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Removal of Ni(II), Cd(II) and Cr(III) from industrial wastewater by raw and modified cotton stalk

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Research Paper 01/10/2014
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Removal of Ni(II), Cd(II) and Cr(III) from industrial wastewater by raw and modified cotton stalk

S. Dehghani, M. Esteki, S. F. Mousavi, B. Mostafazadeh-Fard
J. Bio. Env. Sci.5( 4), 579-592, October 2014.
Certificate: JBES 2014 [Generate Certificate]
Key: BiosorptionCotton stalkIsothermsReal WastewaterSurfactant

Abstract

Waste cotton stalk (CS) and surfactant modified CS (SMCS) biosorbents were evaluated for their ability to remove Ni(II), Cd(II), and Cr(III) ions from wastewater. Sodium dodecyl sulfate (SDS), a commonly used surfactant, was used to modify the raw biomass. The CS and SMCS biosorbents were characterized with Fourier transform infrared (FTIR) spectroscopy and scanning electron microscopy (SEM). The effects of several parameters, such as initial heavy metal (HM) concentration, pH of the solution, charge and concentration of the surfactant, on the sorptive properties of the SMCS were also investigated. The results showed that surfactant modification improved HM removal by the biosorbents, especially when concentration was below the critical micelle concentration (CMC). The trend of HM ions uptaken by the SMCS followed the order of Cr(III) > Ni(II) > Cd(II). Maximum HM removal efficiency of 100% was achieved for Cr(III) and ≥ 90% for Ni(II) and Cd(II) in concentration range of 1-100 mg L-1. Sorption equilibrium data of HM on the biosorbents were analyzed and the results demonstrated that the most appropriate models to simulate the isotherms were Langmuir and Freundlich equations.

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Arief VO, Trilestari K, Sunarso J, Indraswati N, Ismadji S. 2008. Recent progress on biosorption of heavy metals from liquids using low cost biosorbents: Characterization, biosorption parameters and mechanism studies. Clean- Soil, Air, Water 36, 937-962.

Boeriu C, Bravo D, Gosselink R, van Dam J. 2004. Characterization of structure-dependent functional properties of lignin with infrared spectroscopy. Industrial Crops and Products 20, 205-218.

Chung C, Myunghee L, Choe E. 2004. Characterization of cotton fabric scouring by FT-IR ATR spectroscopy. Carbohydrate Polymers 58, 417-420.

Chabani M, Amrane A, Bensmaili A. 2009. Equilibrium sorption isotherms for nitrate on resin Amberlite IRA 400. Journal of Hazardous Materials 165, 27-33.

Çetin T, Ülgen A, Tokalıoğlu Ş. 2011. On-line solid phase extraction of copper in water samples with flow injection flame atomic absorption spectrometry. Clean- Soil, Air, Water 39, 244-249.

Chen H, Zhao J, Wu J, Dai G. 2011. Isotherm, thermodynamic, kinetics and adsorption mechanism studies of methyl orange by surfactant modified silkworm exuviae. Journal of Hazardous Materials 192, 246- 254.

Das D, Basak G, Lakshmi V, Das N. 2012. Kinetics and equilibrium studies on removal of zinc(II) by untreated and anionic surfactant treated dead biomass of yeast: Batch and column mode. Biochemical Engineering Journal 64, 30-47.

Dharnaik AS, Ghosh PK. 2014. Hexavalent chromium [Cr(VI)] removal by the electrochemical ion-exchange process. Environmental Technology 35, 2272-2279.

Djedidi Z, Bouda M, Souissi MA, Cheikh RB, Mercier G , Tyagi RD, Blais JF. 2009. Metals removal from soil, fly ash and sewage sludge leachates by precipitation and dewatering properties of the generated sludge. Journal of Hazardous Materials 172, 1372-1382.

Himmelsbach D, Akin D, Kim J, Hardin I. 2003. Chemical structural investigation of the cotton fiber base and associated seed coat: Fourier-transform infrared mapping and histochemistry. Textile Research Journal 73, 218-288.

Hull M, Kitchener JA. 1969. Interaction of spherical colloidal particles with planar surfaces. Transactions of the Faraday Society 65, 3093.

Krauter P, Martinelli R, Williams K, Martins S. 1996. Removal of Cr(VI) from ground water by Saccharomyces cerevisiae. Biodegradation 7, 277-286.

Litton GM, Olson TM. 1994. Colloid deposition kinetics with surface-active agents: Evidence for discrete surface charge effects. Journal of Colloid and Interface Science 165, 522.

Lin SY, Keigue K, Malderelli C. 1990. Diffusion-controlled surface adsorption studied by pendant drop digitization. AIChE Journal 36, 1785-1795.

Lodeiro P, Barriada JL, Herrero R, Vicente MES. 2006. The marine macroalga Cystoseira baccata as biosorbent for cadmium(II) and lead(II removal: Kinetic and equilibrium studies. Environmental Pollution 142, 264-273.).

Martinez SL, Jèsus VT, Minguela V, Siñeriz F, Raboni M, Copelli S, Rada EC, Ragazzi M. 2014. Treatment of slaughterhouse wastewaters using anaerobic filters. Environmental Technology 35, 322-332.

Martín-Lara MÁ, Rodríguez Rico IL, Alomá Vicente IC, Hoces GB. 2010. Modification of the sorptive characteristics of sugarcane bagasse for removing lead from aqueous solutions. Desalination 256, 58-63.

Martín-Lara MA, Pagnanelli F, Mainelli S, Calero M, Torob L. 2008. Chemical treatment of olive pomace: Effect on acid-basic properties and metal biosorption capacity. Journal of Hazardous Materials 156, 448-457.

Mathialagon T, Viraraghavan T. 2002. Adsorption of cadmium from aqueous solutions by perlite. Journal of Hazardous Materials 94, 291-303.

Miretzky P, Cirelli AF. 2010. Cr(VI) and Cr(III) removal from aqueous solution by raw and modified lignocellulosic materials: A review. Journal of Hazardous Materials 180, 1-19.

Myllytie P, Salmi J, Laine J. 2009. The influence of pH on the adsorption and interaction of chitosan with cellulose. BioResources 4, 1647-1662.

Naumczyk J, Bogacki J, Piotr Marcinowski, Paweł Kowalik. 2014. Cosmetic wastewater treatment by coagulation and advanced oxidation processes. Environmental Technology 35, 541-548.

Nigmatullin R, Lovitt R, Wright C, Linder M, Nakari-Setälä T, Gama M. 2004. Atomic force microscopy study of cellulose surface interaction controlled by cellulose binding domains. Colloids and Surfaces B 35, 125-135.

Ofomaja AE, Naidoo EB, Modise SJ. 2010. Dynamic studies and pseudo-second order modeling of copper(II) biosorption onto pine cone powder. Desalination 251, 112-122.

Paria S, Khilar KC. 2004. A review on experimental studies of surfactant adsorption at the hydrophilic solid–water interface. Advances in Colloid and Interface Science 110, 75-95.

Reddy DHK, Ramana DKV, Seshaiah K, Reddy AVR. 2011. Biosorption of Ni(II) from aqueous phase by  Moringa  oleifera  bark,  a  low  cost  biosorbent. Desalination 268, 150-157.

Rao RAK, Khan MA, Jeon BH. 2010. Utilization of carbon derived from mustard oil cake (CMOC) for the removal of bivalent metal ions: Effect of anionic surfactant on the removal and recovery. Journal of Hazardous Materials 173, 273-282.

Rosen MJ. 2004. Surfactant and interfacial phenomena. Third ed. John Wiley & Sons Inc. 63 p.

Rosen MJ. 2004. Surfactant and interfacial phenomena. Third ed, John Wiley & Sons Inc, 409 p.

Rosales E, Pazos M, Sanromán MA, Tavares T. 2012. Application of zeolite-Arthrobacter viscosus system for the removal of heavy metal and dye: Chromium and Azure B. Desalination 284, 150-156.

Sud D, Mahajan G, Kaur MP. 2008. Agricultural waste material as potential adsorbent for sequestering heavy metal ions from aqueous solutions- A review. Bioresource Technology 99, 6017-6027.

Senturk HB, Ozdes D, Duran C. 2010. Biosorption of Rhodamine 6G from aqueous solutions onto almond shell (Prunus dulcis) as a low cost biosorbent. Desalination 252, 81-87.

Silverstein R, Webster F. 1998. Spectrometric identification of organic compounds. John Wiley & Sons Ltd., Toronto, Canada.

Sips R. 1948. Combined form of Langmuir and Freundlich equations. Biochemical Engineering Journal 16, 490-495.

Wang J, Chen C. 2009. Biosorbents for heavy metals removal and their future. Biotechnology Advances 27, 195-226.

Witek-Krowiak  A,  Szafran  RG,  Modelski  S. 2011. Biosorption of heavy metals from aqueous solutions onto peanut shell as a low-cost biosorbent. Desalination 265, 126-134.

Yusan S, Erenturk SA. 2010. Adsorption equilibrium and kinetics of  U(VI) on beta type of akaganeite. Desalination 263, 233-239.

Zeng Y, Woo H, Lee H, Park J. 2010. Removal of chromate from water using surfactant modified Pohang clinoptilolite and Haruna chabazite. Desalination 257, 102-109.

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