home icon user icon
Welcome to International Network for Natural Sciences | INNS Pub.
Home My Account
Submit Manuscript
double_slash
breadcumb_bg

Studies on synthesis, characterization and photocatalytic activity of activated charcoal doped chitosan (AC-CS)

Paper Details

Research Paper 18/05/2023
Views (188) Download (21)
current_issue_feature_image
publication_file

Studies on synthesis, characterization and photocatalytic activity of activated charcoal doped chitosan (AC-CS)

P. Bhuvaneswari, T. Shanmugavadivu, G. Sabeena, G. Annadurai, E. Sindhuja
J. Bio. Env. Sci.22( 5), 134-142, May 2023.
Certificate: JBES 2023 [Generate Certificate]
Key: Activated carbonChitosanFTIRMalachite green dyePhotocatalytic activitySEMTGA

Abstract

In this study, activated charcoal doped chitosan (AC-CS) was effectively synthesized, and the material was then examined using XRD, FTIR, SEM-EDX, and UV. Results demonstrate that activated charcoal doped chitosan (AC-CS) has a characteristic binding crystalline structure with an average size of 50nm and aggregates of minute fibres in diverse sizes and shapes. Chitosan doped with activated charcoal exhibits UV absorption bands with maximal wavelengths at 308nm. To evaluate the photocatalytic performance of the activated charcoal doped chitosan (AC-CS), Malachite Green dye degradation was utilized. Chitosan that has been doped with activated charcoal (AC-CS) was applied to boost the photocatalytic activity towards the Malachite Green dye. The performance of the photocatalytic reaction was significantly improved by supporting the active charcoal doped chitosan (AC-CS).

VIEWS 24
Cover PDF

Abdel HA, Saad AM, Azzam ST, El-Wakeel BB, Mostafa MB. 2018. Removal of toxic metal ions from wastewater using ZnO@Chitosan cores hell nanocomposite. Environmental Nanotechnology, Monitoring & Management. l 9, 67-75.

Afzal MZ, Sun XF, Liu J. 2018. Enhancement of ciprofloxacin sorption on chitosan/biochar hydrogel beads. Sci Total Environ 639, 560-569.

Ajmal A, Majeed I, Malik RN, Idriss H, Nadeem MA. 2014. Principles and mechanisms of photocatalytic dye degradation on TiO2based photocatalysts: a comparative overview. RSC Adv 4(70), 37003-37026.

Annu A, Raja AN. 2020. Recent development in chitosan-based electrochemical sensors and its sensing application, Int. J. Biol. Macromol 164, 4231-4244,

Aragunde H, Biarnés X, Planas A. 2018. Substrate recognition and specificity of chitin deacetylases and related family 4 carbohydrate esterases. Int J Mol Sci 19, 412

Bhadra P, Mitra MK, Das GC, Dey R, Mukherjee S. 2011. Interaction of chitosan capped ZnO nanorods with Escherichia coli,” Materials Science and Engineering C. 31(5), 929-937.

Bhattacharyya S, Wang H, Ducheyne P. 2012. Polymer-coated mesoporous silica nanoparticles for the controlled release of macromolecules. Acta Biomater 8(9), 3429-3435.

Bhuvaneswari P, Shanmugavadivu T, Sabeena G, Annadurai G, Sindhuja E. 2022. Synthesis and Characterization of Chitosan with Silica (CS) Nanocomposite with Enhanced Antibacterial Activity. Int. J. Res. Pharm. Sci 13(1), 1-8

Budnyak TM, Yanovska ES, Kołodyńska D, Sternik D, Pylypchuk IV, Ischenko MV, Tertykh VA. 2016. Preparation and properties of organomineral adsorbent obtained by sol-gel technology. Journal of Thermal Analysis and Calorimetry 125(3), 1335-1351.

Costa EM, Silva S, Pina C, Tavaria FK, Pintado MM. 2012. Evaluation and insights into chitosan antimicrobial activity against anaerobic oral pathogens. Anaerobe 18(3), 305-309.

Dai K, Zhang X, Fan K. 2013. Hydrothermal synthesis of single-walled carbon nanotube-TiO2 hybrid and its photocatalytic activity. Appl Surf Sci 270, 238-244

Fu YN, Li Y, Li G, Yang L, Yuan Q, Tao L, Wang X. 2017. Adaptive chitosan hollow microspheres as efficient drug carrier. Biomacromolecules 18(7), 2195-2204.

Gong J, Wang X, Shao X, Yuan S, Yang C, Hu X. 2012. Adsorption of heavy metal ions by hierarchically structured magnetite-carbonaceous spheres. Talanta 101, 45-52.

Hasmath Farzana M, Meenakshi S. 2015. Visible light-driven photoactivity of zinc oxide impregnated chitosanbeads for the detoxification of textile dyes. Applied Catalysis A: General 503, 124-134.

Hassan M, Abou-Zeid R, Hassan E. 2017. Membranes based on cellulose nanofibers and activated carbon for removal of Escherichia coli bacteria from water. Polymers (Basel) 9(8), 335.

He Q, Shi J. 2011. Mesoporous silica nanoparticle based nano drug delivery systems: synthesis, controlled drug release and delivery, pharmacokinetics and biocompatibility. Journal of Materials Chemistry 21(16), 5845.

Huang Z, Li Z, Zheng L. 2017. Interaction mechanism of uranium (VI) with three-dimensional graphene oxide-chitosan composite: Insights from batch experiments, IR, XPS, and EXAFS spectroscopy. Chemical Engineering Journal 328, 066-1074.

Jung KW, Choi BH, Hwang MJ. 2016a. Fabrication of granular activated carbons derived from spent coffee grounds by entrapment in calcium alginate beads for adsorption of acid orange 7 and methylene blue. Bioresour Technol 219, 185-195.

Jung KW, Jeong TU, Kang HJ, Ahn KH. 2016b. Characteristics of biochar derived from marine macroalgae and fabrication of granular biochar by entrapment in calcium-alginate beads for phosphate removal from aqueous solution. Bioresour Technol 211, 108-116.

Jurkic LM, Cepanec I, Pavelic SK, Pavelic K. 2013. Biological and therapeutic effects of ortho-silicic acid and some ortho-silicic acid-releasing compounds: New perspectives for therapy. Nutrition & Metabolism 10(1), 2.

Li LH, Deng JC, Deng HR, Liu ZL, Xin L. 2010. Synthesis and characterization of chitosan/ZnO nanoparticle composite membranes. Carbohydrate Research 345(8), 994-998.

Lijun You CI, Huang LU, Feifei AO, Wang Xiaocui Liu, Zhang Q. 2018. Facile synthesis of high performance porous magnetic chitosan-polyethylenimine polymer composite for Congo red removal, International Journal of Biological Macromolecules 107, 1620-1628.

Liu X. Tian J, Li Y. 2019. Enhanced dyes adsorption from wastewater via Fe3O4 nanoparticles functionalized activated carbon, Journal of Hazardous Materials 373, 397-407.

Maldiney T, Kaikkonen MU, Seguin J, Quentin Bessodes M, Airenne KJ, Seppo Yla, Scherman D, Richard C. 2012. In vitro Targeting of Avidin-Expressing Glioma Cells with Biotinylated Persistent Luminescence Nanoparticles 23(3), 472-478.

Manzoor K, Ahmad M, Ahmad S, Ikram S. 2019. Chapter 2-resorbable biomaterials: role of chitosan as a graft in bone tissue engineering, in: Materials for Biomedical Engineering, Elsevier, Amsterdam, Netherlands 23-44.

Martins AF, Facchi SP, Follmann HD, Pereira AG, Rubira AF, Muniz EC. 2014. Antimicrobial activity of chitosan derivatives containing N-quaternized moieties in its backbone: a review. Int. J. Mol. Sci 15(11), 20800-20832.

Mohammed MI, Ismael MK, Gonen M. 2020. Synthesis of Chitosan-Silica Nanocomposite for Removal of Methyl Orange from Water: Composite Characterization and Adsorption Performance. IOP Conference Series: Materials Science and Engi- neering 745.

Nguyen NT, Nguyen NT, Nguyen VA. 2020. In Situ Synthesis and Characterization of ZnO/Chitosan Nanocomposite as an Adsorbent for Removal of Congo Red from Aqueous Solution. Advances in Polymer Technology 19-20, 1-8.

Onishi H, Nagai T, Machida Y. 2020. Applications of chitin, chitosan, and their derivatives to drug carriers for microparticulated or conjugated drug delivery systems, in: Applications of Chitin and chitosan, CRC Press, Boca Raton, Florida, USA 205-231.

Owda ME, Elfeky AS, Abou-Zeid RE, Saleh AI, Awad MA, Abdellatif H, Ahmed F, Elzaref AS. 2022. Enhancement of Photocatalytic And Biological Activities of Chitosan/Activated Carbon Incorporated With TiO2 Nanoparticles. Environmental Science and Pollution Research 29, 18189-18201.

Pouretedal HR, Keshavarz MH, Yosefi MH. Shokrollahi A, Zali A. 2009. Photodegradation of HMX and RDX in the presence of nanocatalyst of zinc sulfide doped with copper. Iran. J. Chem. Chem. Eng 28, 13-19.

Pritha Chakraborty, Vakas Mustafa, Jayanthi Abraham. 2018. Synthesis and Characterization of Chitosan Nanoparticles and Their Application in Removal of Wastewater Contaminants. Nature Environment and Pollution Technology 17(2), 469-478 2018

Sajid M, Ilyas M, Basheer C, Tariq M, Daud M, Baig N, Shehzad F. 2014. Impact of nanoparticles on human and environment: review of toxicity factors, exposures, control strategies, and future prospects. Environ Sci Pollut Res Int 22(6), 4122-43.

Salari M, Sowti Khiabani M, Rezaei Mokarram R, Ghanbarzadeh B, Samadi Kafil H. 2018. Development and evaluation of chitosan based active nanocomposite films containing bacterial cellulose nanocrystals and silver nanoparticles. Food Hydrocoll 84, 414-423.

Samadian H, Maleki H, Allahyari Z, Jaymand M. 2020. Natural polymers-based lightinduced hydrogels: promising biomaterials for biomedical applications. Coord. Chem. Rev 420, 213232.

Saranya Sukumar, Agneeswaran Rudrasenan, Deepa Padmanabhan Nambiar. 2020. Green-Synthesized Rice-Shaped Copper Oxide Nanoparticles Using Caesalpinia bonducella Seed Extract and Their Applications. ACS Omega 5, 1040−1051.

Sharififard H, Rezvanpanah E, Rad SH. 2018. A novel natural chitosan/activated carbon/iron bionanocomposite: Sonochemical synthesis, characterization, and application for cadmium removal in batch and continuous adsorption process. Bioresour Technol 270, 562-569.

Sharma S, Ameta R, Malkani RK, Ameta SC. 2013. Photocatalytic degradation of rose Bengal by semiconducting zinc sulphide used as a photocatalyst. J. Serbian Chem Soc 78, 897-905.

Sumayya AS, Muraleedhara Kurup G. 2017. Marine macromolecules cross-linked hydrogel scaffolds as physiochemically and biologically favorable entities for tissue engineering applications. J. Biomater. Sci. Polym. Ed 28 (9), 807-825.

Sun J, Jiang H, Wu H, Tong C, Pang J, Wu C. 2020. Multifunctional bionanocomposite films based on konjac glucomannan/chitosan with nano-ZnO and mulberry anthocyanin extract for active food packaging. Food Hydrocoll 107, 105942.

Tan G, Kaya M, Tevlek A, Sargin I, Baran T. 2018. Antitumor activity of chitosan from mayfly with comparison to commercially available low, medium and high molecular weight chitosans, In Vitro Cell. Dev. Biol. Anim 54(5), 366-374.

Tang F, Li L, Chen D. 2012. Mesoporous silica nanoparticles: synthesis, biocompatibility and drug delivery. Adv Mater 24(12), 1504-34.

Ullah R, Dutta J. 2008. Photocatalytic degradation of organic dyes with manganesedoped ZnO nanoparticles. J. Hazard. Mater 156, 194-200.

Vichare R, Garner I, Paulson RJ, Tzekov R, Sahiner N, Panguluri SK. 2020. Biofabrication of chitosan-based nanomedicines and its potential use for translational ophthalmic applications. Appl. Sci 10(12), 4189.

Wang H, Gong X, Miao Y. 2019. Preparation and characterization of multilayer films composed of chitosan, sodium alginate and carboxymethyl chitosan-ZnO nanoparticles. Food Chemistry 283, 397-403.

Zabihi E, Babaei A, Shahrampour D, Arab-Bafrani Z, Mirshahidi KS, Majidi HJ. 2019. Facile and rapid in-situ synthesis of chitosan-ZnO nano-hybrids applicable in medical purposes; a novel combination of biomineralization, ultrasound, and bio-safe morphology-conducting agent, International Journal of Biological Macromolecules 131, 107-116.

Submit Manuscript