispersible polyurethanes with antibacterial activity. Colloid Polymer Science 296, 95–106.

Villarín MC, Merel S. 2020. Paradigm shifts and current challenges in wastewater management, Journal of Hazardous Materials 390, 122139.

Ruchianwar N, Bamne A,    Singh J,   Sharma N,   Singh PK,   Umar P,   Haque A, Fozia. 2022. Synthesis of titania/silica nanocomposite for enhanced photodegradation of methylene blue and methyl orange dyes under UV and mercury lights.  Journal of Environmental Science Materials Manufacturing  16, 2576-9898.

YerliSoylu N, Soylu A, Dikmetas DN, Karbancioglu-Guler F, Kucukbayrak S, ErolTaygun M. 2023. Photocatalytic and Antimicrobial Properties of Electrospun TiO2–SiO2–Al2O3–ZrO2–CaO–CeO2 Ceramic Membranes ACS Omega 8(12), 10836-10850.

Nabih S, Shalan AE, Abu Serea, ES, Goda MA, Sanad, MF. 2019, Photocatalytic performance of TiO2/SiO2 nanocomposites for the treatment of different organic dyes, Journal of Material Science 3010, 9623- 9633. Pages 2782-2799, ISSN 2213-3437,

Palhares HG, Nunes EHM, Houmard M. 2021. Heat treatment as a key factor for enhancing the photodegradation performance of hydrothermally-treated sol–gel TiO2–SiO2 nanocomposites. Journal of  Sol-Gel Science and Technology 99, 188–197.

Parand P, Mohammadi M, Akmal AAS, samadpour M, Dehghani  M, Parvazian E. (2020). Sequential RTV/(TiO2/SiO2) nanocomposite deposition for suppressing the leakage current in silicone rubber insulators. Applied Physics A. 126(5).

Prasannamedha G, Kumar PS, Mehala R, Sharumitha TJ, Surendhar D. 2021. Enhanced adsorptive removal of sulfamethoxazole from water using biochar derived from hydrothermal carbonization of sugarcane bagasse. Journal of Hazard Materials 407, 124825.

Eddy DR, Ishmah  SN,  Permana MD, Firdaus ML. 2020. Synthesis of titanium dioxide/silicon dioxide from beach sand as photocatalyst for Cr and Pb Remediation. Catalysts 10(11), 1248.

Ranjbar M, Taher MA, Sam A. 2016. Single-step synthesis of SiO2–TiO2hydrophobic core–shell nanocomposite by hydrothermal method. Journal of Cluster Science 27, 583–592.

Rasouli F, Aber S, Salari D, Khataee AR. 2014.  Optimized removal of Reactive Navy Blue SP-BR by organo-montmorillonite based adsorbents through central composite design. Applied Clay Science 87, 228–234.

Ting Wang, Li Y, Wu W-T, Zhang Y-l, Wu L-G, Chen H-lI. 2021. Effect of chiral-arrangement on the solar adsorption of black TiO2-SiO2mesoporous materials for photodegradation and photolysis, Applied Surface Science 537, 148025.

Mahanta U, Khandelwal M, Deshpande AS. 2022. TiO2@SiO2 nanoparticles for methylene blue removal and photocatalytic degradation under natural sunlight and low-power UV light, Applied Surface Science 576, Part A, 151745.

Van Hung N, Nguyet BTM, Nghi NH, Nguyen VT, Binh TV, Tu NTT, Dung NN, Khieu DQ. 2021. Visible light photocatalytic degradation of organic dyes using W-modified TiO2/SiO2 catalyst. Vietnam Journal of Chemistry 59, 620-638.

Waran P, Pp G. 2016.  Synthesis and characterization of TiO2@SiO2–Ag nanocomposites towards photocatalytic degradation of rhodamine B and methylene blue. Journal of  Material Science. Materials Electronics 27(8).

Zeng L, Sun H, Peng T, Lv X. 2019. Comparison of the Phase Transition and Degradation of Methylene Blue of TiO2, TiO2/Montmorillonite Mixture and TiO2/Montmorillonite Composite. Frontier Chemistry 7, 538.