Synthesis and evaluation of chitosan nanoparticle doped activated carbon (CSNPs@AC) as a photocatalyst to earn the degradation of organic dye

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Research Paper 15/06/2023
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Synthesis and evaluation of chitosan nanoparticle doped activated carbon (CSNPs@AC) as a photocatalyst to earn the degradation of organic dye

T. Shanmugavadivu, P. Bhuvaneswari, G. Sabeena, G. Annadurai, E. Pushpalakshmi, S. Rajaduraipandian, E. Sindhuja
J. Bio. Env. Sci.22( 6), 177-184, June 2023.
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Abstract

Growing human and industrial activity causes organic contaminants like dyes to contaminate water resources. This study created a nanocomposite photocatalyst for the breakdown of organic dye pollutants called a chitosan nanoparticle doped activated carbon (CSNPs@AC). The creation of the chitosan nanoparticle-doped activated carbon (CSNPs@AC) nanocomposite was confirmed by XRD, UV, FT-IR, and SEM-EDX studies. Using malachite green (MG) as a model organic dye, photocatalytic degradation was examined under UV and visible light. During photocatalytic degradation, it was discovered that the absorbance decreased in direct proportion to the drop in dye concentration. With MG, the degeneration happened more quickly. Additionally, the photocatalyst was more effective at degrading malachite green (MG) under UV light.

VIEWS 68

Ajmal A, Majeed I, Malik RN, Idriss H, Nadeem MA. 2014. Principles and mechanisms of photocatalytic dye degradation on TiO2 based photocatalysts: a comparative overview. RSC Advances 4(70), 37003-37026.

Altintig E, Onaran M, Sarı A, Altundag H, Tuzen M. 2018. Preparation, characterization and evaluation of bio-based magnetic activated carbon for effective adsorption of malachite green from aqueous solution. Materials Chemistry and Physics 220, pp.313-321.

Balagangadharan K, Dhivya S, Selvamurugan N. 2017. Chitosan based nanofibers in bone tissue engineering. International journal of biological macromolecules 104, 1372-1382.

Culp Sandra, Beland Frederick. 1996. Malachite Green: A Toxicological Review. International Journal of Toxicology 15(3), 219-238.

Dai K, Zhang X, Fan K, Peng T, Wei B. 2013. Hydrothermal synthesis of single-walled carbon nanotube-TiO2 hybrid and its photocatalytic activity. Applied Surface Science 270, 238-244.

Farahmandjou, M, Soflaee F. 2015. Synthesis and characterization of α-Fe2O3 nanoparticles by simple co-precipitation method. Phys. Chem. Res 3, 191-196.

Gholami P, Khataee A, Soltani RDC, Dinpazhoh L, Bhatnagar A. 2020. Photocatalytic degradation of gemifloxacin antibiotic using Zn-Co-LDH@ biochar nanocomposite. Journal of hazardous materials 382, 121070.

Hanif NSM, Shahril NSM, Azmar A, Winie T. 2015. Studies on the effect of acid treated TiO2 on the electrical and tensile properties of hexanoyl chitosan-polystyrene-LiCF3SO3 composite polymer electrolytes. In AIP Conference Proceedings 1674(1), 020028.

Hassandoost R, Pouran SR, Khataee A, Orooji Y, Joo SW. 2019. Hierarchically structured ternary heterojunctions based on Ce3+/Ce4+ modified Fe3O4 nanoparticles anchored onto graphene oxide sheets as magnetic visible-light-active photocatalysts for decontamination of oxytetracycline. J. Hazard. Mater 376, 200-211.

Hu B, Guo Y, Li H, Liu X, Fu Y, Ding F. 2021. Recent advances in chitosan-based layer-by-layer biomaterials and their biomedical applications. Carbohydrate Polymers 271, 118427.

Kanhere J, Gopinathan R, Banerjee J. 2014. Cytotoxicity and genotoxicity of malachite green on non-target aquatic organisms: Chlorella pyrenoidosa and Daphnia magna. Water, Air, & Soil Pollution 225, 1-8.

Kumar KY, Muralidhara H, Nayaka YA, Balasubramanyam J, Hanumanthappa H. 2013. Low-cost synthesis of metal oxide nanoparticles and their application in adsorption of commercial dye and heavy metal ion in aqueous solution Powder Technol 246, 125-136.

Kumar MNR. 2000. A review of chitin and chitosan applications. Reactive and functional polymers 46(1), 1-27.

Nagpal M, Kakkar R. 2022. The selective removal of Congo red using dumbbell-shaped hierarchically porous Ca-Mg mixed oxide. Applied Surface Science Advances 8, 100221.

Nguyen NT, Nguyen NT, Nguyen VA. 2020. In Situ Synthesis and Characterization of ZnO/Chitosan Nanocomposite as an Adsorbent for Removal of Congo Red from Aqueous Solution. Advances in Polymer Technology 20, 1-8.

Nie Q, Nie S. 2019. High-performance liquid chromatography for food quality evaluation. In Evaluation Technologies for Food Quality 267-299.

Owda ME, Elfeky AS, Abouzeid RE, Saleh AK, Awad MA, Abdellatif HA, Ahmed FM Elzaref AS. 2021. Enhancement of photocatalytic and biological activities of chitosan/activated carbon incorporated with TiO2 nanoparticles. Environmental Science and Pollution Research 29, 18189-18201.

Peternel IT, Koprivanac N, Bozic AML, Kusic HM. 2007. Comparative study of UV/TiO2, UV/ZnO and photo-Fenton processes for the organic reactive dye degradation in aqueous solution. J. Hazard Mater 148(12), 477-484.

Rabea EI, Badawy MET, Stevens CV, Smagghe G, Steurbaut W. 2003. Chitosan as antimicrobial agent: applications and mode of action. Biomacromolecules 4, 1457-1465.

Rajabi M, Kazem Mahanpoor, Moradi O. 2019. Preparation of PMMA/GO and PMMA/GO-Fe3O4 nanocomposites for malachite green dye adsorption: Kinetic and thermodynamic studies 167, 544 555.

Rathore BS, Chauhan NPS, Rawal MK, Ameta SC, Ameta R. 2020. Chitosan-polyaniline-copper (II) oxide hybrid composite for the removal of methyl orange dye. Polym. Bull. 77, 4833-4850.

Roy DC, Biswas SK, Sheam MM. 2020. Bioremediation of malachite green dye by two bacterial strains isolated from textile effluents. Current Research in Microbial Sciences 49, 1-20.

Sabeena G, Vainath Praveen S, Pushpalakshmi E, Annadurai, G. 2023. Comparative synthesis and characterization of nanocomposites using chemical and green approaches including a comparison study on in vivo and in vitro biological properties. Nanoscale Advances 5, 767-785

Sarojini G, Babu SV, Rajamohan N, Rajasimman M. 2022. Performance evaluation of polymer-marine biomass-based nanocomposite for the adsorptive removal of malachite green from synthetic wastewater. Environmental Research 204, 112-132.

Shahidi F, Arachchi JKV, Jeon YJ. 1999. Food applications of chitin and chitosan. Trends in food science & technology 10(2), 37-51.

Shamsizadeh A, Mehrorang Ghaedi, Ansari, AA, Azizian S, Mihir Kumar Purkait. 2014. Tin oxide nanoparticle loaded on activated carbon as new adsorbent for efficient removal of malachite green-oxalate: Non-linear kinetics and isotherm study 195, 212-218.

Sharififard H, Rezvanpanah E, Rad SH. 2018. A novel natural chitosan/activated carbon/iron bionanocomposite: Sonochemical synthesis, characterization, and application for cadmium removal in batch and continuous adsorption process. Bioresour Technol 270, 562-569.

Singh Rathore B, Pal Singh Chauhan N, Panneerselvam P, Jadoun S, Barani M, Ameta SC, Ameta R. 2022. Synthesis and Characterization of Ch-PANI-Fe2O3 Nanocomposite and Its Water Remediation Applications. Water 14(22), 3615.

Srivastava S, Sinha R, Roy D. 2004. Toxicological effects of malachite green. Aquatic Toxicology 66(3), 319-329.

Tang SH, Ahmad Zaini MA. 2020. Development of activated carbon pellets using a facile low-cost binder for effective malachite green dye removal. Journal of Cleaner Production 253, 119970.

Tewari K, Singhal G, Arya RK. 2018. Adsorption removal of malachite green dye from aqueous solution. Rev. Chem. Eng 34, 427-453

Tsai WT, Chen HR. 2010. Removal of malachite green from aqueous solution using low-cost chlorella-based biomass. J Hazard Mater 15, 1-3.

Venkatesan J, Anil S, Kim SK, Shim MS. 2017. Chitosan as a vehicle for growth factor delivery: various preparations and their applications in bone tissue regeneration. Int. J. Biol. Macromol 104, 1383-1397.

Verma DK, Malik R, Meena J, Rameshwari R. 2021. Synthesis, characterization and applications of chitosan based metallic nanoparticles: A review. Journal of Applied and Natural Science 13(2), 544-551.

Wang D, Liu L, Jiang X. 2015. Adsorption and removal of malachite green from aqueous solution using magnetic β-cyclodextrin-graphene oxide nanocomposites as adsorbents. Colloids Surf Physicochem Eng Asp 466, 166-173.

Zhao X, Lv L, Pan B, Zhang W, Zhang S, Zhang Q. 2011. Polymer-supported nanocomposites for environmental application: A review. Chemical Engineering Journal 170, 381-394.

Zhou L, Jin J, Liu Z, Liang X, Shang C. 2011. Adsorption of acid dyes from aqueous solutions by the ethylenediamine-modified magnetic chitosan nanoparticles. Journal of Hazardous Materials 185, 1045-1052.