Characterization studies of activated carbon prepared from agricultural wastes of Vachellia nilotica

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Research Paper 06/09/2024
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Characterization studies of activated carbon prepared from agricultural wastes of Vachellia nilotica

R. Beautlin Nisha, M. Jaya Rajan
J. Bio. Env. Sci.25( 3), 94-101, September 2024.
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Abstract

In this study, Vachellia nilotica was utilized to formulate initiated activated carbon (AC), which was then incubated with potassium hydroxide at 600°C for two hours. FTIR, TGA/DTA, and SEM/EDAX were used to characterize the functional groups, surface shape, thermal stability, and elemental identification of the activated carbon. Furthermore, the efficacy of the AC remediation was evaluated using dye (Congo Red) under different conditions, such as pH and dose, and the maximum amount of Congo Red that the adsorptive material could absorb was measured using the Langmuir and Freundlich adsorption isotherm principles. The Langmuir isotherm model fits the maximal dye adsorption capacity well, which was attained at 24.35 g/L. In order to improve (raise) the water’s potability level, the research’s findings suggest that Vachellia nilotica may be used as a cost-effective and capable raw material to create initiated carbon for wastewater treatment.

VIEWS 49

Abisha BR, Anish CI, Beautlin Nisha R, Daniel Sam N, Jaya Rajan M. 2021. Adsorption and equilibrium studies of methyl orange on tamarind shell activated carbon and their characterization. Phosphorus Sulphur and Silicon and the Related Elements 197(3), 225-230. https://doi.org/10.1080/10426507.2021.1993849.

Banerjee S, Chattopadhyaya MC. 2017. Adsorption characteristics for the removal of a toxic dye, tartrazine from aqueous solutions by a low-cost agricultural by-product. Arabian Journal of Chemistry 10(Sup.2), S1629-S1638.

Bergaoui M, Nakhli A, Benguerba Y, Khalfaoui M, Erto A, Soetaredjo FE, Ismadji S, Ernst B. 2018. Novel insights into the adsorption mechanism of methylene blue onto organo-bentonite: Adsorption isotherms modeling and molecular simulation. J Mol Liq 272, 697-707. https://doi.org/10.1016/j.molliq.2018.10.001

Cheng Y, Zhou QX, Ma QY. 2003. Advances in dye wastewater treatment technology. Environmental Pollution Control Technologies and Equipment 46, 56-60.

Egbosiuba TC, Abdulkareem AS, Kovo AS, Afolabi EA, Tijani JO, Auta M, Roos WD. 2020. Ultrasonic enhanced adsorption of methylene blue onto the optimized surface area of activated carbon: Adsorption isotherm, kinetics and thermodynamics. Chem Eng Res Des 153, 315-336. https://doi.org/10.1016/j.cherd.2019.10.016

Hagemann N, Spokas K, Schmidt HP, Kägi R, Böhler M, Bucheli T. 2018. Activated carbon, biochar and charcoal: linkages and synergies across pyrogenic carbon’s ABCs. Water 10(2), 182.

Inthapanya X, Wu S, Han Z, Zeng G, Wu M, Yang C. 2019. Adsorptive removal of anionic dye using calcined oyster shells: isotherms, kinetics, and thermodynamics. Environ Sci Pollut Res Int 26, 5944.

Jain R, Sikarwar S. 2013. Adsorption and desorption studies of Congo red using low-cost adsorbent: Activated de-oiled mustard. Desalination and Water Treatment 52, 7400-7411. https://doi.org/10.1080/19443994.2013.837004

Jaishankar M, Tseten T, Anbalagan N, Mathew BB, Beeregowda KN. 2014. Toxicity, mechanism, and health effects of some heavy metals. Interdiscip Toxicol 7(2), 60-72. https://doi.org/10.2478/INTOX-2014-0009

Jayarajan M, Arunachala R, Gurusamy A. 2011. Use of low-cost nano-porous materials of pomelo fruit peel wastes in removal of textile dye. Res J Environ Sci 5, 434-443. https://doi.org/10.3923/rjes.2011.434.443

Jayarajan M, Arunachalam R, Annadurai G. 2011. Agricultural wastes of jackfruit peel nano-porous adsorbent for removal of rhodamine dye. Asian J Appl Sci 4(3), 263-270. https://doi.org/10.3923/ajaps.2011.263.270

Li T, Du Q, Wang X, Xia Y. 2010. Removal of lead from aqueous solution by activated carbon prepared from Enteromorpha prolifera by zinc chloride activation. Journal of Hazardous Materials 183, 583–589.

Lina Y, Wu S, Li X, Wu X, Yang C, Zeng G, Peng Y, Zhou Q, Lu L. 2018. Appl Catal B 227, 557.

Ozer C, Imamoglu M, Turhan Y, Boysan F. 2012. Removal of methylene blue from aqueous solutions using phosphoric acid activated carbon produced from hazelnut husks. Toxicol Environ Chem 94, 1283. https://doi.org/10.1080/02772248.2012.717669

Rashid RA, Jawad AH, Ishak MABM, Kasim NN. 2018. Sains Malays 47, 603.

Selvarajan P, Fawaz M, Sathish CI, Li M, Chu D, Yu X, Breesec MBH, Yi J, Vinu A. 2021. Activated graphene nanoplatelets decorated with carbon nitrides for efficient electrocatalytic oxygen reduction reaction. Advanced Energy and Sustainability Research 2100104, 1–11. https://doi.org/10.1002/aesr.202100104.

Uner O, Geçgel U, Bayrak Y. 2016. Adsorption of methylene blue by an efficient activated carbon prepared from Citrullus lanatus rind: Kinetic, isotherm, thermodynamic, and mechanism analysis. Water Air Soil Pollut 227, 247.

Yadav S, Yadav A, Bagotia N, Sharma AK, Kumar S. 2021. Adsorptive potential of modified plant-based adsorbents for sequestration of dyes and heavy metals from wastewater – A review. J Water Process Eng 42. https://doi.org/10.1016/j.jwpe.2021.102148.