The synthesis of activated carbon from ground nut shells and its characteristics for the active removal of textile dyes

Paper Details

Research Paper 07/03/2024
Views (746)
current_issue_feature_image
publication_file

The synthesis of activated carbon from ground nut shells and its characteristics for the active removal of textile dyes

R. Beautlin Nisha, M. Jaya Rajan
J. Biodiv. & Environ. Sci. 24(3), 20-26, March 2024.
Copyright Statement: Copyright 2024; The Author(s).
License: CC BY-NC 4.0

Abstract

Conversion and utilization of agricultural waste biomass into activated carbon is an alternative for high cost green adsorbents. The preparation of Activated carbon from Ground nut shell, and agricultural waste was investigated and presented here. Ground nut shell activated carbon is infused with Potassium hydroxide and carbonized (6000C, 1hrs). The obtained substance was activated to improve the surface area. On increasing the pore volume maximum adsorption capacity will be attained. The resulting activated carbon was characterized for its functional groups, Thermal Stability, surface morphology, and Elemental Identification using FTIR, TGA/DTA, and SEM. The dye removal efficiency of the prepared activated carbon was evaluated by using Congo red. Parameters like dosage, concentration, and pH are monitored to improve the properties of the prepared material for adsorbing synthetic dyes and industrial effluents. The monolayer adsorption (Langmuir) and the multilayer adsorption (Freundlich) isotherm models were determined to identify the maximum uptake (qmax) of Congo red by the adsorbent.

Abisha BR, Anish CI, Beautlin Nisha R, Daniel Sam N, Jaya Rajan M. 2021. Adsorption and equilibrium studies of methyl orange on tamarind shell activated carbon and their characterization. Phosphorus, Sulfur, and Silicon and the Related Elements 197(3), 225-230. https://doi.org/10.1080/10426507.2021.1993849

Extross A, Waknis A, Tagad C, Gedam V, Pathak P. 2022. Adsorption of congo red using carbon from leaves and stem of water hyacinth: equilibrium, kinetics, thermodynamic studies. International Journal of Environmental Science and Technology 20. DOI: 10.1007/s13762-022-03938-x.

Hazrat Ali, Ezzat Khan, Ikram Ilahi. 2019. Environmental Chemistry and Ecotoxicology of Hazardous Heavy Metals: Environmental Persistence, Toxicity, and Bioaccumulation.  Journal of Chemistry 4, 1-14. DOI: 10.1155/2019/6730305

Jaishankar M, Tseten T, Anbalagan N, Mathew BB, Beeregowda KN. 2014. Toxicity, mechanism and health effects of some heavy metals. InterdiscipToxicol. 7(2), 60-72. DOI: 10.2478/INTOX-2014-0009.

Jayarajan M, Arunachalam R, Annadurai G. 2011. Agricultural wastes of jackfruit peel nano-porous adsorbent for removal of rhodamine dye.” Asian Journal of Applied Sciences 4(3), 263-270. DOI: 10.3923/ajaps.2011.263.270

Jayarajan M, Arunachala R, Gurusamy A. 2011. Use of Low Cost Nano-porous Materials of Pomelo Fruit Peel Wastes in Removal of Textile Dye. Research Journal of Environmental Sciences 5, 434-443.

Kumari S, Khan S. 2018. Effect of Fe3O4 NPs application on fluoride (F) accumulation efficiency of Prosopis juliflora. Ecotoxicology and environmental safety 166, 419-426. DOI: 10.1016/j.ecoenv.2018.09.103.

Muzammil A, Miandad R, Muhammad W, Gehany F, Barakat MA. 2019. Remediation of wastewater using various nano-materials, Arabian Journal of Chemistry 12(8), 4897-4919.

Mulu Berhe Desta. 2013. Batch Sorption Experiments: Langmuir and Freundlich Isotherm Studies for the Adsorption of Textile Metal Ions onto Teff Straw (Eragrostis tef) Agricultural Waste. Journal of Thermodynamics, vol. 2013, Article ID 375830, 6 pages, 2013. https://doi.org/10.1155/2013/375830

Nimibofa A, Ebelegi AN, Wankasi D. 2017. Modelling and Interpretation of Adsorption Isotherms. Journal of Chemistry, vol. 2017, Article ID 3039817, 11 pages, 2017. https://doi.org/10.1155/2017/3039817.

Rahman MM, Adil M, Yusof AM, Kamaruzzaman YB, Ansary RH. 2014. Removal of heavy metal ions with acid-activated carbons derived from oil palm and coconut shells. Porous Materials 7 (5), 3634–3650. DOI: 10.3390/ma7053634.

Rajasulochana P, Preethy V. 2016.  Comparison on efficiency of various techniques in treatment of waste and sewage water – A comprehensive review. Resource-Efficient Technologies 2(4), 175-184.

Jain R, Sikarwar S. 2013. Adsorption and desorption studies of Congo red using low-cost adsorbent: activated de-oiled mustard. Desalination and Water Treatment 52, 7400-7411. DOI: 10.1080/19443994.2013.837004.

Rondina DJG, Ymbong DV, Cadutdut MJM, Nalasa JRS, Paradero JB, Mabayo VIF, Arazo RO. 2019. Utilization of a novel activated carbon adsorbent from press mud of sugarcane industry for the optimized removal of methyl orange dye in aqueous solution. Applied Water Science 9(8), 181. DOI: 10.1007/s13201-019-1063-0

Sushmita Banerjee, Chattopadhyaya MC. 2017. Adsorption characteristics for the removal of a toxic dye, tartrazine from aqueous solutions by a low cost agricultural by-product. Arabian Journal of Chemistry 10(Sup.2), S1629-S1638.

Singh H, Choden S. 2015. Comparison of adsorption behaviour and kinetic modeling of bio-waste materials using basic dye as adsorbate. Indian Journal of Chemical Technology 21, 359-367. DOI: 10.1061/9780784412725.ch08.

Sun B, Yuan Y, Li H, Li X, Zhang C, Guo F, Liu X, Wang K, Zhao XS. 2019. Waste-cellulose-derived porous carbon adsorbents for methyl orange removal. Chemical Engineering Journal 371, 55-63. DOI: doi.org/10.1016/j.cej.2019.04.031

Shariati-Rad M, Irandoust M, Amri S, Mostafa F,  Fattaneh J. 2014. Magnetic solid phase adsorption, preconcentration and determination of methyl orange in water samples using silica coated magnetic nanoparticles and central composite design. Int Nano Lett 4, 91–101. https://doi.org/10.1007/s40089-014-0124-5

Kwikima MM, Mateso S, Chebude Y. 2021. Potentials of agricultural wastes as the ultimate alternative adsorbent for cadmium removal from wastewater. A review. Scientific African, vol. 13, e00934. https://doi.org/10.1016/j.sciaf.2021.e00934

Yadav S, Yadav A, Bagotia N, Sharma AK, Kumar S. 2021. Adsorptive Potential of Modified Plant-Based Adsorbents for Sequestration of Dyes and Heavy Metals from Wastewater – A Review. J. Water Process. Eng. 42. DOI: 10.1016/J.JWPE.2021.102148.

Related Articles

Antioxidant and anti-inflammatory activity of Pleurotus citrinopileatus Singer and Pleurotus sajor-caju (Fr.) Singer

P. Maheswari, P. Madhanraj, V. Ambikapathy, P. Prakash, A. Panneerselvam, J. Biodiv. & Environ. Sci. 27(2), 90-96, August 2025.

Mangrove abundance, diversity, and productivity in effluent-rich estuarine portion of Butuanon River, Mandaue City, Cebu

John Michael B. Genterolizo, Miguelito A. Ruelan, Laarlyn N. Abalos, Kathleen Kay M. Buendia, J. Biodiv. & Environ. Sci. 27(2), 77-89, August 2025.

Cytogenetic and pathological investigations in maize × teosinte hybrids: Chromosome behaviour, spore identification, and inheritance of maydis leaf blight resistance

Krishan Pal, Ravi Kishan Soni, Devraj, Rohit Kumar Tiwari, Ram Avtar, J. Biodiv. & Environ. Sci. 27(2), 70-76, August 2025.

Conservation and trade dynamics of non-timber forest products in local markets in south western Cameroon

Kato Samuel Namuene, Mojoko Fiona Mbella, Godswill Ntsomboh-Ntsefong, Eunice Waki, Hudjicarel Kiekeh, J. Biodiv. & Environ. Sci. 27(2), 58-69, August 2025.

Overemphasis on blue carbon leads to biodiversity loss: A case study on subsidence coastal wetlands in southwest Taiwan

Yih-Tsong Ueng, Feng-Jiau Lin, Ya-Wen Hsiao, Perng-Sheng Chen, Hsiao-Yun Chang, J. Biodiv. & Environ. Sci. 27(2), 46-57, August 2025.

An assessment of the current scenario of biodiversity in Ghana in the context of climate change

Patrick Aaniamenga Bowan, Francis Tuuli Gamuo Junior, J. Biodiv. & Environ. Sci. 27(2), 35-45, August 2025.

Entomofaunal diversity in cowpea [Vigna unguiculata (L.) Walp.] cultivation systems within the cotton-growing zone of central Benin

Lionel Zadji, Roland Bocco, Mohamed Yaya, Abdou-Abou-Bakari Lassissi, Raphael Okounou Toko, J. Biodiv. & Environ. Sci. 27(2), 21-34, August 2025.

Biogenic fabrication of biochar-functionalized iron oxide nanoparticles using Miscanthus sinensis for oxytetracycline removal and toxicological assessment

Meenakshi Sundaram Sharmila, Gurusamy, Annadurai, J. Biodiv. & Environ. Sci. 27(2), 10-20, August 2025.