Detection and Identification of multiresidual Pesticides in Water of Hudiara Drain and Its Adjoining Areas

Paper Details

Research Paper 01/11/2021
Views (564) Download (25)
current_issue_feature_image
publication_file

Detection and Identification of multiresidual Pesticides in Water of Hudiara Drain and Its Adjoining Areas

Zahra Asghar, Saima Atif, Dr Numrah Nisar, Prof. Dr Tahira Aziz Mughal
Int. J. Biosci.19( 5), 137-147, November 2021.
Certificate: IJB 2021 [Generate Certificate]

Abstract

Pesticides play a vital role in green revolution by boosting the quality and quantity crops. The present study was designed for the detection and identification of multiresidual pesticides in water. The sources of environmental water samples were surface water and drinking water taken from the adjoining areas of Hudiara drain. An analytical method was produced and optimized for the detection and quantification of selected OPPs based on solid-phase extraction and high-performance liquid chromatography, coupled with a diode array detector (SPE–HPLC–DAD). The chromatographic separation was done using C18 column. Different organophosphorus pesticides (OPPs) were determined having specific peak areas, peak numbers, and their retention times along with their chemical structures. Each subsequent pesticide shows a unique behavior in three different solvents i.e., methanol, ethanol and acetonitrile in the water samples for the optimization of micro-pesticides in drinking water. The presence of large amount of pesticides in the sampling areas is due to the manufacturing industry for pesticides and agriculture farms in the adjoining areas. The measures should be taken for monitoring and controlling the use of pesticides according to permissible limits.

VIEWS 32

Affum AO, Acquaah SO, Osae SD, Kwaansa-Ansah EE. 2018. Distribution and risk assessment of banned and other current-use pesticides in surface and groundwaters consumed in an agricultural catchment dominated by cocoa crops in the Ankobra Basin, Ghana. Science of the Total Environment 633, 630-640.

Appannagari RR. 2017. Environmental pollution causes and consequences: A study. North Asian International Research Journal of Social Science & Humanities 3(8), 2454-9827.

Caldas SS, Bolzan CM, Guilherme JR, Kisner Silveira MA, Venquiaruti Escarrone AL, Primel EG. 2013. Determination of pharmaceuticals, personal care products, and pesticides in surface and treated waters: Method development and survey. Environmental science and pollution research international 20(8), 5855–5863.

Daughton CG. 2003. Cradle-to-cradle stewardship of drugs for minimizing their environmental disposition while promoting human health. I. Rationale for and avenues toward a green pharmacy. Environmental Health Perspectives 111(5), 757-774

Emad Soliman A, Ahmed El-Moghazy Y, Mohammed Mohy El-Din S, Magdy A. Massoud. 2013. Microencapsulation of Essential Oils within Alginate: Formulation and in Vitro Evaluation of Antifungal Activity, Journal of Encapsulation and Adsorption Sciences 3(1), Article ID:29469,8 pages

Feng J, Loussala HM, Han S, Ji X, Li C,  Sun M. 2020. Recent advances of ionic liquids in sample preparation. TrAC Trends in Analytical Chemistry 125, 115833.

Heberer T. 2002. Tracking persistent pharmaceutical residues from municipal sewage to drinking water. Journal of Hydrology 266(3), 175-189.

Lishman L, Smyth SA, Sarafin K, Kleywegt S, Toito J, Peart T, Lee B, Servos M, Beland M, Seto P. 2006. Occurrence and reductions of pharmaceuticals and personal care products and estrogens by municipal wastewater treatment plants in Ontario, Canada. Science of the Total Environment 367(2-3), 544-558.

Murray KE, Thomas, MS, Bodour AA. 2010. Prioritizing research for trace pollutants and emerging contaminants in the freshwater environment. Environmental Pollution 158, 3462-3471.

Sanchez-Gonzalez S, Pose-Juan E, Herrero-Hernandez E, Alvarez-Martin A, Jesus Sanchez-Martin M, Rodriguez-Cruz S. 2013. Pesticide residues in ground waters and soils of agricultural areas in the Agueda River Basin from Spain and Portugal. International Journal of Environmental Analytical chemistry 93(15), 1585–1601.

Tankiewicz M, Biziuk M. 2018. Fast, sensitive and reliable multi-residue method for routine determination of 34 pesticides from various chemical groups in water samples by using dispersive liquid–liquid microextraction coupled with gas chromatography–mass spectrometry. Analytical and bioanalytical chemistry 410(5), 1533-1550.

Wang X, Li P. 2015. Rapid screening of mycotoxins in liquid milk and milk powder by automated size-exclusion SPE-UPLC–MS/MS and quantification of matrix effects over the whole chromatographic run. Food chemistry 173, 897-904.

Wee YS, Omar TFT, Aris ZA, Lee Y. 2016. Surface Water Organophosphorus Pesticides Concentration and Distribution in the Langat River, Selangor, Malaysia. Exposure and Health 8, 497–511

Yang Y, Yin S, Wu L, Li Y, Sun C. 2021. Application of ionic liquid-based air-assisted dispersive liquid–liquid microextraction combined with high-performance liquid chromatography for the determination of six tetracyclines in honey. European Food Research and Technology 247(11), 2777-2785.

Yu J. 2015. Investigation on pesticide residues in rural drinking water in typical provinces of north and south China. International Journal of Environmental Research and Public Health 32, 721–723.

Zhang X, Zhao Y, Cui X, Wang X, Shen H, Chen Z, Luo F. 2018. Application and enantiomeric residue determination of diniconazole in tea and grape and apple by supercritical fluid chromatography coupled with quadrupole-time-of-flight mass spectrometry. Journal of Chromatography A, 1581, 144-155.